Tree ring based streamflow reconstruction for the Upper Yellow River over the past 1234 years

We established a Juniperus przewalski tree ring width chronology, based on tree ring cores collected from the A’nyêmaqên Mountains. Statistical analysis showed that the chronology was highly correlated with instrumental streamflow records from previous August to current July from the Tangnaihai Station in the upper reaches of the Yellow River, with a correlation coefficient of 0.656. Streamflow for the upper reaches of the Yellow River was reconstructed for the past 1234 years. Low flow periods for the 11-year averaged streamflow reconstruction were definite as lower than mean plus 1 standard deviation, and high flow periods were higher than mean minus 1 standard deviation. Over the past 1234 years, high flows occurred 18 times, and low flows occurred 12 times. The main low flow periods were identified as AD 1140–1156, AD 1295–1309, AD 1473–1500, and AD 1820–1847, and the main high flow periods were identified as AD 846–873, and AD 1375–1400. Extremely low streamflow over the reconstruction period was seen during the late 15th century, coinciding with a widespread drought phenomenon, which took place in the northeastern Tibetan Plateau over the same period. Reconstructed streamflow shows significant low-frequency variability, which is in line with drought variability of neighboring regions, as inferred from tree rings and other proxies. Multi-taper spectral analysis suggests the existence of significant periods of 2–5, 22, 35–38, 55–62, and 114–227 years, particularly significant for cyclic variations of years 159 and 36.     

Simulated and reconstructed winter temperature in the eastern China during the last millennium

Since the 1990s, under the auspicious impetus of two international research programs, the “Past Global Changes” (PAGES) and the “Climate Variability and Pre- dictability” (CLIVAR), massive research work has been carried out on climate and environment changes over the past 2000 years[1-3]. But majority of the studies has been centered on obtaining various kinds of climatic proxy data (such as historical documents, tree rings, ice cores, lake cores) and focused on the reconstruction of…     

Temporal and spatial variations in the Palmer Drought Severity Index over the past four centuries in arid, semiarid, and semihumid East Asia

Based on a database of 106 annually resolved tree-ring chronologies and 244 Palmer Drought Severity Index(PDSI)grid data,we attempted to reconstruct gridded spatial drought patterns in each year over the past four centuries in the arid,semiarid,and semihumid East Asia.The results showed that these regions mainly experienced drought events during the periods from AD 1601 to AD 1652,AD 1680 to AD 1718,AD 1779 to AD 1791,AD 1807 to AD 1824,AD 1846 to AD 1885,and AD 1961 to AD 1999.In the middle of the 16th century,severe droughts occurred mainly in North China;during the period from AD 1876 to AD 1878,droughts occurred in most parts of northern China;and from the 1920s to 1940s,catastrophic drought events spread across almost all of northern China and Mongolia.These historical drought events caused severe ecological and environmental problems and substantially affected the development of human society.In these regions,temperature and summer monsoon precipitation are the main factors influencing drought events.In western areas,PDSI and temperature exhibit a close relationship,whereas in eastern areas,summer monsoon rainfall is the dominant factor influencing variations in PDSI.     

A 457-year reconstruction of precipitation in the southeastern Qinghai-Tibet Plateau, China using tree-ring records

This paper presents a 457-year reconstruction of precipitation in the southeastern Qinghai-Tibet Plateau using tree-ring records.Tree-ring samples were collected from the Hengduan Mountains in the southeastern part of the Qinghai-Tibet Plateau,China.A nearly 500-year chronology was developed using tree-ring width records.Correlation analysis shows moisture is the main factor limiting tree growth in this region.Ring-widths were significantly positively correlated with the Palmer Drought Severity Index(PDSI) and precipitation in many months.The highest correlation coefficient was found between the annual growth of trees and precipitation from the previous September to the current June(0.738).Based on this relationship,we reconstructed the precipitation history from 1509 to 2006.The reconstruction explains 54.4%(Radj2=53.5%,N=49,F=56.12) of the actual precipitation variation during the calibration period(1958-2006).During the reliable period of the reconstruction(1549-2006),some low-frequency climate signals are included,indicating this region has been getting wetter in the last 20 years.The reconstruction documents six apparently dry and five pluvial periods and the 17th century dry period lasted longer than any other.When compared with other recent studies,this study and these earlier reconstructions show a similar trend in the variation of drought and pluvial.Further spatial correlation analysis confirms that the reconstructed precipitation adequately represents the rainfall history of the entire Hengduan Mountain area.The Multi-taper method,a type of spectral analysis,reveals that precipitation in this area had significant(P<0.01) spectral peaks at 3-5 a,60 a and 79-85 a.     

Temperature variability since A.D. 1837 inferred from tree-ring maximum density of <Emphasis Type="Italic">Abies fabri</Emphasis> on Gongga Mountain,China

Two tree-ring MXD (maximum latewood density) chronologies of Abies fabri were developed from the eastern slopes of Gongga Mountain, and a regional chronology (RC) was established based on the two MXD chronologies. There were significant positive correlations between the three MXD chronologies and August–September temperature, and the RC had the highest correlation (r=0.733, n=48, P<0.001) with mean August–September temperature. Based on growth-climate analyses, we reconstructed mean August–September temperature during the past 171 years for the study area. The reconstruction explained 53.5% of the instrumental temperature variance during the period 1960–2007 (F=52.8, R²_adj =52.4%). In the past 171 years, there were 22 very warm years and 23 very cold years, four cold periods (1837–1842, 1884–1891, 1899–1905 and 1984–1989) and three warm periods (1966–1973, 1916–1924 and 1876–1881). Our reconstruction was validated by other tree ring-based temperature reconstructions from the surrounding area and documented climate disaster events.     

干旱对华北地区植被变化的影响

利用中分辨率成像光谱仪(moderate-resolutionimagingspectroradiometer,MODIS)归一化植被指数 (normalizeddifferencevegetationindex,NDVI)数据产品和气象站点的帕尔默干旱指数(thepalmerdroughtseverity index,PDSI)数据,分析了2001-2013年华北地区及3个主要地表覆盖类型区植被变化的时空特征和干旱的变化特征, 并以不同时间尺度分析了干旱对植被变化的影响.结果表明:1)华北地区植被NDVI空间分布差异较大,NDVI总体上 呈东南高、西北低的分布特点.2001-2013年,华北地区植被活动呈增强的趋势,其中秋季植被活动的增强趋势最明显. 2)2001-2013年,华北地区的干旱总体上有所减轻,其中秋季干旱减轻的趋势最明显.3)华北地区植被年际变化与干旱 有显著的正相关关系,干旱对植被生长状态有较大影响.北部草原区和中部落叶阔叶林带的植被年际变化与干旱的正相 关性显著;而南部农作物区不显著,干旱对农作物生长状态影响较不明显.4)在季节尺度上,华北地区夏季植被变化与干 旱的正相关性最为显著,夏季植被生长状态最容易受到干旱的影响;以16d的植被数据分析表明,NDVI距平值更适合 表征华北地区植被生长状态与干旱的关系.      

Millennial temperature reconstruction based on tree-ring widths of Qilian juniper from Wulan, Qinghai Province, China

The climate of the past 1000 years is an important context for evaluating the recent climate warming. However, there are few 1000-year-long climate reconstructions with annual resolution in the Qinghal-Tibet Plateau. In this paper, a dendroclimatic analysis was conducted for the radial growth of Qilian juniper from the upper forest limit in Wulan, Qinghai Province. The results of correlation analysis between the tree-ring widths and the climate variables indicate that the growth of junipers at the upper forest limit is mainly limited by low temperatures of September, November and February of the pregrowth season, and July of the current growth season. There is no significant correlation between the tree-ring widths and precipitation. A mean temperature from the previous year＇s September to the current year＇s April was reconstructed for the Wulan area since A.D. 1000. The reconstruction can explain 40.8% of the instrumental variance in the calibration period （1856-2002）. The reconstruction shows that the 20th century is the warmest 100 years, and the 1990s is the warmest decade during the past 1000 years, while the coldest 100 years and decade occur at 1600-1699 and 1642-1651, respectively. The variations are verified well by the temperature reconstruction of the middle Qilian Mountain （QL） and the total organic carbon （TOC） in the Qinghai Lake sediments. The comparison of our reconstruction with the annual temperature reconstruction of extra-tropical Northern Hemisphere suggests that the climate of Wulan during the Medieval Warm Period is of obvious regional specialty, but there was a good response to the climate of hemispheric scales during the recent 400 years.     

Meridional seesaw-like distribution of the Meiyu rainfall over the Changjiang-Huaihe River Valley and characteristics in the anomalous climate years

Although Meiyu rainfall has its in-phase spatial variability over the Changjiang-Huaihe River Valley (CHRV) in most years, it is distributed in some years like a seesaw to the north and south of the Changjiang River, when the precipitation tends to be nearly normal throughout the valley, which would inevitably increase difficulties of making short-term prediction of the rainfall. For this reason, EOF analysis is made on 15 related stations’ precipitation from June to July during 1951─2004, revealing that the EOF2 mode shows largely a north-south seesaw-like pattern, and thereby classifying Meiyu patterns into two types: "northern drought and southern flood (NDSF)" and "northern flood and southern drought (NFSD)". Afterwards, the authors investigated ocean-atmospheric characteristics when these two anomalous types occured using the NCEP reanalysis (version 1) and the extended reconstructed SSTs (version 2). The results show that in the NDSF years, the low-level frontal area and moisture convergence center lie more southward, accompanied by weaker subtropical summer mon- soon over East Asia, with the western Pacific subtropical high and 200 hPa South Asia High being more southward. Both the Northern and Southern Hemisphere Annular Modes are stronger than normal in preceding February; SST is higher off China during boreal winter and spring and the opposite happens in the NFSD years. Also, this seesaw-form Meiyu rainfall distribution might be affected to some degree by the previous ENSO event.     

Variations of the spring precipitation day numbers reconstructed from tree rings in the Urumqi River drainage,Tianshan Mts. over the last 370 years

The tree-ring cores of Tianshan spruces col-lected from nine sites in the Urumqi River drainage of the middle Tianshan Mountains were used to establish three types of the tree-ring width chronologies over the last 370 years, using the international standard method of dendro-chronology. Our study demonstrates that dendrochronologycan be better used to reconstruct the number of the precipi-tation day than to reconstruct the precipitation amount in middle Tianshan Mountains. It is found that the residual chronology among the three tree-ring width chronologies has the best relationship with number of spring precipitation days from May 20 to June 8. The chronologies at Haxiong-gou B site and Zaierdegou site in the Urumiqi drainage have the highest correlation with the observed number of spring precipitation days at Daxigou meteorological station, and are used to reconstruct the spring precipitation days over the last 370 years in the drainage. The main significant decreasing trend of the number of the spring precipitation days oc-curred during 1665--1717, while the significant increasing trends happened during 1805--1841 and 1914--1943. The reconstructed series of the number of spring precipitation days has quasi-periodic variations of 3.3, 2.1, 2.5, 12.3 and 32.0 years with the dominated short periodical changes. The long cycle of 32 years is shown quite clearly in the 10-year smoothed sequence. The maximum spring precipitation days occurred mainly in the 1630s, 1840s and 1940s, while the lowest number of spring precipitation days for the 10-year average occurred in the 1710s.     

Climate change over southern Qinghai Plateau in the past 500 years recorded in <Emphasis Type="Italic">Sabina tibetica</Emphasis> tree rings

Two tree ring-width chronologies of Sabina tibetica were developed based on cores sampled in Qumalai and Zhiduo, southern Qinghai Plateau. The response function analysis showed that the chronologies were sensitive to temperature and precipitation from April to June in the plateau. Moisture index (MI) was defined, reconstructed and extended back to AD 1550. The cross-validation method was used to check the stability of the calibration equation, and the result indicated that the equation was stable. Six severe dry periods were found in this region in the past 453-year reconstruction, which were 1592 to 1610, 1649 to 1665, 1687 to 1697, 1740 to 1750, 1818 to 1829 and 1918 to 1933. Five severe wetting periods were 1669 to 1682, 1700 to 1709, 1800 to 1814, 1898 to 1909 and 1935 to 1950. Spectrum analysis indicated that there existed long-term cycles of 60.4 and 53.4 a, solar cycle of 11 a and short-term cycles of 8, 6 and 4 a in the reconstructed series.     

Low temperature thermodynamic study of the stable and metastable phases of vanadium

The low temperature thermodynamics of the stable phase of vanadium has been assessed by the polynomial and Debye models from the experimental data available in literature. By means of the con-strained nonlinear least squares curve fitting arithmetic,two sets of parameter values have been de-termined. Expressions of the thermodynamic functions Cp(T) and G(T)-H(298.15 K) at 0―298.15 K are presented. The low temperature thermodynamics of the metastable phase of vanadium can only be extrapolated by the Debye model. The expression of the thermodynamic function Cp(T) at 0―298.15 K is presented.     

A high-resolution climatic chanse since Holocene inferred from multi-proxy of lake sediment in westerly area of China

Multi-proxy data are presented and a discuss is made of paleoclimatic and paleoenvironmental changes during Holocene from a 225-cm-long sediment core from Wulungu Lake, located in westerly area of China. The chronology is constructed from six AMS radiocarbon dates on the bulk organic matter. Analyses of pollen, TOC, TN, δ^13Corg, ostracod assemblages and the shell stable isotopes, suggest Holocene climate pattern as follows： temperate and dry （10.0-7.6 cal. ka BP） -warm and wet （7.6-5.3 cal. ka BP） -warm and moist （5.3-3.6 cal. ka BP） -temperate and dry （3.6-2.1 cal. ka BP）-temperate and moist （2.1-1.3 cal. ka BP） -cool and dry （1.3 cal. ka BP-present）. With the climatic change, Wulungu Lake experienced two large-scale retreat （5.3-3.6 cal. ka BP and 1.3 cal. ka BP-present） and an obvious transgression （7.6-5.3 cal. ka BP）. The records of climatic and environmental evolution of Wulungu Lake were in good accordance with those of adjacent areas. It responded to regional environmental change, global abrupt climate events and followed the westerly climate change mode.     

Theoretic study of the reaction mechanism between （Me）3CO· radical and trans-3-hexene

The reaction mechanism between （Me）3CO· radical and trans-3-hexene in benzene was studied for the first time at the B3LYP/6-311＋＋G（d,p）//B3LYP/6-31G（d）＋ZPVE level. Two distinct elementary channels were identified as： （1） abstraction-addition; （2） addition-addition-elimination. Analysis of the potential energy surface demonstrates that for the title reaction, channels （1） and （2） have the major and minor contribution, respectively. Our calculated results can well explain the recently observed product distribution by Coseri et al. （J. Org. Chem. 2005, 70, 4629）. However, we found that the addition-abstraction channel proposed by Coseri et al. is kinetically infeasible.     

SHRIMP zircon U-Pb dating of the Gangou granitoids, Central Tianshan Mountains, Northwest China and tectonic significances

Two types of granitoids, highly deformed eugen grenitoids end undeformed fine-grained grenitoids, ere widely distributed in Gangou area, Central Tianshen Mountains, Northwest China. The augen grenitoids are high-K calc-alkaline characterized by high K20, Rb, Y and Th, and low Sr and Sr/Y. They also have high contents of large ion lithophile elements （LILE）, such as Be, Rb, K and Th, and relatively low contents of high field strength elements （HFSE）, such as Zr, Y and Nb. The fine-grained granitoids are calc-alkaline cherecterlzed by high Sr, low Y and HREE, similar to adakitic rocks, and with Na20/K20〈2 （1.76-1.91）, high/sr （0.70689--0.70981）, and negative εNd（t） （-2.4-5.3）. High-precision SHRIMP U-Pb zircon dating results indicate that the Gangou augen greniUods were formed at 428 ± 10 Me, and the fine-grained granitoids were emplaced at 361 -368 Me. These geochemical and U-Pb zircon data have significant implications for the timing of closure of the Mishigou-Gangou Ocean and the evolution of the Central Tianshan orogenic belt.     

Coesite in eclogite from the North Qaidam Mountains and its implications

Coesite provides direct evidence for ultrahigh pressure metamorphism. Although coesite has been found as inclusions in zircon in paragneiss of the north Qaidam Mountains, it has never been identified in eclogite. In this contribution, based on petrographic observations and in situ Raman microprobe spectroscopy, coesite was identified as inclusions in garnet of eclogite from the Aercituoshan, Dulan UHP metamorphic unit, north Qaidam Mountains. Coesite is partly replaced by quartz, showing a pali-sade texture. This is the first report on coesite in eclogite from the north Qaidam Mountains, and is also supported by garnet-omphacite-phengite geothermobarometry (2.7―3.25 GPa, 670―730℃). Coesite and its pseudomorphs have not been found in eclogites and associated rocks of other units of the north Qaidam Mountains. Further studies are required to confirm if all metamorphic units in the north Qaidam Mountains underwent the ultrahigh-pressure metamorphism.     

Reconstructing mean maximum temperature of growing season from the maximum density of the Schrenk Spruce in Yili, Xinjiang, China

To study the historical temperature variation in Yili of Xinjiang, the tree-ring chronologies of maximum density （MXD） and tree-ring width （TRW） were established with the Schrenk Spruce （Picea schrenkiana Fisch. et Mey） collected from six sites to analyze the characteristics and ability of response to climate change. The results suggest that the MXD chronology of the Schrenk Spruce from different sampling sites responded to climate change well and were positively correlated with the mean maximum temperature and the mean temperature from April to August in the study area. The mean maximum temperature anomaly from April to August, spanning the years from 1848 to 2000, was reconstructed by three MXD chronologies which were selected by stepwise regression. The reconstructed function was stable and explained 56.2% of the variance. The reconstructed results indicated a cold span of 153 years in spring and summer from the beginning of the 1950s to the beginning of the 1970s in the Yili valley. No strongly increasing tendency was detected in the mean maximum temperature anomaly from April to August during this reconstructed period.     

Statistic characteristics and weather significance of infrared TBB during May―August in Beijing and its vicinity

In order to meet the demand of nowcasting convective storms in Beijing, the climatological characteristics of convective storms in Beijing and its vicinity were analyzed based on the infrared （IR） temperature of black body （TBB） data during May--August of 1997--2004. The climatological probabilities, the diurnal cycle and the spatial distribution of convective storms are given respectively in this paper. The results show that the climatological characteristics of convective storms denoted by TBB≤-52℃ are consistent with those statistic studies based on the surface and lightning observations. Furthermore, the climatological characteristics of May and June are very different from those of July and August, showing that there are two types of convective storms in this region. One occurs in the transient polar air mass on the midlatitude continent during the late spring and early summer. This type of convection arises with thunder, strong wind gust and hail over the mountainous area in the northern part of this region from afternoon to nightfall, the other occurs with heavy rainfall in the warm and moist air mass over the North China Plain and vicinity of Bohai Sea. This study also shows that the long-term data of IR TBB observed by geostationary satellite can complement the temporal and spatial limitation of the weather radar and surface observations.     

A tree-ring-based reconstruction of the Yimin River annual runoff in the Hulun Buir region, Inner Mongolia, for the past 135 years

Based on the relationships between the regional tree-ring chronology(RC) of moisture-sensitive Pinus sylvestris var.mongolica and the monthly mean maximum temperature,annual precipitation and annual runoff,a reconstruction of the runoff of the Yimin River was performed for the period 1868-2002.The model was stable and could explain 52.2% of the variance for the calibration period of 1956-2002.During the past 135 years,21 extremely dry years and 19 extremely wet years occurred.These years represented 15.6% and 14.1% of the total study period,respectively.Six severe drought events lasting two years or more occurred in 1950-1951,1986-1987,1905-1909,1926-1928,1968-1969 and 1919-1920.Four wetter events occurred during 1954-1959,1932-1934,1939-1940 and 1990-1991.Comparisons with other tree-ring-based streamflow reconstructions or chronologies for surrounding areas supplied a high degree of confidence in our reconstruction.Power spectrum and wavelet analyses suggested that the reconstructed annual runoff variation in the Hulun Buir region and surrounding area could be associated with large-scale atmospheric-oceanic variability,such as the Pacific Decadal Oscillation(PDO) and El Ni o-Southern Oscillation(ENSO),and sunspot activity.     

Myoglobin as Mimetic Enzyme and Its Analytical Application in Determination of H2O2

0 IntroductionSltougdiiceasl csoynstceermnsin gharveeac btieveen o txhyeg ei nm psopretcaienst ( oRbjOecSt) iinn bbiioo--medicine and analytical chemistry in recent years[1-4]. Manyi mportant life phenomena and diseases are relatedtotheinter-mediates of ROS[5-7].ROS have beeni mplicated as ani mpor-tant causative factor in cell damage,including apoptosis andnecrosis . Their proposed actions comprise lipid peroxidation,DNAdamage,the mitochondrial respiratory chain destructionand protein mo…     

Latitudinal shift and tilt of the ring current during magnetic storms

The equatorial ring current (ERC) theory suggested that the distribution of global disturbed horizontal geomagnetic field only depends on the cosine of station’s latitude. However, we always observe a larger ΔH at higher latitude stations than lower ones, implying that the ERC could tilt or/and shift with respect to the equatorial plane during intense storms. In this paper, we analyze 11 intense magnetic storms from 2000 to 2004, and introduce two configurational factors to characterize the topology of storm time ring current. The results show that ERC has occasionally deviated off equatorial plane with both tilt angle δ_t≈13°―25° and latitude shift δ_s≈0°―21.8°. The ground disturbed field distribution should be improved as ΔH_k = ΔH_maxcos(φ_k-δ ), which agree well with the geomagnetic observations.