青椒中还原型维生素C含量的测定

主要介绍了钼蓝比色法测定青椒中还原型维生素C含量的基本原理和方法。井对最大吸收波长和最佳显色条件进行了探究,实验结果是在波长839nm处有强吸收,维生素c含量在0．004-0．024mg／mL范围内呈线性关系,方法的变异系数小于2．51％,回收率为97．2％。该方法简单、快速、准确,用此法测得市售青椒样品中的还原型维生素c的含量为0．2390mg／g。     

水温对饮料中维生素C含量的影响

采用紫外分光光度法,Cu2 做催化剂氧化抗坏血酸(还原型维生素C),差值法消除样品中其他成分的干扰吸收,检测了不同温度水冲泡卡夫柠檬C冲剂得到的溶液中还原型维生素C含量的差别.结果显示,冲泡冲剂所用的水温越高,得到的溶液中还原型维生素C越少,对维生素C的有效摄取有显著影响.     

硒纳米微粒的共振散射光谱特性及其应用

在盐酸介质中,维生素C还原Se（Ⅵ）生成较稳定的硒纳米微粒.它在可见光范围内无明显特征吸收峰,在340,470,470和520 nm处产生4个共振散射峰.维生素C浓度在0.05～4.0 mg/L范围内与I340nm呈良好的线性关系.据此本文建立了一个检出限为0.01 mg/L维生素C的共振散射光谱新方法,并用于合成样品和药品中Vc含量的分析,结果满意.     

甲磺酸帕珠沙星紫外光谱性质的研究及应用

在0．1mol／L HCI介质中，甲磺酸帕珠沙星的紫外吸收最强且稳定，最大吸收峰在247nm处，另外在331nm处也有显著吸收．在247nm处，吸光度与药物质量浓度在0～30．0mg／L（R=0．99996）范围内呈线性关系，检测限为0．026mg／L,在331nm处，吸光度与药物质量浓度在0～90．0mg／L（R=0．99995）范围内呈线性关系，检测限为0．144mg／L．该方法操作简便快捷，灵敏度较高，体系稳定．用于合成样品中甲磺酸帕珠沙星的测定，结果满意．     

电晕放电等离子体与H_2O_2氧化降解甲基蓝的光谱行为比较

采用紫外-可见光谱和FT-IR研究了电晕放电等离子体与H_2O_2氧化两种方法降解甲基蓝过程溶液的颜色变化和光谱行为差异。紫外-可见光谱结果表明,电晕放电等离子体降解甲基蓝过程溶液的颜色先加深再逐渐变浅,而H_2O_2氧化甲基蓝过程溶液的颜色一直变浅;H_2O_2氧化甲基蓝过程产生的中间物质在紫外-可见谱图中279 nm与372 nm处产生新吸收峰,而电晕放电等离子体降解甲基蓝过程的紫外-可见谱图中603 nm处甲基蓝发色基团吸收峰的强度先增强后减弱,并无新吸收峰出现。FT-IR分析结果表明,电晕放电等离子体技术破坏了甲基蓝结构中不稳定的环外C=C及C=N,在1 692.4 cm-1和1 400.4 cm-1处分别生成C=O和N=O的吸收峰;而H_2O_2氧化过程只破坏了C=N,在1 386.4 cm-1处产生N=O的吸收峰,表明这两种处理方法均对甲基蓝溶液有一定的降解能力。     

紫外分光光度法测定沙棘中维生素C含量

在pH=6．O的醋酸-醋酸钠缓冲溶液体系中，Cu(Ⅱ)可以催化氧化维生素C：在267nm处紫外吸收可用于直接测定沙棘中维生素C含量，并用活性炭吸附沙棘中的色素，与碘量法比较，结果基本一致。     

分光光度法同时测定饮料中的苋菜红和柠檬黄

采用紫外可见分光光度法同时测定市售葡萄味饮料中苋菜红和柠檬黄的含量. 饮料中苋菜红在521nm处有最大吸收峰,摩尔吸收系数为1.36×104 L·mol-1·cm-1;柠檬黄在428nm处有最大吸收峰,摩尔吸收系数为3.54×104 L·mol-1·cm-1,相对标准偏差(RSD)分别为0.10%和0.11%,回收率为95.0%～98.1%. 该方法不需要进行色素的分离,所需仪器设备简单,操作简便,准确度高.     

高粱色素含量测定方法的研究

用光度法研究了2种测定高粱色素含量的方法.一种是利用高粱色素溶液在494 nm处有最大吸收峰进行含量测定(直接测定法);另一种是在高粱色素溶液中加入显色剂后,在510 nm处有最大吸收峰而进行含量测定(间接测定法).结果表明,对于理论含量为20.0 g/L高粱色素溶液,用直接法和间接法测定的质量浓度分别为19.44 g/L和18.40 g/L,相对标准差分别为0.46%和3.37%,加标回收率分别为98.83%和88.58%.直接测定法具有快速、准确的特点.     

萝卜维生素C的分光光度法测定

探讨分光光度测定萝卜维生素C的方法,脎的最大吸收波长为490nm,线性回归方程：A=0.055＋0.42025C,r=0.9998。在0～0.320g.L-1浓度范围内呈良好的线性关系。     

偶氮胂Ⅰ-过氧化氢催化光度法测定茶叶中痕量锰

研究了在HAc-NaAc介质中,以氨三乙酸为活化剂,锰(Ⅱ)催化过氧化氢氧化偶氮胂Ⅰ褪色反应的条件及影响因素,建立了动力学光度法测定痕量锰(Ⅱ)的新方法.结果表明,该体系在509 nm处有最大吸收峰,测定锰的线性范围为0.004 0~0.016 0 mg/L,该催化反应的表观活化能为59.44 kJ/mol,表观速率常数为1.45×10-3s-1.用于茶叶中锰的测定,回收率均在99%~105%之间,相对标准偏差为2.1%.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with