聚氨酯涂层剂湿热活性分析及防水透湿性能的研究

通过扫描电镜（SEM）、差热分析（DSC）、透湿杯法测量等手段，对合成的PU涂层膜及涂层布进行了一系列观测，推断该涂层是属于无微孔亲水性透湿。透湿量大小取决于亲水基的含量。观察到织物透湿量随环境温度的升高而增加，这种变化对应于聚合物中PEG，PTMG组分的相变区，有一定的热效应。这种性能可赋予织物“防水透湿调温”功能，明显增加织物服用舒适性。     

Gore-tex防水透湿层压织物的概述

介绍了各类防水透湿织物的种类、性能及研究发展状况,着重叙述了商品名为Gore-tex的PTFE微孔膜层压织物,并提出了存在的问题.     

防水透湿层压复合织物粘合和固化工艺的研究

研究了采用湿固化聚氨酯热溶胶生产防水透湿层压复合织物的粘合及固化工艺.结果表明,较为理想的工艺是:转移温度为湿固化聚氨酯在粘度为10 000 mPa.s时所对应的温度93℃,车速为10～20 m/min,固化温度在30℃以上,湿度在90%以上.     

聚氨酯微孔膜的防水透湿性及电镜分析

以聚氨酯微孔膜的电膜照片，分析在不同组成和不同的成型条件下制取的膜的结构和性能，得到了采用配比为１０／０５／０５的ＮＮ二甲基甲酰胺／四氢呋喃／乙二醇的混合溶剂和高温分级快干条件下形成的ＰＵ膜．该膜具有细密微孔结构和优良的防水透湿性     

Coolmax织物导湿性能研究

对Coolmax织物的导湿性能进行研究，设计了10种织物试样，分别测试它们的吸湿排汗能力、透湿率、带液率、干燥速率，讨论了同组织结构不同Coolmax含量及紧度对织物导湿性能的影响。     

聚氨酯涂层织物单缝法撕裂性能的研究

对18种不同规格基布的聚氨酯涂层织物，用一般多元线性回归和逐步回归方法，研究了纱线性能和织物结构指标等因素与单缝法撕裂强力间的关系。分析计算表明：影响单缝法经向撕裂强力的主要因素是经纱强力，其次是经纱从涂层织物抽出时的抽出阻力、纬密和经密，而经纱断裂伸长率和其他因素的影响则较小。     

聚氨酯涂层织物撕裂强力的研究

对12种不同规格的涂层织物，采用4种不同撕裂方法进行撕裂强力的测定，得到了不同撕裂方法测得的撕裂强力之间的相关关系，同时讨论了涂层及涂层工艺对织物撕裂强力的影响。在前人的机织物撕裂强力模型的基础上，得到了涂层织物梯形法撕裂强力的理论表达式，并对梯形法撕裂强力的理论值和实测值进行了比较和影响因素的分析，实验表明该理论表达式对涂层织物撕强值的预测有较好的效果。     

壳聚糖整理羊毛织物透湿性能研究

使用双氧水在超声波辅助条件下制备了不同分子质量的壳聚糖,用黏度法测定了分子量,并对羊毛织物进行整理.借助SEM、FTIR分析羊毛纤维表面形貌和结构,并测试了羊毛织物透湿性能.结果表明,借助柠檬酸的桥梁作用,壳聚糖和羊毛纤维发生了化学反应.当壳聚糖分子质量为5×104、质量分数为1%时处理羊毛织物,其透湿性能最好.     

水分散聚氨酯阴离子体涂层行为的研究

本文研究了水分散聚氨酯阴离子体涂层剂的聚集状态与性能的关系,特别是对影响织物涂层的主要因素作了探讨。本文在下列几个方面作了研究:(1) PU(聚氨酯,Polyurethane)阴离子体与HPAM(水解聚丙烯酰胺,Hydrolyzed polyacrylamide)共混二相结构对玻璃化温度T_g及透湿量的影响;(2) PU大分子(AB)_n型结构对力学性能及涂层性能的影响;(3) 交链剂的交链行为;(4) 离子化度对贮存稳定性的影响。此外,在研究PU阴离子体涂层性能的控制因素方面提出了新的见解,即调节PU阴离子体中硬段含量可获得透湿性强且弹性好的涂层织物。     

大麻织物的舒适性能研究

通过织物的透气、透湿及毛细效应等实验对大麻织物的舒适性能进行研究并与苎麻、亚麻织物进行比较,认为大麻织物在透湿性和毛细效应等方面有较大优势,在易出汗的夏季,大麻面料着装比较舒适.     

Condensation of Water Vapor on Waterproof Breathable Fabrics

Condensation occurs when the local vapor pressure rises above the saturation vapor pressure at the local temperature in theory. A new measuring apparatus were made to obtain temperature and relative humidity simultaneously for the purpose of investigating the mechanism of condensation occurred on the fabrics. The experiment conducted at the standard condition of temperature of 20℃ and relative humidity of 65%. The result obtained from experiment showed that condensation could occur under the situation closed to saturation line as the temperature on fabric may be lower than dew point of water vapor in the measuring box depending on the experiment conducted at an ambient environment temperature of 20℃ The range of fabrics studied showed that PTFE laminated fabrics except nylon gingham PTFE laminated fabric facilitates the loss of water vapor and therefore prevent condensation. It is necessary to develop studies from a wide range of fabrics, especially breathable fabrics and under bad experiment conditio     

浅谈DL纳米改性聚氨酯防水材料在工程中的应用

针对厨房、卫生间屋顶长期漏水的难题，研究了一种将DL纳米改性聚氨酯防水材料的理论与实践、技术与操作成功地融为一体，从而形成完整的施工过程的质量控制方法，并对DL纳米改性聚氨酯防水材料在工程中的应用情况做了具体介绍。     

Method of Stabilizing the Surface Energy of Fabrics Coated with Silicone

Silicone coatings have been used in this study. The method adopted was the liquid drop analysis on the coated fabrics. The contact angle between a liquid drop and the fabric surface was measured with two liquids continuously and recorded by a computer. The surface energy was calculated by means of Owens method. Kinetic measurement was adopted. The contact angle of liquids on the fabric coated silicone decreased with time was found. A compound solution DX has been found, so that the contact angle of the liquids on the fabric washed with DX becomes constant, and the surface energy of the fabric can be reduced to below 15 mJ/m2.     

A Novel Aqueous Polyurethane Containing Short Fluoroalkyl Chains： Synthesis and Application on Cotton Fabrics

IntroductionFluorinated coatings are the most i mportant class ofwater and oil repellent finishing agents for textiles due totheir opti mum perfor mance in lowering the surface freeenergy[1]and i mproving both hydrophobicity andoleophobicity . But in recent years , the fluorocarbonscontaining long perfluoroalkyl chains are facing theproblems such as the persistence ,bioaccumulation,and/ortoxicity in environment and some of them have beenbanned fromthe market[2]. Thus , many efforts have beenma…     

Novel Waterborne Fluorinated Polyurethane Containing Fluoroalkyl Side Chain:Synthesis,Characterization and Application on Cotton Fabric

A polyether diol poly[3-bromomethyl-3-tridecafluorooctyloxymethyloxetane]glycol(PFBOX 3) was prepared in 91% yield from ring opening polymerization of 3-bromomethyl-3-tridecafluorooctyloxymethyloxetane 2 which was derived from 3,3-dibromomethyloxetane 1 and 1H,1H,2H,2H-perfluorooctanol.The waterborne fluorinated polyurethane FPU was thus obtained by condensed polymerization of PFBOX 3 with isophoronediisocyanate(IPDI).The structure of FPU was characterized by Fourier transform infrared spectrometer(FTIR).FP...     

负载纳米TiO2的纯棉抗菌织物

在室温条件下采用射频磁控溅射方法,在纯棉机织物表面沉积TiO2功能纳米结构层.利用原子力显微镜和X射线衍射仪分别分析其表面形貌和晶态结构,同时对负载纳米TiO2织物的抗菌性和耐洗性进行了初步研究.实验表明,在拟定的溅射工艺条件下,纯棉机织物表面沉积了晶粒较为均匀、粒径较小的锐钛矿型纳米TiO2功能结构层,这一功能层使负载织物呈现出优良的抗菌性能;同时负载织物具有良好的耐洗性,经30次洗涤后,其抗菌性能仍保持在很高的水平.     

Study on a New Method of Reducing the Water Shrinkage of Rabbit Hair Knitted Fabrics

Introduction Rabbithair,asakindofvaluableanimalfibers,has manygoodpropertiessuchasbulk,whiteness,lightness,smoothandgoodwarmthretentionandsoon.Withthe developmentoftextileindustry,theapplicationofrabbit hairscontinuestoexpandandgainmoreandmoreattentions.Productsofhighpercentrabbithairsseemmoreluxurious.However,thereisalayerofscalesonthesurfaceasother animalfibers,fabricsmadeofrabbithairsoftenshrink afterwashing,whichdecreasesthedimensionalstabilityof fabrics,andmakesdailycaredifficult.Inaddit…     

水性隔热防水膏的研制及性能测定

为了解决隔热防水粉在防水施工中存在的问题,研制了水性隔热防水膏,介绍了水性隔热防水膏的制造、防水隔热机理及其主要性能的简易测试方法．结果表明,水性隔热防水膏具有湿法施工、不怕风吹、不起灰的特点,适于平面、斜面和立面的防水施工,其防水隔热性能与隔热防水粉相同,而且克服了隔热防水粉在防水施工中存在的困难．