贵州高硫高品位铝土矿硫溶出性能研究

对不同硫含量的贵州高硫铝土矿硫的溶出率进行了研究。在铝土矿硫含量一定的条件下,考查石灰添加量、溶出温度、苛性碱浓度和溶出时间等对硫的溶出率的影响,得出对硫溶出率影响较大的影响因素。实验结果表明,中等硫含量的高硫铝土矿能得到较低硫溶出率,较适宜的溶出条件为溶出温度260℃,碱浓度195 g/l,石灰添加量CaO12%,时间50 min.     

用高品位高硫铝土矿生产氧化铝时的除硫新方法研究

本文研究了贵州高硫型高品位铝土矿溶出性能,考查了石灰添加量、溶出温度、苛性碱浓度和溶出时间对氧化铝溶出率的影响以及铝土矿的硫向溶液中的转化率(即硫的溶出率)的影响;还研究了用铝酸钡净化拜耳赤泥洗液的除硫条件和效果。     

平果铝土矿最佳溶出条件研究

采用正交分析方法对平果铝土矿的溶出率进行最优分析，得到了氧化铝的溶出率与溶出温度、溶出时间、苛性碱浓度及石灰添加量的数学模型，利用该数学模型可以看出各个因素对溶出率影响的趋势，获得最佳的溶出条件，可以根据该模型制定更为合理的溶出工艺参数。     

低品位高硫铝土矿脱硅精矿溶出及微观结构演变

为有效开发与利用低品位高硫铝土矿,降低拜耳法流程中硫矿物的危害并提高氧化铝溶出率,采用高压溶出工艺考察苛碱质量浓度、时间、石灰添加量和温度对脱硅精矿溶出性能的影响。研究结果表明:最佳溶出条件为溶出条件为温度280°C,苛碱质量浓度245 g/L,时间70 min,石灰添加质量分数8%,在此条件下的相对溶出率为95.14%,比原矿和焙烧矿相对溶出率分别提高7.50%和9.77%,脱硅精矿溶出液中硫质量浓度为0.11 g/L,硫的实际溶出率为11.2%;脱硅精矿比表面积增大为31.25 m2/g,孔容和孔径分别增至0.0784 cm3/g和14.76 nm;氧化铝晶体[113]面在碱浸过程中晶粒粒径减小;脱硅精矿晶面间距减小,Al—O键长变大并存在0.185 4和1.971 0 nm 2种键长。     

中低品位贵州铝土矿石灰拜尔法溶出工艺

采用铝硅比为5.48的贵州中低品位一水硬铝石型铝土矿进行石灰拜尔法溶出实验,系统地研究石灰添加量、母液苛碱质量浓度和溶出温度等因素对溶出过程的影响。研究结果表明:随着石灰添加量的增大,溶出赤泥铝硅比和钠硅比均呈明显的下降趋势,增大石灰添加量对降低碱耗效果十分明显。贵州中低品位铝土矿石灰拜尔法适宜的溶出条件如下:石灰添加量为10%,配料分子比为1.45,循环母液苛碱质量浓度为200 g/L左右,溶出温度为270℃左右,溶出时间50 min,在此溶出条件下,溶出液苛性比1.40,赤泥铝硅比1.20,钠硅比0.38,氧化铝相对溶出率95%。     

石灰对三水铝石型铝土矿低温溶出行为的影响

研究了不同石灰添加量对3种国外三水铝石型铝土矿在145℃时溶出性能的影响规律及其作用机理.国外三水铝石型铝土矿主要由三水铝石、针铁矿、赤铁矿、高岭石和石英等组成,并含有一定的锐钛矿和一水软铝石.研究结果表明,添加石灰能够促进脱硅反应的进行,降低溶出后铝酸钠溶液中二氧化硅的质量浓度,随着石灰质量分数的增加,溶液的硅量指数逐渐提高;添加石灰降低三水铝石型铝土矿的氧化铝溶出率,其与石灰的质量分数呈线性递减关系;石灰促进脱硅产物由水合铝硅酸钠向水化石榴石转变,随着石灰质量分数的增加,溶出液中的苛碱质量浓度逐渐提高,赤泥中碱的质量分数逐渐降低.     

低品位高硫铝土矿静态焙烧脱硫及溶出性能

以低品位高硫铝土矿为原料,通过静态焙烧-活化溶出技术路线,解决脱硫同时兼顾溶出性能。采取XRD,SEM和Materials Studio等手段,分析焙烧脱硫-活化溶出过程中氧化铝及一水硬铝石晶体转变,得出焙烧矿最佳溶出条件,对比分析原矿与焙烧矿溶出动力学。研究结果表明:焙烧促使一水铝石晶体减小,氧化铝晶体变大、结晶更加完整;当静态焙烧温度为600℃和时间为180 s时,焙烧后铝土矿中硫质量分数为0.29%,脱硫率为75.83%;在600℃焙烧90 s时,矿石最佳溶出条件为溶出温度280℃、溶出时间70 min、苛碱质量浓度为245 g/L、CaO添加质量分数10%,此时氧化铝相对溶出率为94.8%;正交实验结果表明影响氧化铝溶出率的主次因素排序为温度、CaO添加质量分数、时间、苛碱质量浓度;原矿与焙烧矿在溶出过程中其表观活化能分别为48.89 kJ/mol和63.99 kJ/mol,氧化铝溶出主要受内扩散控制;焙烧矿和原矿在特定溶出条件下氧化铝相对溶出率(y)与溶出温度(T)之间的关系分别为:y=u(T)=-372.59+2.800 53T-0.004 06T~2和y=u(T)=-563.42+4.324 69T-0.007 14T~2,以焙烧矿经验公式作为参数优化依据,在285℃时氧化铝溶出率为95.63%。     

高硫铝土矿悬浮态焙烧及焙烧矿的溶出性能

为了验证高硫铝土矿悬浮态焙烧工艺及装置的可靠性和长期稳定性,为工业生产线的设计提供必要的工艺和设备结构参数,在基础研究和中试条件试验的基础上,以黔北地区全硫(ST)质量分数1.93%的一水硬铝石型高硫铝土矿为原料,进行750 kg/h规模的连续性验证试验。研究结果表明:悬浮炉内轴向温度650~460℃,粉料在炉内有效停留时间约3 s,所得焙烧矿中硫化物型硫的平均质量分数为0.05%,ST质量分数小于0.3%。在溶出温度260℃、溶出时间60 min、石灰添加量9%、苛性碱质量浓度236 g/L、溶出液Na和Al分子比1.50的条件下,焙烧矿相对溶出率接近99.5%,相对于原矿,溶出效果得到提高。     

碳酸盐在铝土矿溶出过程中的脱除行为

采用XRD,XRF,SEM-EDS和PSD等检测手段,系统研究了不同石灰添加量、溶出温度、晶种添加量和碳酸盐质量浓度下一水硬铝石型铝土矿高压溶出过程中铝酸钠溶液中碳酸盐含量的变化规律及其脱除机理.结果表明:铝酸钠溶液中碳酸盐质量浓度为25 g·L^-1时,氧化铝溶出和碳酸盐脱除的最佳条件为:石灰添加量为11%,溶出温度为270℃,此时氧化铝的溶出率和碳酸盐的脱除率分别为72.47%和68.95%.具有板条状结构的霞石(Na₆(Al₆Si₆O₂₄)·Na₂CO₃·2H₂O)为脱除碳酸盐时的主要产物.铝酸钠溶液中碳酸盐质量浓度在25 g·L^-1以下时碳酸盐更易脱除.     

粗粒径高硫铝土矿焙烧前后脱硫及溶出性能研究

对贵州省某一水硬铝石型的高硫铝土矿进行焙烧脱硫实验研究。探究焙烧时间、焙烧温度等条件对脱硫的影响,并借助XRD对焙烧机理进行分析;在这个基础上,对比矿物焙烧前后的高压溶出实验,观察两种溶出液中的硫的变化规律以及溶出性能的改变。结果表明:在焙烧温度700℃、时间为30 min及粒径为830μm时,矿石中硫含量从2.33%降至0.68%;矿石经过高温焙烧后,矿石成分发生改变,溶出性能得以提高;对于硫存在形式以黄铁矿为主的高硫铝土矿,焙烧后溶出液的硫浓度相比原矿溶出液大幅降低,且硫的溶出率由原矿的28.8%降至14.8%,氧化铝相对溶出率增加到95%以上。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with