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1.
作者首次发现了Si3N4-MgO-CeO2系陶瓷在烧结过程中玻璃相自动析晶这一独特现象.对于Si3N4-MgO-CeO2系陶瓷在1450℃,MgO-CeO2就会与Si3N4颗粒表面的SiO2反应形成硅酸盐液相,冷却后则成为玻璃相保留在烧结体中;当烧结温度高于1550℃时,作者发现,CeO2仍留在玻璃相中,但MgO会自动析晶出来,其结果是大大减少了烧结体中严重影响其高温性能的玻璃相的含量,对于提高烧结氮化硅陶瓷的高温性能有重要作用 相似文献
2.
Al2O3—ZrO2—SiC陶瓷的快速烧结与力学性能 总被引:1,自引:0,他引:1
研究反应结合Al2O3-ZrO3-SiC复合陶瓷的快速烧结工艺和力学性能,讨论反应结合过程及物相变化,快速烧结是抑制晶粒生长,获得均匀,细微,致密结构有效途径No.3复合陶瓷在1550℃经10min的快速烧结,材料的力生能达到了较好水平,经度555MPa,断裂韧性3.6MPa.m^1/2维氏硬度17.1GPa。 相似文献
3.
复合稳定ZrO2在高温热处理过程中,发生立方相向四方相的相变,由于Y2O3或Ce2O3和MgO的复合稳定作用,相变过程产生大量介稳的t-ZrO2析出体。可相变四方相含量随热处理时间而增加,其中外2mol%Y2O3的(Y,Mg)-PSZ/MgAl2O4材料处理至800h仍未降低。热处理过程中Y2O3和Ce2O3始终存在于晶格中稳定ZrO2.复合稳定剂充分体现了对立方和四方相的稳定作用,多元PSZ的稳 相似文献
4.
合成了新型蓝色光致发光材料Ca8Mg(SiO4)4Cl2:Ce(3+),并对其进行了光谱测试.分析了Ce(3+)在Ca8Mg(SiO4)4Cl2晶体中应占据的晶体学格位.测试结果表明,在紫外光激发下,Ca8Mg(SiO4)4Cl2:Ce(3+)的发射光谱为一峰位在410nm~425nm之间的宽谱带,经分析确认作为发光中心的Ce(3+)占据Ca8Mg(SiO4)4Cl2晶体中多面体八配位的Ca(Ⅱ)格位. 相似文献
5.
实验研究CaO-MgO-SiO2熔块对Al2O3瓷烧结的作用结果表明:在20%wt%CaO,30wt%MgO,50wt%SiO2区域附近的熔块能很好地促进Al2O3瓷的低温烧结;除了第2相对晶界的钉扎作用以及固溶作用外,MgO在烧结中的作用能维持CaO/SiO2比,即维持烧结系统中的液相量;La2O3,Sm2O3能使Al2O3瓷的烧结温度下降大约30℃,其表面显微结构也有所改善。 相似文献
6.
研究了烧结温度和时间对Fe-3.1Mn-1.2Si-0.4C烧结刚性能与组织的影响,实验结果表明:提高烧结温度和延长烧结时间都能改善Fe-3.1Mn-1.2Si-0.4C烧结钢的机械性能;并使烧结试样由膨胀逐渐向收缩过渡,Fe-3.1Mn-1.2Si-0.4C烧结网在1100℃以上烧结时,由于有液相的出现,合金化过程可以被大大地提高,在烧结过程中,只有那些较小的硅锰母合金颗粒才能全部熔化,而那些尺 相似文献
7.
1,2-二环戊二烯基四甲基二硅烷与丁基锂作用生成[四甲基二硅撑]双(环戊二烯基负离子盐),后者随即与六羰基钨反应形成1,1-[四甲基二硅撑]双[环戊二烯基三羰基钨负离子盐],(Me2SiSiMe2)·[Cp′(CO)3W-]2·2Li+(I).(I)分别与六种卤化物反应,生成在钨原子上引入取代基的产物:(Me2SiSiMe2).[Cp′W(CO)3R]2,(R:Me,C2H5,2;PhCH2,3;CH2COOC2H5,4;CH3CO,5;P3hSn,6).(I)用醋酸处理后,随即分别与CCl4,NBS及I2作用,生成相应的钨卤化物,(Me2SiSiMe2)[Cp′W(CO)3X]2,(X:C1,8;Br,9;I,10),(I)与Fe3+/H3O+作用发生氧化偶联,生成双核W-W键产物(Me2SiSiMe2)[Cp′W(CO)3]2,11.(Cp′=C5H4) 相似文献
8.
MgO-B2O3-SiO2三元系1000℃时,35%≤MgO%〈60%组成范围内平衡相均为固相,其相关系可由Mg3B2O6-Mg2SiO4-Mg2B2O5,Mg2B2O5-Mg2SiO4-MgSiO3,Mg2B2O5-MgSiO3-SiO2三个结线三角形表示。各平衡相量之间关系可应用XRD定量相分析或重心规则计算。 相似文献
9.
B2O3—MgO—SiO2—CaO—Fe3O4系固结块的抗压强度和还原性 总被引:2,自引:0,他引:2
用五因子回归正交设计法对B2O3-MgO-SiO2-CaO-Fe3O4五元系的抗压强度、还原性同组分、温度的关系做了系统的研究,建立了抗压强度、还原率两指标同B2O3,MgO,SiO2,CaO/SiO2,t因素的二次回归数学模型,B2O3对还原性影响不大,而对抗压强度影响显著,当B2O3含量为4-6%时,抗压强度最大,MgO增加还原性降低,但对抗压强度影响不大,随着温度上升,抗压强度和还原性均降低 相似文献
10.
GPS ZrO2(Y-TZP)-Si3N4复合材料的显微结构 总被引:2,自引:0,他引:2
采用透射电镜和扫描电镜对气氛加压烧结(GPS)和ZrO2(Y-TZP)-SiN4复合材料的显微结构进行了研究,发现主晶相β-Si3N4中普遍存在位错,但分散于氮化硅基体中的ZrO2对位错有钉扎作用;并且发现ZrO2(Y-TZP)-Si3N4复合材料中存在晶界玻璃相结晶化现象。 相似文献
11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness. 相似文献
12.
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly. 相似文献
13.
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well. 相似文献
14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation. 相似文献
15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。 相似文献
16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death. 相似文献
17.
Miao Maosheng 《华南师范大学学报(自然科学版)》2014,(6)
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula- 相似文献
18.
Yang Weitao 《华南师范大学学报(自然科学版)》2014,46(6):137-138
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re- 相似文献
19.
Bernard Kirtman 《华南师范大学学报(自然科学版)》2014,(6)
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that 相似文献
20.
《上海师范大学学报(自然科学版)》2014,(5):550
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with 相似文献