级配碳化硅/环氧树脂复合材料冲蚀性能研究

该文主要研究了碳化硅/环氧树脂复合材料的冲蚀磨损性能,分析了颗粒级配搭配对于复合材料耐冲蚀性能与力学性能的影响,并且讨论了冲蚀磨损机理以及偶联剂对于复合材料体系的作用。为了获得最优的耐冲蚀性能,利用田口法设计了实验,对级配颗粒结构进行了优化。结果表明：级配颗粒搭配具有增加硬质点、提高密度、降低磨损率的作用,当级配体系为70%550μm、30%110μm时,试验固相含量高。耐冲蚀效果较好。     

亚微米SiCp/Al复合材料的磨损性能

以亚微米级（130nm）SiCp和100—200目（149—75μm）Al粉为原料,采用冷压烧结和热挤压方法制备出不同体积分数的微米SiCp增强Al基复合材料,并在油润滑条件下,对其滑动磨擦特性进行了研究．结果表明i在较高载荷下,体积分数为1．5％和5．0％的SiCp／Al基复合材料具有优异的滑动磨损抗力,且随SiCp含量增加,复合材料的耐磨性能提高,耐磨性可迭市售挤压态锡青铜QSn6．5—0．4的1．21和4．06倍、纯Al的1．10和3．66倍;其磨损表面和次表面在摩擦推挤形变的作用下形成了Al基体＋孔隙＋尺寸适中、近球状、弥散分布SiCp的理想耐磨减摩组织．     

不同颗粒增强铁基复合材料磨损性能的对比

采用动态电流直加热制备,提出了分段加热工艺,研究了陶瓷颗粒增强铁基复合材料的磨损性能和磨损机理.结果表明:四种不同颗粒增强铁基复合材料的磨损量均在#45钢磨损量的15%以下;Ti(C,N)对改善材料磨损性能作用最强,表明与基体界面可经受一定变形量的强化粒子最有利于提高耐磨性;复合材料的耐磨性均在强化粒子体积分数为10%时达到最好.铁基复合材料表现出高摩擦系数时耐磨性反而更好的特性,在耐磨材料应用方面显示出巨大优势.     

磨粒粒径对Si3N4结构陶瓷冲蚀磨损性能的影响

以冲蚀磨损工况下的典型应用材料Cr15Mo3高铬铸铁为对比材料,采用转盘式液-固双相流试验机研究了不同SiC磨粒粒径对Si3N4结构陶瓷抗冲蚀磨损性能的影响,分析了试验材料冲蚀磨损的微观失效机制.研究结果表明:在各种粒径磨粒的冲蚀磨损条件下,Cr15Mo3铸铁的冲蚀磨损率都比Si3N4结构陶瓷的高,Si3N4结构陶瓷的抗冲蚀磨损能力是Cr15Mo3铸铁的20倍左右;粗颗粒磨料冲蚀条件下试验材料的体积损失比细颗粒磨料冲蚀条件下的大,即磨粒越粗冲蚀磨损越严重;在微观上,Cr15Mo3的腐蚀坑、冲蚀坑多,基体材料冲刷磨损严重,W型失效形貌明显,而Si3N4结构陶瓷的冲蚀磨损面比较光滑,材料失效主要是晶界粘结相失去多所致;结构致密、晶粒细小并有细小柱状晶的存在等是Si3N4结构陶瓷抗冲蚀磨损性能优异的主要原因.     

铸造碳化铬增强锰白铜基复合材料磨料磨损机理

采用真空熔铸法制备铸造碳化铬增强锰白铜基复合材料,对铸造锰白铜时效处理后,在ML10型磨损试验机上选用不同粒度的SiC砂纸和不同载荷进行磨损试验,研究了材料的二体磨料磨损机理.结果表明:铸造碳化铬增强锰白铜基复合材料的耐磨性随着载荷和磨料粒度的增加而降低;在相同试验条件下,耐磨性随着碳化铬颗粒体积分数和碳化铬颗粒尺寸的增大而提高;碳化铬颗粒尺寸相对较大时,其磨损以局部断裂为主;碳化铬颗粒尺寸相对较小时,碳化铬颗粒的磨损主要以整体脱落形式进行.     

纳米SiC含量对Ti3SiC2/Al复合材料摩擦磨损特性的影响

采用SPS方法制备出SiC和Ti3SiC2双相增强Al基复合材料,并在MM-200型摩擦磨损实验机上进行干摩擦试验。研究了不同含量SiC对Ti3SiC2/Al复合材料组织及耐磨性的影响,结果表明,颗粒体积分数及磨损载荷对复合材料摩擦磨损特性有显著影响。复合材料具有良好的摩擦磨损性能,烧结温度为550℃,SiC的体积分数从0.5%上升到2%时,复合材料的摩擦系数从0.34降到0.285,降低16.2%。烧结温度为400℃,SiC的体积分数从0.5%上升到2%时,复合材料的磨损量从0.0079降到0.0039,降低50.63%。     

树脂基复合材料身管热性能改良分析

该文根据复合材料细观力学模型,推导了树脂基复合材料填充金属粉末后的热导率、热膨胀系数的理论公式,从理论分析预测了金属粉末含量对复合材料身管热性能的影响,通过计算算例,检验证实了树脂基复合材料添加金属粉末后其导热性能有很大的提高,金属粉末体积分数为10％时,树脂基复合材料垂直于纤维方向热导率提高近3倍,复合材料身管的温度场能够得到很好改善。这些对复合材料身管的实际应用具有重要的参考价值。     

硬质合金颗粒增强铁基复合材料的三体磨料磨损性能

以回收的钨钴钛类硬质合金为增强颗粒,采用负压铸渗工艺制备了颗粒增强高铬铸铁基复合材料,并借助于金相分析和X射线衍射等手段研究了复合材料的微观界面.由于铸渗过程中增强颗粒的部分熔解及W、C、Co和Fe等元素的扩散,在界面处产生了Fe3 W3C、CO3W3C等化合物,形成了明显的过渡层,从而确保了增强颗粒与基体之间为冶金结合.利用三体磨料磨损试验机研究了复合材料的磨损性能,结果表明:磨损过程分为4个阶段,复合材料的体积磨损量随着磨损试验的进行先下降后上升,其中在第3阶段迭到最低值;复合材料的体积磨损量随着磨料粒度增大而逐渐增加.将制备的复合材料同工程中常用的热处理态高铬铸铁以及WC颗粒增强高铬铸铁基复合材料进行了耐磨性对比,发现其体积磨损量显著低于高铬铸铁,而与WC颗粒增强高铬铸铁基复合材料差别不大,显示出优异的性能价格比.     

SiC颗粒增强铝基复合材料断裂韧性的研究进展

介绍了SiC颗粒增强铝基复合材料断裂韧性的研究现状,着重分析了基体合金成分、SiC颗粒体积分数、颗粒粒度形貌、界面性质以及热处理工艺对复合材料断裂韧性的影响,并对SiC复合材料的研究进行了探讨和展望。     

热喷涂合金—陶瓷涂层的冲蚀特性

本文使用自制的CMS-120冲蚀磨损试验机对多种合金——陶瓷涂层的石英砂冲蚀特性进行了试验研究。研究结果表明:合金涂层中加入适当比例的硬质陶瓷颗粒可改变原涂层的抗冲蚀性能,使其同时兼备脆性材料和塑性材料的优点,即在低角冲击下,涂层呈现脆性材料的冲蚀特点,在高角冲击下又可呈现塑性材料的冲蚀特点。     

铝基颗粒复合材料与性能的研究

以硬质颗粒作为增强体的铝基复合材料,避免了纤维增强金属基复合材料制备过程中造成的纤维受损,制备工艺复杂及纤维昂贵等缺点,并可克服自生复合材料增强相的成分、形态、尺寸及相对量受到平衡相图、亚稳相图及生长动力学的严格限制,使复合材料的取材具有广泛性和灵活性,是近年来金属基复合材料的重点研究方向之一.     

Effect of Al<Subscript>2</Subscript>O<Subscript>3sf</Subscript> addition on the friction and wear properties of (SiC<Subscript>p</Subscript>+Al<Subscript>2</Subscript>O<Subscript>3sf</Subscript>)/Al2024 composites fabricated by pressure infiltration

Aluminum (Al) 2024 matrix composites reinforced with alumina short fibers (Al₂O_3sf) and silicon carbide particles (SiC_p) as wear-resistant materials were prepared by pressure infiltration in this study. Further, the effect of Al₂O_3sf on the friction and wear properties of the as-synthesized composites was systematically investigated, and the relationship between volume fraction and wear mechanism was discussed. The results showed that the addition of Al₂O_3sf, characterized by the ratio of Al₂O_3sf to SiC_p, significantly affected the properties of the composites and resulted in changes in wear mechanisms. When the volume ratio of Al₂O_3sf to SiC_p was increased from 0 to 1, the rate of wear mass loss (K_m) and coefficients of friction (COFs) of the composites decreased, and the wear mechanisms were abrasive wear and furrow wear. When the volume ratio was increased from 1 to 3, the COF decreased continuously; however, the K_m increased rapidly and the wear mechanism became adhesive wear.     

颗粒增强不锈钢基复合材料冲蚀磨损性能研究

在MMG－200高温氧化-冲刷腐蚀磨损试验机上,考察了Al     

Effect of Al_2O_(3sf) addition on the friction and wear properties of(SiC_p+Al_2O_(3sf))/Al2024 composites fabricated by pressure infiltration

Aluminum(Al) 2024 matrix composites reinforced with alumina short fibers(Al_2O_(3sf)) and silicon carbide particles(SiC_p) as wear-resistant materials were prepared by pressure infiltration in this study. Further, the effect of Al_2O_(3sf) on the friction and wear properties of the as-synthesized composites was systematically investigated, and the relationship between volume fraction and wear mechanism was discussed. The results showed that the addition of Al_2O_(3sf), characterized by the ratio of Al_2O_(3sf) to SiC_p, significantly affected the properties of the composites and resulted in changes in wear mechanisms. When the volume ratio of Al_2O_(3sf) to SiC_p was increased from 0 to 1, the rate of wear mass loss(K_m) and coefficients of friction(COFs) of the composites decreased, and the wear mechanisms were abrasive wear and furrow wear. When the volume ratio was increased from 1 to 3, the COF decreased continuously; however, the K_m increased rapidly and the wear mechanism became adhesive wear.     

氩弧熔铸TiC-TiB_2/Fe复合材料的组织与耐磨性

为改善合金材料的耐磨性能,采用氩弧熔铸技术,以Fe、Ti、B和C粉为原料,按质量分数比45∶30∶20∶5制备原位合成TiC-TiB2/Fe复合材料。通过扫描电镜、X射线衍射仪、洛氏硬度计及摩擦磨损试验机对复合材料的显微组织、物相、洛氏硬度和耐磨性进行分析研究。结果表明:复合材料由原位生成的TiB2和TiC增强颗粒相及α-Fe相组成,颗粒呈块状、板条状和多边形,且颗粒结合地很紧密。复合材料的平均洛氏硬度约为9.37 GPa。在室温干滑动磨损条件下,该熔铸复合材料的耐磨性约是GCr15工具钢的6倍。该研究为原位合成TiC-TiB2/Fe复合材料的制备提供了一种新方法。     

Effect of reinforcement content on the adhesive wear behavior of Cu10Sn5Ni/Si3N4 composites produced by stir casting

The main objective of this paper was to fabricate Cu10Sn5Ni alloy and its composites reinforced with various contents of Si3N4 particles (5wt％,10wt％,and 15wt％) and to investigate their dry sliding wear behavior using a pin-on-disk tribometer.Microstructural examinations of the specimens revealed a uniform dispersion of Si3N4 particles in the copper matrix.Wear experiments were performed for all combinations of parameters,such as load (10,20,and 30 N),sliding distance (500,1000,and 1500 m),and sliding velocity (1,2,and 3 m/s),for the alloy and the composites.The results revealed that wear rate increased with increasing load and increasing sliding distance,whereas the wear rate decreased and then increased with increasing sliding velocity.The primary wear mechanism encountered at low loads was mild adhesive wear,whereas that at high loads was severe delamination wear.An oxide layer was formed at low velocities,whereas a combination of shear and plastic deformation occurred at high velocities.The mechanism at short sliding distances was ploughing action of Si3N4 particles,which act as protrusions;by contrast,at long sliding distances,direct metal-metal contact occurred.Among the investigated samples,the Cu/10wt％ Si3N4 composite exhibited the best wear resistance at a load of 10 N,a velocity of 2 m/s,and a sliding distance of 500 m.     

冶金级氧化铝颗粒磨损指数分析

为了保证冶金级氧化铝的高效输送和加料，对氧化铝的粒径分布和抗磨损性能提出一定要求，研究和探讨了冶金级氧化铝的抗磨损性能.利用依据国家标准设计的氧化铝磨损指数测定仪，对从不同氧化铝企业采样的32种氧化铝进行了磨损前后的粒径分布测试和磨损指数计算，研究了磨损指数和粒径分布之间的关系.数据分析结果重新强调了综合考虑磨损指数和粒度分布的重要性.同时分析了铝电解干法烟气净化系统对氧化铝的磨损程度.还提出了一种衡量氧化铝粒径分布好坏的方法.     

Microstructure,mechanical properties,and wear resistance of VC<Subscript>p</Subscript>-reinforced Fe-matrix composites treated by Q&amp;P process

A quenching and partitioning (Q&P) process was applied to vanadium carbide particle (VCp)-reinforced Fe-matrix composites (VC-Fe-MCs) to obtain a multiphase microstructure comprising VC, V₈C₇, M₃C, α-Fe, and γ-Fe. The effects of the austenitizing temperature and the quenching temperature on the microstructure, mechanical properties, and wear resistance of the VC-Fe-MCs were studied. The results show that the size of the carbide became coarse and that the shape of some particles began to transform from diffused graininess into a chrysanthemum-shaped structure with increasing austenitizing temperature. The microhardness decreased with increasing austenitizing temperature but substantially increased after wear testing compared with the microhardness before wear testing; the microhardness values improved by 20.0% ±2.5%. Retained austenite enhanced the impact toughness and promoted the transformation-induced plasticity (TRIP) effect to improve wear resistance under certain load conditions.     

SiC颗粒特性对无压熔渗SiCp/Al复合材料热物理性能的影响

采用粉末注射成形-无压熔渗相结合技术制备出了电子封装用高体积分数SiCp/Al复合材料. 重点研究了SiC粒径、体积分数以及粒径大小等颗粒特性对所制备复合材料热物理性能的影响规律. 研究结果表明,SiCp/Al复合材料的热导率随SiC粒径的增大和体积分数的增加而增加;SiC粒径的大小对复合材料的热膨胀系数(CTE)没有显著的影响,而其体积分数对CTE的影响较大. CTE随着SiC颗粒体积分数的增加而减小,CTE实验值与基于Turner模型的预测值比较接近. 通过对不同粒径的SiC粉末进行级配,可以实现体积分数在53%～68%、CTE(20～100℃)在7.8×10-6～5.4×10-6K-1、热导率在140～190W·m·K-1范围内变化.