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1.
单一和混合胶束溶液中乙酰苯胺碱性水解反应动力学   总被引:1,自引:0,他引:1  
根据Beer定律和不可逆与可逆连续一级反应动力学方程,建立了不可逆与可逆连续一级反应体系溶液的吸光度方程,在40℃下乙腈水溶液中,用紫外分光光度法研究了单一和混合胶束及功能分子对乙酰苯胺碱性水解反应的催化作用。应用自函数回归法得到反应的动力学混合参数λ1和λ2,由λ1和λ2求得了反应的动力学参数k1,k-1,k2,k3。CTAB和SDS胶束,CTAB/BHMI,SOS/BHMI混合胶束和功能分子2  相似文献   

2.
通过对文题的研究,发现反应初期为动力学控制,对[Fe2+]为三级反应,频率因子为3.87×10121min-1,活化能为109.8kJ/mo1;反应后期为传质控制,对[Fe2+]为一级反应,频率因子为5.87×106min-1,活化能为35.5kJ/mol。氧分压对宏观反应速率影响不显著,在整个反应过程中反应速率对[O2]为0.2级反应。还得到了氧化过程的优化串级温度序列。  相似文献   

3.
本文分析了直墙建筑抛石基础块石在波浪作用下的稳定条件,提出了稳定块重的确定可以无量纲数相对于无量纲数V/gT,d1/d及m的相关函数表示,分析了稳定判别标准及不同损坏率的块重换算关系。  相似文献   

4.
提出一种IC芯片设计中双极型器件直流模型参数的提取方法。采取GP模型建立双向目标函数进行全局优化提取,分1级和2级参数两层处理.1级参数系提取IC设计中各管的共同参数,2级参烽则为提取与各个管的结构和尺寸相关的特定参数,尽管提取对象只是样管,但可以由模型内在关系通过程序计算出各管的特定参数,从而保证了电路模拟所需输入参数的真实性。  相似文献   

5.
利用嵌入马尔可夫链法,讨论了空竭服务单重休假M1X1,M2X2/G/1(E,SV)排队系统,在平稳状态下,得到了离去时刻系统队长的母函数,并证明了系统队长存在随机分解。  相似文献   

6.
用代数方法求出了一个分式函数(Fy,p0,p1,p2)的极大极小值,从而证明了作者原先给出的色散方程中四点显格式的最佳稳定条件为│αΔt/x^3│≤maxminF(y,p1,p1,p2)=2p0+1/4这里,p1是参数,满足下条条件之一:1,p1/-1/2,p0=0,P2〉0 2.p1≥0,p0=αp1,p2=βp1,α^2-2β+2αβ≤0,β≥α〉0 3.p2=0,p0=αp1〉0,α〈0,  相似文献   

7.
根据热动力学的基础理论,本文建立了等浓度三级反应的无量纲参数法.计算了20℃时环氧氯丙烷与氢溴酸反应,15和20℃时甲醛与氮反应的速率常数.在误差范围内与文献值相符合.证明了等浓度三级反应的正确性,拓宽了无量纲参数法的应用范围  相似文献   

8.
借助计算机研究了放热对峙反应:SO2+(1/2)O2→SO3。根据经验速率方程描绘出反应速率对温度依赖关系的曲线。用Newton法计算了不同转化率下的最适宜温度Tm,并用实验结果加以检验。用Runge-Kutta法解出该经验速率方程,从而确定了在反应系统中各个组分的分压与时间的关系,获得了在工程设计中有用的动力学参数  相似文献   

9.
用与Hennekemper不同的方法研究了(f^k+1)^(k)的值分布,将Hennekemper所得的基本不等式推广至小函数情形,得到了如下定理:设f为超越亚纯函数,F=(f^k+1)^(k),k∈N,ψ为非零的小函数,则T(x,f)≤(1+2k+1/4k^2+2k-1)N(r,1/f)+4k+2/4k^2+2k-1N↑-(r,1/F-ψ)+S(r,f)。  相似文献   

10.
用分子动力学模拟方法,重新确定了液氮的范德瓦尔参数,结合光谱数据,建立了适用于计算机模拟的N2的位能函数,函数形式采用量子力学力场,所得的范德瓦尔参数σ等于3.796A,ε等于0.2498kJ/mol。用得到的N2的位能函数对216个N2分子在三个不同温度下进行分子动力学模拟,计算了液氮的密度和蒸发热,计算结果和实验值的误差大约分别为1%和2%。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

18.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

19.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

20.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

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