工具钢表面激光熔覆耐磨性试验研究

使用5kWCO2激光器对9SiCr工具钢表面进行Co基和Ni基合金熔覆处理·利用销盘式摩擦试验机对激光熔覆表面和Q235配副进行干摩擦和油润滑试验,通过扫描电镜研究了熔覆层表面磨损形貌并分析了干摩擦和润滑条件下磨损机理·试验结果表明,熔覆区磨损形式主要是磨粒、粘着磨损·干摩擦时,Ni合金熔覆层比Co合金耐磨性要好;润滑条件下,两种合金的耐磨性比干摩擦时都有很大提高     

H13钢表面激光熔覆Ni60A合金组织及性能分析

利用HUST-5000横流CO2激光器在H13热作模具钢表面制备了Ni60A镍基合金涂层。采用金相显微镜和XRD等对熔覆层的微观组织及成分进行了分析,利用显微硬度仪和磨损试验机分别测试了熔覆层的显微硬度和耐磨性能。分析表明,激光熔覆层与基体形成了良好的冶金结合,熔覆层的组织主要由FeNi3、Ni2Si和γ(Fe-Ni)等相组成;熔覆层显微硬度HV0.2在800~900之间,明显高于H13钢基体的硬度。摩擦磨损试验表明,在相同的条件下,熔覆层的耐磨性能是基体的2倍多,且随载荷的增加,磨损量的变化较小。     

WC含量对铁基复合涂层组织与磨损性能的研究

为了解决导辊零部件表面易磨损失效问题,采用激光熔覆在GCR15轴承钢表面制备了不同WC含量铁基复合熔覆层.分别通过SEM、EDS、XRD和磨损试验机对熔覆层微观组织、元素分布、物相组成和耐磨性能进行分析.结果发现,WC的添加量对合金熔覆层组织及性能影响较大.熔覆层与GCR15轴承钢基材冶金结合良好,熔覆层组织主要由胞状晶和等轴树枝晶组成,物相以Fe_3W_3C、Fe_2W_2C为主.熔覆层平均显微硬度随WC含量的增加而增加,其中WC含量为质量分数50%的熔覆层平均显微硬度最高,约为基材的3倍.在耐磨性能方面,磨损机理主要为磨料磨损和氧化磨损.随着熔覆层WC质量分数的增加,磨损量先减小后变大,WC含量为质量分数30%的熔覆层耐磨性能最佳.     

TC4合金氩弧熔覆TiN复合涂层的组织及耐磨性

为提高钛合金表面性能,以TiN粉和Ti粉为原料,利用氩弧熔覆技术,在TC4合金表面成功制备出TiN增强Ti基复合涂层。采用扫描电镜、X射线衍射仪分析了熔覆涂层的显微组织和物相组成;利用显微硬度仪、摩擦磨损试验机测试了复合涂层的显微硬度和室温干滑动磨损条件下的耐磨性能。结果表明:氩弧熔覆涂层组织均匀致密,熔覆层与基体呈冶金结合,熔覆涂层主要由TiN棒状树枝晶和TiN颗粒组成,复合涂层明显改善了TC4合金的表面硬度,涂层的最高显微硬度可达9.5 GPa;复合涂层在室温干滑动磨损实验条件下具有优异的耐磨性,磨损机制主要是磨粒磨损,其耐磨性较TC4合金基体提高近9倍。     

碳钢表面激光熔覆镍基合金涂层及其高温磨损行为

应用激光熔覆法,采用镍基NiCrSiB合金粉末,在20#碳钢表面制备了熔覆涂层.利用X射线衍射仪分析熔覆层的相组成;利用摩擦磨损实验机对熔覆层的高温耐磨性能进行了研究;利用扫描电镜观察熔覆层形貌.结果表明:所制得熔覆层组织均一、致密,与基体形成了良好的冶金结合.镍基合金激光熔覆层硬度提高到基体的4倍;高温磨损率约为基体的1/3.熔覆层耐磨能力增强的主要原因在于熔覆层与基体良好的冶金结合,固溶强化和硼化物、硼碳化物等析出相的强化作用.     

碳纳米管对Ni60合金激光熔覆层的耐磨性影响

采用激光熔覆技术,在45#钢表面进行了镍基合金粉末添加碳纳米管的熔覆试验,对熔覆层横截面进行了硬度测试和显微组织分析,对熔覆层表面进行了X射线衍射物相分析和摩擦磨损试验.结果表明,碳纳米管能够提高镍基合金激光熔覆层的硬度和耐磨性能,当碳纳米管的质量分数为0.4%时,镍基合金激光熔覆层的耐磨性能最好.     

镍基激光熔覆层腐蚀磨损交互作用

采用CO2激光器在5Cr21Mn9Ni4N不锈钢表面制备了含CeO2的镍基激光熔覆层,并对不同成分的激光熔覆层进行动态腐蚀试验、动态磨损试验和腐蚀磨损双重影响试验.分析讨论CeO2、冲击速度、硫酸介质浓度和石英砂浆对镍基激光熔覆层动态腐蚀速率、动态磨损速率和腐蚀磨损速率作用的影响.在腐蚀磨损中,腐蚀和磨损共同作用、相互增强,熔覆层的抗腐蚀磨损作用的性能与熔覆层的耐磨性、耐蚀性的综合性能相关.     

氩弧熔覆原位合成ZrC-TiB2/Fe基复合涂层组织与耐磨性

为提高钢材料表面性能,以Ti、Zr、B4C和Fe等粉末为原料,采用氩弧熔覆技术,在Q345D钢表面制备出原位合成ZrC和TiB2颗粒增强Fe基复合涂层。利用扫描电镜、X射线衍射仪、显微硬度计和滑动摩擦磨损实验机研究了熔覆层的显微组织、硬度和耐磨性。结果表明:熔覆层组织由方块状ZrC颗粒、长条状TiB2颗粒和α-Fe基体组成;熔覆层与基体呈冶金结合,界面洁净无裂纹、气孔等缺陷;熔覆层平均硬度(HV)为14 GPa;在室温干滑动摩擦磨损实验条件下,其耐磨性约为基体的18倍。该研究为原位合成ZrC和TiB2提供了新方法。     

La2O3对Ni基合金激光熔覆层组织和耐磨性的影响

在Ｎｉ基自熔合金粉末中添加不同量的Ｌａ２Ｏ３,并利用激光形成熔覆层。利用扫描电镜、Ｘ射线能谱仪、Ｘ射线衍射仪、显微硬度计和环块摩擦磨损实验机等对激光熔覆层显微组织、化学成分、相结构、显微硬度和摩擦磨损性能进行了研究。结果表明,在激光熔覆层中添加Ｌａ２Ｏ３能细化和净化显微组织;降低基材对熔覆层的稀释率;减小固溶体的晶格常数;提高熔覆层的显微硬度;降低熔覆层摩擦系数并提高其耐磨性能。该文还探讨了Ｌａ２Ｏ３作用的机理。     

等离子熔覆Ni基耐磨涂层制备及摩擦学性能

以商用WF260合金粉末为原料,采用等离子熔覆技术在20钢表面制备镍(Ni)基耐磨涂层。在室温干摩擦条件下,采用MM-200型摩擦磨损试验机测试涂层的摩擦磨损性能。采用扫描电镜(SEM)、能谱仪(EDS)及X射线衍射仪(XRD)等对涂层的微观结构和组织成分进行了表征。研究结果表明:所制涂层呈层片状分布,与基体的冶金结合良好,表面存在孔隙现象。组织中存在大量的树枝晶,等离子熔覆层中主要物相为γ-(Ni,Fe)、(Fe,Cr,Ni)mCn、Cr_2Ni_3、BPO_4及Fe_5C_2。20钢的磨损率为1. 90 mm~3/min,涂层的磨损率为0. 26 mm~3/min,大幅改善了基体的耐磨性。涂层的磨损机制为磨粒磨损以及氧化磨损,其主要强化机制为弥散强化和固溶强化。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the     

An affordable accurate evaluation of the binding conformations predicted by molecular docking studies in bio-system

Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with     

Journal of Donghua University ( English Edition) Contents of Volume 31

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