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1.
用表面张力方法研究了有机电解质四乙基溴化铵((Et)4NB)对离子型表面活性剂SDS和DTAB胶束化行为的影响,并与无机电解质NaBr的结果比较.实验结果表明,(Et)4NB促进SDS胶束化的能力强于NaBr;但促进DTAB胶束化的能力与NaBr基本一样.这说明:(Et)4N+与SDS胶束间除了相反电荷静电吸引外,其乙基和表面活性剂碳氢链间还具有弱疏水相互作用,两者结合使(Et)4N+嵌入SDS胶束离子头基中;这种疏水作用强度不及静电力,在静电排斥下,(Et)4N+乙基和DTA+碳氢链间疏水相互作用未能发生.  相似文献   

2.
项明  周建 《贵州科学》1998,16(1):1-8
用乙基碳化亚二胺(EDC)、二乙基焦碳酸(DEPC)、磷酸吡哆醛(PLP)、过氧化氢(H2O2)、三硝基苯磺酸(TNBS)、对氯汞苯甲酸(PCMB)、N-经琥珀酰亚胺(NBS)、碘乙酸(IAC)和二硫基二硝基苯甲酸(DTNB)分别对禾黑 霉本的三种果胶裂解酶(PⅠ,PⅡ,PⅢ)进行了化学修饰,紫外可见光谱的实验结果证明,各种试剂都与果胶酶氨基酸特定残基共价结合,大多数氨基酸残基的化学修饰对果胶酶的  相似文献   

3.
以市售鱼为原料,进行其高温激活蛋白酶(HTAP)的提取纯化通过抽提、高速离心分离、DEAE-TOYOPEARL650M离子交换色谱、SEPHACRYLS200凝胶过滤等方法,把HTAP从鱼中分离提取出来运用SDS-聚丙烯酰胺凝胶电泳(SDS-PAGE)法对分离提纯的HTAP纯度进行鉴定,并通过此法测出了该HTAP的分子量为39000  相似文献   

4.
可聚合性季铵盐及其聚合物的合成与表征   总被引:1,自引:1,他引:0  
合成了三种含不饱和双键和季铵盐:甲基丙烯酰氧乙基-苄基-二甲氯化铵(MB-DAC),甲基丙烯酰氧乙基-丁基-二甲基溴化铵(MBDAB)和甲基丙烯酰氧乙基-乙基-二甲基溴化铵(MEDAB),用红外光谱,元素分析,核磁共振谱对其结构进行了表征。用自由基聚合法合成了MBDAC的均聚物及其与甲基丙烯酸甲酯和苯乙烯的共聚物,并用元素分析、GPC,红外光谱等表征了聚合物的结构,用DSC和TG研究了其热稳定性,  相似文献   

5.
浅论高校教师业务档案的建立与管理   总被引:1,自引:0,他引:1  
浅论高校教师业务档案的建立与管理童晓风(浙江水产学院院长办公室,舟山316101)ONESTABLISHMENTANDMANAGEMENTOFEDUCATIONALDOCUMENTSFORCOLLEGETEACHERSTongXiaofeng(ZhE...  相似文献   

6.
THERISEANDDECLINEOFTHEUNITEDSTATESSHIPPINGANDSHIPBUILDINGINDUSTRIES¥(CaptainJamesS.C.Chao,DCS,LL.D.JohnJ.Clark,Ph.D.)Abstract...  相似文献   

7.
在较强的酸性介质中加入硫脲将大量Cu2+ 掩蔽,然后加过量EDTA加热使Sn4 + 定量络合用六次甲基四胺调整酸度至pH=55 ,以二甲酚橙做指示剂用硝酸铅溶液滴定过量的EDTA,然后加氟化钠将Sn- EDTA中的EDTA 析出,再用硝酸铅溶液滴定此析出的EDTA以计算锡的含量  相似文献   

8.
漳泽水库的绿藻植物   总被引:3,自引:1,他引:3  
漳泽水库的绿藻植物谢树莲张瑜娥*李晓红*(山西大学生命科学系,太原030006)CHLOROPHYTAOFTHEZHANGZERESERVOIRXieShulianZhangYueLiXiaohong(DepartmentofLifeScience,...  相似文献   

9.
制备了5′端共价连接EDTA的寡聚核苷酸与生命金属的螯合物ODN-5′-EDTAM(n+),其中M(n+)为Fe(Ⅱ),Co(Ⅱ)或Cu(Ⅱ);分析、计算了这3个螯合物形成的最佳pH值范围,ODN-EDTAFe(Ⅱ)为pH5.8~8.6,ODN-EDTACo(Ⅱ)为PH4.6~8.1,ODN-EDTACu(Ⅱ)为pH3.4~5.7;在此条件下,剪切反应必须的Mg2+并不与Fe(Ⅱ),Co(Ⅱ)或Cu(Ⅱ)竞争EDTA,也不会形成沉淀;讨论了ODN-EDTAM(n+)切割DNA双链的反应机理:修饰寡核苷酸通过氢键在DNA双链的大沟结合形成三链体,在O2和还原剂DTT作用下,Fe作为催化剂,产生羟基自由基,氧化糖环,切割EDTAFe(Ⅱ)附近的DNA双链.  相似文献   

10.
首次制得二乙基胺甲基膦酸锆-亚磷酸锆Zr(HPO_3)_(2-x)·(O_3PCH_2NEt_2)_x·H_2O(ZDEAMP-ZP,x=0.75,0.60,0.50).将ZDEAMP-ZP用溴化苄季铵化,得到部分季铵化的产物:溴化苄基二乙基铵甲基膦酸锆-二乙基胺甲基膦酸锆-业磷酸锆Zr(HPO_3)_(2-x)·(O_3PCH_2NEt_2)_(x-y)·(O_3PCH_2N ̄+Et_2·CH_2Ph·Br ̄-)_y·H_2O(Y<X,ZBDEAMPB-ZDEAMP-ZP).ZBDEAMPB-ZDEAMP-ZP用于进行液/固/液或固固/液三相催化的亲核取代成醚、卤代烃和羧酸盐合成酯及二氯卡宾加成反应,均得到良好的结果。催化剂易于分离和回收,通常回收70%~100%,催化剂重复使用10次以上无明显失活。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of  相似文献   

20.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

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