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1.
用偏最小二乘法(PLS)校正火焰原子吸收分析中Mn403.307nm对Ga403.298nm干扰。实验结果表明,PLS法是谱线重叠干扰的有效校正方法,同时预示着该法可成为用一种元素空心阴极灯同时测定谱线重叠的二种元素的分析方法。  相似文献   

2.
制备了块状的SiO2气凝胶,把具有很好电致发光(EL)和光致发光(PL)性能的8-羟基喹啉铝渗入到气凝胶的纳米孔洞中,可见-紫外吸收光谱表明8-羟基喹啉铝在SiO2气凝胶的纳米孔洞中发生了化学吸附,且吸附作用随着气凝胶密度的减小而增强:PL谱中8-羟基喹啉铝的光致发射谱峰从470nm移至450nm。  相似文献   

3.
利用金属有机气相沉积技术生长InGaAsP/InP多量子阱结构,通过改变生长程序,得到了优化的陡峭量子阱界面.并利用光致发光(PL)和X射线双晶衍射对其界面质量分析,X射线双晶衍射表明界面起伏为一个原子层厚度,在10K温度下PL谱半峰高宽(FWHM)为7meV  相似文献   

4.
研究了二氧化锡/多孔硅/硅(SnO_2/PS/Si)的光伏谱和吸附性质,由分析光伏谱得出在SnO_2/PS/Si之间存在着二个异质结:一个是SnO_2/PS异质结;另一个是PS/Si异质结,当样品吸附CO气体后,光电压明显减少,实验结果表明,利用光电压的变化可以检测CO等有害气体.本文对新气体敏感材料SnO_2/PS/Si的有关气体吸附机制进行了讨论.  相似文献   

5.
对与InP晶格匹配的InGaAsP四元系量子阱材料进行了一系列热稳定性能的研究,通过光荧光谱(PL)的测量发现:InGaAsP四元系量子阱材料在650 ℃以上的常规退火条件下有量子阱混合现象产生,而单量子阱结构较多量子阱或超晶格结构更容易产生量子阱混合.对单量子阱片进行快速退火处理后,荧光峰位置、峰宽无明显变化,表明量子阱混合的产生除了依赖于退火温度的高低,也与退火时间的长短密切相关.  相似文献   

6.
该文根据光电阴极的量子产额谱,导出了光谱响应S(λ),通过选择合适参数,计算的S20光谱响应曲线与实验基本吻合。该文也分析了阴极厚度D,阴极结构参量P,光电阴极光谱响应截止波长λ_j和光电子逸出深度L对S(λ)的影响,认为D、P和λ_j是决定S20阴极性能的主要因素。  相似文献   

7.
合成了一个苯并咪唑桥连的双核铜(Ⅱ)配合物,Na3[Cu2(NTA)2bZim]·10H2O(NTA为三乙酸三价负离子,Bzim为苯并咪唑负离子),并用元素分析,摩尔电导,UV/VIS,IR,ESR谱,进行了表征。用X-射线单晶衍射法测定了配合物的晶体结构,它属于三斜晶系,P-↓1空间群,晶胞参数a=1.0426(7)nm,b=1.2074(5)nm,c=1.4680(2)nm,a=73.62(3  相似文献   

8.
在0.16~0.32nol/L的盐酸溶液中,维多利亚蓝4R(VB4R)的共振瑞利散射(RRS)、二级散射(SOS)和倍频散射(MFS)均十分微弱。在过量碘化物存在下,当硒(Ⅳ)氧化I^-形成I3^-配阴离子并进一步与VB4R反应形成离子缔合配合物时,3种散射均大大增强并产生相应的散射光谱。最大RRS波长位于582nm,另在320nm,410nm,452nm,470nm,800nm和940nm处有强  相似文献   

9.
研究了Fe78B13Si9合金纳米晶(27nm)和粗晶(250nm)试样的高温拉伸蠕变。纳米晶和粗晶试样蠕变初期阶段的应变-时间关系均符合Andrade的指数律。根据稳态蠕变激活能和应力指数的数值,认为纳米晶试样的蠕变由界面扩散机制控制,而粗晶试样的蠕变由一种复合机制控制。文中报道的Fe-B-Si合金与以前报道Ni-P合金高温蠕变的结果有相同的规律。  相似文献   

10.
偏最小二乘法用于荧光光度法同时测定磷,硅的研究   总被引:1,自引:0,他引:1  
将偏最小二乘法(PLS)用于荧光光度法同时测定磷、硅,对荧光光度法测定条件及PLS法最佳条件进行了试验和讨论。所建立的方法用于合金钢中磷、硅进行测定,获得了较满意的结果.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

19.
20.
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has  相似文献   

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