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1.
作者研究以Carbotrap作吸附剂,采集大气中卤烃化合物,并直接采用热脱附气相色谱法,对新型吸附剂Carbotrap的突破体积、回收率、分析精度、固定液的选择等作了试验。本法具有灵敏度高、色谱峰形好、吸附剂可反复使用等优点,可对大气中ppb级卤烃化合物进行测定  相似文献   

2.
6^#溶剂油脱芳精制吸附剂再生技术   总被引:2,自引:0,他引:2  
吸附剂的再生直接影响吸附精制工艺的成败,决定了吸附过程能耗及吸附剂寿命。对吸附过程中已被轻质芳烃饱和13X型分子筛的再生脱附剂进行了筛选,比较。结果表明,工厂中副产C5馏分是合适的脱附剂。研究表明,温度,空速等因素对脱附效果有影响,脱附温度应于高300℃,脱附剂空速可随工艺要求在LHSV变化范围0.8-1.25h^-1内选择。  相似文献   

3.
载铜活性炭吸附分离氢气中的微量CO   总被引:12,自引:0,他引:12  
对文题的吸附平衡、吸附及脱附的工艺条件进行了考察。用Lang-muir-Freundlich公式关联了吸附平衡数据。根据吸附的性质,关联了吸附穿透曲线,解释了床层动力学现象。结果表明,利用此技术可将氢气中CO体积含量从2×10 ̄(-6)~16×10 ̄(-6)降至1×10 ̄(-6)以下,吸附剂单位处理量达6×10 ̄(-3)m ̄3/g以上(标准状况下气体体积)。同时,吸附剂再生容易,经120℃处理,即可脱附完全。该吸附剂经多次循环,性能稳定,具有一定工业应用价值。  相似文献   

4.
用13X分子筛在连续流动的吸附实验装置上对胜利石脑油进行了液相吸附脱芳烃实验研究.考察了该油品中一些轻质芳烃在该吸附剂上的吸附特性,对胜利石脑油液相吸附脱芳烃的吸附条件和再生方法进行了实验筛选.结果表明,该油品中各轻质芳烃在该吸附剂上吸附能力大小的排列顺序为:邻二甲苯>苯>乙笨=苯;在空速为0.2~0.8h ̄(-1)范围内,温度为60℃条件下对胜利石脑油进行液相脱芳烃实验,取得了满意的结果.用水蒸汽作为脱附剂在250℃时可以在较短的时间内完成吸附剂的再生.  相似文献   

5.
介绍了试验工艺流程、主要设备、控制方法及试验结果.采用蜂窝状活性炭吸附浓缩,小风量热空气脱附催化燃烧的工艺,完成了处理风量25000~30000m3/h含苯系物废气的工业试验.研究结果表明:对苯系物吸附净化效率在90%左右,排放浓度<100mg/m3,达到国家排放标准;用催化燃烧排放的热废气对蜂窝状活性炭脱附再生安全、有效、节能;催化燃烧过程可利用自身燃烧热进行或只耗少量电能;在国内首次实现工业微机对该工艺自动控制,解决了手工操作难以实现的控制过程,数据采集方便,准确.该方法具有设备体积小、耗能低、维修操作方便等特点,是治理低浓度、大风量有机废气的可行办法.  相似文献   

6.
制备了负载型Ru-Co羰基簇催化剂,用X-ray光电子能谱(XPS)和程序升温脱羰(TPD)等技术,对负载型双金属簇催化剂的表面化学性质和不同气氛中的脱附产物进行了研究,发现负载后,簇合物KRuCo3(CO)12中的RuCo3簇骨架与担体表面原子发生强相互作用。在反应温度下,可形成高分散型催化剂。认为CO加氢反应是按碳烯机理进行。  相似文献   

7.
制备了负载型Ru-Co羰基簇催化剂,用X-ray光电子能谱(XPS)和程序升温脱羰(TPD)等技术,对负载型双金属簇催化剂的表面化学性质和不同气氛中的脱附产物进行了研究,发现负载后,簇合物KRuCo_3(CO)_(12)中的RuCo_3簇骨架与担体表面原子发生强相互作用.在反应温度下,可形成高分散型催化剂.认为CO加氢反应是按碳烯机理进行.  相似文献   

8.
活性炭纤维在挥发性有机废气处理中的应用   总被引:2,自引:0,他引:2  
因活性炭纤维比普通活性炭性能优异、吸附量大,吸附脱附速度快,因此被应用于挥发性有机废气中苯系物、醋酸丁酯、甲醇等的吸附.介绍了活性炭纤维的分类、制备工艺、结构和性能.并展望了活性炭纤维在环保领域挥发性有机废气处理中的应用前景.  相似文献   

9.
吸附制冷用复合吸附剂的制备   总被引:2,自引:0,他引:2  
用静态法测定主要吸附材料和自制复合吸附剂对水的吸附量,用TG-DTA法对主要吸附材料的热稳定性和自制吸附剂对水的脱附峰端温度进行分析。对吸附剂原料复合比例、焙烧温度和扩孔剂种类等制备条件进行了实验研究。结果表明:自制复合吸附剂比单一吸附材料对水有着更大的吸附能力;DTA分析的脱水的峰端温度明显低于单一吸附材料;采用较高的焙烧温度和分段焙烧方法,可明显改善复合吸附剂的吸附性能及强度;对于用不同的吸附材料复合的吸附剂,需加入不同的扩孔剂,方可增加孔容和孔径,改善其吸附性能;自制复合吸附剂对水的吸附量显著高于13x和硅胶等传统吸附剂。其中,M1-9906和M1-9907复合吸附剂对水的吸附量大约是13x和硅胶的2-3倍。  相似文献   

10.
海泡石吸附脱除低浓度SO2废气的研究   总被引:4,自引:0,他引:4  
海泡石矿适当处理制得的吸附剂有效强的吸附脱硫能力,适合低浓度SO2废气的处理,并且脱附容易,脱附再生后重复作用性能好,脱附富集的SO2可用于硫酸生产。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

18.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

19.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

20.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

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