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1.
采用分步降解法合成了2:17钨砷酸钾杂多配合物.用元素分析,VO2+光度滴定、紫外光谱、红外光谱、X-射线衍射、循环伏安、热重-差热分析对标题化合物进行了表征.实验结果表明,它具有一空缺α2型Dawson结构及不可逆的氧化还原性.较1:11钨砷酸钾有更强的氧化性和比2:18钨砷酸铵杂多配合物有稍高的热稳定性.  相似文献   

2.
本文报导了[P2W17(TiO2)O61]8-杂多阴离子钾盐的合成,通过元素分析、IR.UV及核磁共振谱等对化合物进行了表征,确认钛取代的位置是Dawson结构的"极位"上。  相似文献   

3.
采用立体有择方法合成了具有Dawson结构的2种杂多酸盐,它们分别是:a2-K2「P2W17TiO62」.5H2O和a-1,2,3-K19H2「P2W16Ti3O62」.2H2O;并利用化学位移顺序对所合成的杂多配合物的^183WNMR谱予于指认,确定了合成化合物的基本结构。  相似文献   

4.
用嵌入改性法合成了10种通式为K15H2[Ln(P2W16MoO61)2]·nH2O,Ln=(La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Yb)的新型稀土杂多化合物,通过元素分析、IR和UV测定,证明所合成的10种化合物同属于Dawson结构,利用TG-DTA及变温IR技术考察了该系列化合物的热稳定性.  相似文献   

5.
利用控制电位电解的方法合成了8种未见文报道的Dawson结构的钨砷稀土杂多蓝:Ln2H2As2W18O62·xH2O(2e杂多蓝)和Ln2H4As2W18O62·xH2O(4e杂多蓝),其中Ln=La,Ce,Pr,Nd。通过红外光谱,紫外光谱,极谱,光电子能谱、顺磁共振,热重-差热重对其进行了表征,并进行了结构和性质的研究。结果表明,还原前后杂多酸盐的结构虽有轻微的变化,但热稳定性和在溶液中的稳定  相似文献   

6.
过渡金属取代的钨磷杂多配合物的导电性及磁性   总被引:7,自引:1,他引:6  
杂多化合物具有独特的结构和优异的性能,在催化、热稳定性、抗病毒等方面有广泛用途.我们曾报道了取代型钨像杂多化合物[1]以及钨硅杂多化合物[2]的导电性和磁性,在本文研究了取代型钨磷杂多配合物的导电性和磁性.过渡金属的钨磷配合物热稳定性好,导电能力强,且具有磁交换作用,是一类新型的有实用前景的无机分子功能材料.1实验部分 所用仪器为:U.S.A BIO-RAD FIS-7, Leeman ICP发射光谱仪,CAHN—2000磁天平(美国CHAN公司),ER 200—D—SRC 10/12电子顺磁共振仪(…  相似文献   

7.
合成了三种通式为(ET)11「P2M18O62」,的Dawson-Wells结构杂多荷移跃迁盐。用元素分析,IR,Uv-vis,^31P NMR,EPR,磁化率和电导率等物理2测试手段进行了表征和性质研究,显示具有不同的磁行为。  相似文献   

8.
合成了具有Dawson结构的钼钒磷杂多酸,并将其转变为相应的十六烷基吡啶盐,利用IR,CV,31PNMR,UV等手段进行表征.讨论了钒取代后杂多化合物的结构特征.  相似文献   

9.
首次合成了具有Dawson结构的钨钛砷三元混配杂多配合物。用元素分析和热重分析确定了杂多配合物的组成为K_8[As_2W_(17)TiO_(62)]·10H_2O。采用X—射线衍射、红外光谱、紫外光谱、循环伏安、差热等方法系统地研究了它的结构和光谱性质、氧化还原性和热稳定性,结果表明,Dawson结构钨钛砷杂多配合物较K_(10)As_2W_(17)O_(61)·20H_2O杂多配合物有强的氧化性和热稳定性性。  相似文献   

10.
在H2O/CHCl3体系中,由5-磺基水杨酸的存在与否分别合成了茜素红二茂钛配合物。结果发现,5-磺基水杨酸对两相法合成茜素红二茂钛配合物有明显催化作用。所得化合物经元素分析、IR、X衍射及热重分析等确定了结构,在配合物结构中,茜素红配体中的两个羟基氧均与钛键合,形成五元环状二茂钛配合物,且化合物中还存在两个结晶水。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of  相似文献   

20.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

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