华南武夷山早古生代构造事件的^40Ar／^39Ar同位素年龄研究

华南武夷山地区广泛发育一套强烈韧性剪切变形的中、高级变质岩系,其新生矿物白云母非常普遍.对武夷山南麓政和县蝴碟街大理岩和北麓弋阳县慈竹片麻状花岗岩中的动力变质矿物白云母进行40Ar/39Ar法同位素测年,分别获得391±3Ma和421±8Ma的坪年龄值,以及385±5Ma和422±6Ma的等时线年龄值,时代相当于志留纪末到泥盆纪初.结合地质证据,认为武夷山地区存在过一期早古生代沉积作用和早古生代末期的构造热事件.至少有一期的强烈韧性剪切变形和糜棱岩化作用是该构造事件所导致     

Ar－HCl分子的振动光谱

本文报道了ＶａｎｄｅｒＷａａｌｓ分子Ａｒ－ＨＣｌ及其同位素分子Ａｒ－Ｈ３７Ｃｌ，Ａｒ－ＤＣｌ和Ａｒ－Ｄ３７Ｃｌ的振动激发态的能级和波函数的计算结果．通过计算谱带频率与观测数据的比较确定Ａｒ－ＨＣｌ的势能面．这一势能函数可对ＶａｎｄｅｒＷａａｌｓ分子Ａｒ－ＨＣｌ的分子间振动频率的同位素效应给出合理的解释．     

伊利石K—Ar测年在确定油气成藏期中的应用

利用伊利石Ｋ－Ａｒ测年确定油气成藏期,能够得出其绝对年龄,因而备受人们重视。可是在解释Ｋ－Ａｒ测年资料时,存在一些问题和假设。如果解释者对这些问题和假设没足够的认识,其解释结果就会有。文中以几个具体实例讨论了利用伊利石Ｋ－Ａｒ测年确定成熟期时对油气的充注时间和特征进行正确解释的方法。     

年轻火山岩激光40Ar/39Ar定年中的n值与MSWD值

激光熔蚀⁴⁰Ar/³⁹Ar等时线法是第四纪年轻火山岩样品精细定年的新方法, 该方法处于逐步完善过程中。针对怎样判定获得的年龄结果是否可靠的问题, 通过对数据处理过程中所用参数的分析, 认为样品属性是决定年轻火山岩精细定年结果质量和可靠性的关键因素, 与样品测试数n值相关的加权均方差MSWD(mean square weighted deviation)是判断同一样品各测试点的数据是否符合正态分布, 能否用来客观地评价测试结果, 进而评估样品是否适合进行相关测试, 结果是否可靠的重要指标。其次, 属于同一真实年龄值样品的MSWD在99.7%置信区间的取值范围可通过计算加以确认, 并提出对于表面年龄和等时线年龄数据, 必须定量地考察相应的MSWD值, 判定在具有足够样品测试数(足够大的n值)的情况下, 是否符合概率统计的正态分布, 确定样品是否对应同一年龄真实值。在MSWD值达不到理想值1.0的情况下, 可以利用表面年龄概率密度曲线, 区分测试样品内部包含的非同源或非等时或封闭不好体系的数据, 再结合MSWD与n值关系, 适量地去除部分偏离正态分布的测试数据, 识别出可能归属多个年龄真实值的测试数据组, 并以此计算不同数据组的反等时线年龄, 获得年轻火山岩喷发的准确年龄。     

西藏南部羊应乡后碰撞火山岩40Ar/39Ar年龄及其地质意义

通过西藏羊应乡地热田 4个高钾火山岩样品进行的快中子4 0 Ar/39Ar阶段升温定年结果 ,并结合其岩石地球化学研究数据 ,确定该地热田后碰撞火山作用发生在 (10 .73± 0 .0 9)～ (11.4 0±0 .11)Ma之间 ,形成与加厚下地壳 ,构造环境与岩石圈地幔减薄有关 .通过对青藏高原南部冈底斯地区新近纪火山岩同位素年龄的展布的进一步分析 ,认为后碰撞高钾火山岩在该区广泛存在 ,并有由西向东逐渐年轻的趋势 .     

河南老湾金矿床40Ar/39Ar定年及铅同位素研究

河南老湾金矿床为桐柏山北坡金银成矿带的主要组成矿床 ,矿床分布受龟山岩组、老湾花岗岩和韧性剪切带控制。石英单矿物的 4 0 Ar/ 39Ar定年方法测得金矿床的成矿年龄为 ( 91.5± 1.0 ) Ma,即金矿床形成于燕山晚期。铅同位素的研究结果表明燕山晚期形成的老湾花岗岩为矿床形成提供了成矿热液和主要的成矿物质 ,龟山岩组变质岩为矿床的另一个物源     

辽宁二道沟金矿床稳定同位素地球化学研究

通过对石英中流体包裹体的氢、氧同位素研究,揭示二道沟金矿床含矿热水溶液的δＤ为－７１‰～－１０２．５‰、δ１８ＯＨ２Ｏ为１．５３‰～６．７‰;在δ１８Ｏ－δ１８Ｄ图解中它们位于２００℃时大气降水与火山岩发生水岩交换的演化线与３００℃时大气降水与火山岩发生水岩交换的演化线所夹的区域内,表明成矿流体主要为大气降水来源的地下水,而不是岩浆热液;说明该矿床产于火山岩中的大气降水参与的浅成低温热液型金矿床．     

排山楼金矿床~(40)Ar-~(39)Ar年龄及其地质意义

采用Ar-Ar同位素测年法对辽宁排山楼金矿床矿化阶段形成的钾长石和似斑状花岗岩中的钾长石进行了测试,获得矿化阶段形成钾长石40Ar-39Ar坪年龄为(116.69±1.15)Ma,等时线年龄为(116.97±1.39)Ma,以及似斑状花岗岩中原生钾长石40Ar-39Ar坪年龄为(126.71±2.03)Ma,等时线年龄为(124.00±4.32)Ma的数据.前者代表了该矿床的形成年龄,即该矿床形成于早白垩世,后者表明金矿化不早于(126.71±2.03)Ma.这一成矿年龄与华北陆块北缘大部分金矿床的成矿年龄一致,表明华北陆块北缘绝大多数金矿床形成于中国东部中生代动力学体制发生转折的时期.     

新疆萨热阔布金矿黑云母~(40)Ar/~(39)Ar年龄及矿床成因启示

新疆萨热阔布金矿位于阿尔泰造山带南缘克兰盆地内,矿体呈脉状产于康布铁堡组火山岩地层中。为准确厘定其成矿时代,对矿区含矿石英脉中的云母进行了年龄测定,1件黑云母样品的40Ar/39Ar坪年龄为(213.5±2.3)Ma,相应的等时线年龄为(212.4±2.2)Ma,反等时线年龄为(212.5±2.2)Ma,与坪年龄在误差范围内一致。据此,萨热阔布金矿成矿作用发生于约213 Ma,成矿年龄晚于成岩年龄(~400 Ma)约180 Ma。因此,萨热阔布金矿为后生矿床。成矿年龄略晚于区域变质作用(~250 Ma)约37 Ma,推测成矿与阿尔泰造山带碰撞造山作用有关。结合矿床地质特征和流体包裹体特征,认为萨热阔布金矿为碰撞造山体制下形成的造山型金矿。     

40Ar/39Ar同位素体系及其在地学上的应用

40Ar/39Ar同位素体系大体经历了3个技术阶段常规 40Ar/39Ar定年技术、40Ar/39Ar分步加热定年技术和40Ar/39Ar激光显微探针定年技术.研究表明可以通过大气中40Ar/39Ar比值随时间的变化窥探地球去气作用的时间和强度;40Ar/39Ar法不仅有助于研究岩浆冷却过程和花岗岩侵位机制等岩浆动力学的历史和壳幔演化,而且对研究热液成矿年龄也是很有效方法之一;在一定的地质条件下,沉积地层时代越老,40Ar/39Ar值越高;当今40Ar/39Ar年代法已为全球环境演变研究提供了一种强有力的工具.     

Laser step-heating ^40Ar/^39Ar dating on young volcanic rocks

An attempt was made to use CO_2 laser step-heating method to date the late Pleistocene basaltic groundmass (DF-2) from Tengchong volcanic field. Among the fourteen heating steps, ten define a good inverse isochron (MSWD = 1.4) with an age of 32.2 ± 7.1 ka (2 σ).The inverse isochron also shows that the initial argon isotopic ratio is 297.1±2.0 (2σ) which is the same as the atmospheric argon at the 2σ error level. Study indicates that it is a useful means to date young volcanic groundmass with low K content by using CO_2 laser step-heating ~(40)Ar/~(39)Ar method.     

Ultra-violet laser probe measurement of ^40Ar／^39Ar age profile in phlogopite

Ultra-Violet Laser Ablation Microprobe (UVLAMP) extraction technique enables the direct investigation of Ar-Ar age prorde in crystals, and yields more information on rates and durations of geological process than conventional single time snapshots. Phlogopite flakes from lamprophyre at Pishan dyke in western Kunlun were dated by using an UV laser (λ= 213 nm) microprobe with spot analyses. The results show good agreement with those from the conventional ^40Ar/^39Ar step heating experiments. This indicates that the Ar isotopes are distributed homogenously in the phlogopite and the UVLAMP can be a powerful tool in the study of thermal history.     

~(40)Ar/~(39)Ar age evidence for Altyn fault tectonic activities in western China

As the northern boundary of the Tibetan Plateau theAltyn fault is a huge NEE strike-slip fault belt in the inner Asian continent. Its formation and evolution are closelyrelated to the uplift of the whole plateau and the mass es-cape to the east. In recent years the Altyn fault has be-come a hot point of geological study in the Tibetan Pla-teau. The formation age of the Altyn fault was argued for a long time. Some researchers emphasized that the Altyn fault had commenced since early Paleo…     

^40Ar/^39Ar dating for Cenozoic kamafugite from western Qinling in Gansu Province

A suite of Cenozoic ultra-potassic volcanic rocks and carbonatites are widespread along the Lixian-Dang- chang areas of western Qinling in Gansu Province. There are abundant mantle-derived xenoliths within these ultra-potassic volcanic rocks. Systemmatic …     

江西庐山中生代构造事件的40Ar/39Ar同位素年龄研究

江西庐山"星子变质核杂岩"中发育有大量中生代花岗岩,这些花岗岩中具有强烈的韧脆性剪切变形,典型的新生变质矿物为绢云母.通过对庐山海会花岗岩(其形成年龄为122～130 Ma)中动力变质矿物绢云母进行40Ar/39Ar法同位素测年,分别获得104.22 Ma±0.18 Ma和104.95 Ma±0.22 Ma的坪年龄值,以及104.7 Ma土0.36 Ma和105.03Ma±0.8 Ma的等时线年龄值,这表明江西庐山地区在130～104 Ma期间经历了从伸展构造环境向左行走滑构造环境的转变.     

Potash-rich volcanic rocks and lamprophyres in western Shandong Province: 40Ar39Ar dating and source tracing

Highly precise 40Ar39Ar dating results demonstrate that the ages of potash-rich volcanic rocks in western Shandong Province are 114.7-124.3 Ma, and that of the lamprophyres is 119.6 Ma. The potash-rich volcanic rocks have relatively high (87Sr/86Sr)i ratios ( 0.708715-0.711418)and distinctly negative εNd values ( -11.47 - -17.54), and are enriched in radiogenic lead (206Pb/204pb=17.341-17.622,207pb/204Pb=15.525-15.538, 208Pb/204pb = 37.563-37.684).Similarly, the lamprophyres also have quite low εNd values ( -11.57 - -19.64). Based on the fact that the Sr, Nd and Pb isotopic compositions of potash-rich volcanic rocks are very consistent with that of the clinopyroxene separates, and by integrating comprehensive analyses of their tectonic settings,and extensive comparisons of the Sr, Nd isotopic compositions with that of the related simultaneous rocks, it is concluded that the potash-rich volcanic rocks and lamprophyres in western Shandong Province were most possibly derived from the partial melting of enriched mantle which was caused by source contamination and metasomatism of subducted continental crustal materials.``     

40Ar retention in the terrestrial planets

The solid Earth is widely believed to have lost its original gases through a combination of early catastrophic release and regulated output over geologic time. In principle, the abundance of 40Ar in the atmosphere represents the time-integrated loss of gases from the interior, thought to occur through partial melting in the mantle followed by melt ascent to the surface and gas exsolution. Here we present data that reveal two major difficulties with this simple magmatic degassing scenario--argon seems to be compatible in the major phases of the terrestrial planets, and argon diffusion in these phases is slow at upper-mantle conditions. These results challenge the common belief that the upper mantle is nearly degassed of 40Ar, and they call into question the suitability of 40Ar as a monitor of planetary degassing. An alternative to magmatism is needed to release argon to the atmosphere, with one possibility being hydration of oceanic lithosphere consisting of relatively argon-rich olivine and orthopyroxene.