Preparation of organic thin-film field effect transistor

The organic thin-film field effect transistor was prepared through vacuum deposition by using teflon as di-electric material. Indium-tin-oxide acted as the source and drain electrodes. Copper phthalocyanine and teflon were used as the semiconductor layer and dielectric layer, respectively. The gate electrode was made of Ag. The channel length between the source and drain was 50 μm. After preparing the source and drain electrodes by lithography, the copper phthalocyanine layer, teflon layer and Ag layerwere prepared by vacuum deposition sequentially. The field effect electron mobility of the device reached 1.1×10ˉ6 cm2/(V@s), and the on/off current ratio reached 500.     

无结晶体管的研究现状及展望

晶体管是电子设备的关键器件,对电子设备的性能起到很大的作用.现有的晶体管主要是由引入掺杂原子到半导体材料中形成半导体结构成.而无结晶体管是源极、漏极、沟道共用一根纳米线,没有形成传统的源极结和漏极结,因此简化了制作工艺,降低了制作成本.本文主要论述了无结晶体管的发展历史、工作原理、主要性能和分类,并对无结晶体管的应用进行了展望.     

有机薄膜晶体管的发展现状、机遇与挑战

 由于有机薄膜晶体管（OTFT）可采用低温低成本印刷工艺按需加工,及其良好的机械柔韧性和不断提升的器件性能,获得了学术界和产业界的密切关注,在包括柔性显示和传感器等诸多领域展现了巨大的应用潜力,但目前OTFT离大规模产业化还存在一定距离。结合市场实际需求,对OTFT现阶段的发展现状、机遇与存在的挑战进行总结。     

对称薄膜双栅MOSFET温度特性的研究

文章对薄膜双栅MOSFET器件的温度特性进行了研究。首先对其进行理论分析,得到亚阈值电流、阈值电压和饱和电流等随温度的变化关系,并计算出理论结果,再用Medici模拟仿真加以验证,比较了不同温度下的输出特性、饱和漏电流、阈值电压与温度变化的关系,验证结果表明两者是一致的。     

有机薄膜光敏三极管动态特性及其应用

为研究试制的有机半导体酞菁铜薄膜静电感应光敏三极管的动态特性,采用电阻分压的方法检测对方波信号的响应速度,测定上升时间为268.1ns.根据所测得的参数,建立了该三极管的微变等效电路,并对参数对器件工作的影响进行了分析.结果证明该器件可以在大面积图像感光传感器中使用,并根据其光敏特性和动态特性,提出了图像感光阵列的设计方法和工作原理.     

Di-electrophoresis assembly and fabrication of SWCNT field-effect transistor

In the process of fabricating nano electrical device or system based on single-walled carbon nanotube （SWCNT）, the controllable assembly and fabrication of SWCNT field-effect transistor （SWCNT FET） is a key issue. SWCNT FET is the most basic and important component in nano electronics. After microelectrode chip of back-gate FET is designed and fabricated, di-electrophoresis technology is adopted to realize the controllable alignment and assembly of SWCNTs, based on dispersing SWCNT by sodium dodecyl sulphate （SDS） facilitated ultra-sonication technique and removing impurities by centrifugal technique. The experiments of SWCNTs assembly demonstrate that SWCNTs are aligned and assembled uniformly at the microelectrodes gap with the alignment density nearly proportional to di-electrophoresis duration and solution concentration. After the processes of rinsing, drying and improving, metallic SWCNTs among the assembled SWCNTs are burned out and residual SDS is removed, and perfect field-effect performance of SWCNT FET is eventually obtained.     

柔性衬底上金属褶皱结构制备及相关特性研究

采用磁控溅射技术在聚二甲基硅氧烷(PDMS)上制备金属褶皱结构,有效地解决了柔性结构发生形变时电阻值发生较大改变甚至失效的问题。研究了不同溅射时间对金属褶皱结构周期及高度的影响,并对金属褶皱结构的电学性能进行测试。利用原子力显微镜分析表征柔性衬底上金属褶皱结构的表面形貌,利用数字万用表进行样品表面电阻值的测量。测试结果表明:随着溅射时间的增加,金属褶皱结构的周期和高度都呈增大趋势,电阻增长率变得缓慢,对信号的响应程度也越来越小。     

Inkjet printing for flexible electronics: Materials,processes and equipments

Inkjet printing, known as digital writing technique, can directly deposit functional materials to form pattern onto substrate. This paper provides an overview of inkjet printing technologies for flexible electronics. Firstly, we highlight materials challenges in implementing flexible devices into practical application, especially for inkjet printing process. Then the micro/nano-patterning technologies of inkjet printing are discussed, including conventional inkjet printing techniques and electrohydrodynamic printing techniques. Thirdly, the related equipments on inkjet printing are shown. Finally, challenges for its future development are also discussed. The main purpose of the work is to condense the basic knowledge and highlight the challenges associated with the burgeoning and exciting field of inkjet printing for flexible electronics.     

有机场效应晶体管的研究与应用进展

有机场效应晶体管(Organic Field Effect Transistors,OFETs)是以有机半导体材料作为有源层的晶体管器件。和传统的无机半导体器件相比,由于其可应用于生产大面积柔性设备而被人们广泛的研究,在有机发光、有机光探测器、有机太阳能电池、压力传感器、有机存储设备、柔性平板显示、电子纸等众多领域具有潜在而广泛的应用前景。文中对OFET结构和工作原理做了简要介绍,之后重点讨论了最近几年来OFET中有机材料和绝缘体材料的发展状况,接着总结了OFET制备技术及其应用新领域,最后对OFET发展面临问题及应用前景做了归纳和展望。     

柔性衬底上铝背电极制备及相关特性研究

采用射频磁控溅射技术在聚酰亚胺柔性衬底上制备硅基薄膜太阳能电池用铝背电板,研究了不同溅射功率和工作气压条件对铝电极薄膜性能的影响.利用原子力显微镜分析表征了薄膜的表面形貌和粗糙度,薄膜的电学性能和光学性能分别采用四探针测量仪和紫外可见近红外分光光度计进行分析表征.测试结果表明:随着溅射功率的增加,薄膜表面均方根粗糙度迅...     

GaN基高电子迁移率晶体管器件的可靠性及退化机制研究进展

GaN基高电子迁移率晶体管（high electron mobility transistor,HEMT）器件在航天、通讯、雷达、电动汽车等领域具有广泛的应用,近年来成为电力电子器件的研究热点。在实际应用中,GaN基HEMT器件随着使用时间的延长会发生退化甚至失效的情况,器件的可靠性问题仍是进一步提高HEMT器件应用的绊脚石。因此,研究器件的可靠性及退化机制对于进一步优化器件性能具有极其重要的意义。将从影响器件可靠性的几个关键因素如高电场应力、高温存储、高温电场和重离子辐照等进行阐述,主要对近几年文献里报道的几种失效机制及相应的失效现象进行了综述和总结,最后讨论了进一步优化器件可靠性的措施,对进一步提高HEMT器件的应用起促进作用。     

基于表面势的有机薄膜晶体管漏电流的解析模型

考虑到有机薄膜晶体管(OTFT)带隙中存在指数分布的陷阱态密度,提出了基于表面势的电流解析模型.在模型建立过程中,使用薄层电荷近似区分扩散电流和漂移电流;采用泰勒展开来实现表面势的解析求解,得到较高的求解精度.基于变程跳跃理论,即载流子在局域态之间的热激活特征的隧穿输运机理,解释了OTFT的转移特性和温度特性.模型计算...     

生物碱－半导体场效应传感器的研制及应用

研制了生物碱（秋水仙碱或毛果芸香碱）－半导体场效应传感器，并测得了器件的浓度线性范围：２．５０×１０－５～４．００×１０－３ｍｏｌ／Ｌ（秋水仙碱）；９．９０×１０－５～５．０５×１０－３ｍｏｌ／Ｌ（毛果芸香碱）．该传感器可应用于药物制剂中秋水仙碱的测定．方法简便，效果良好．     

多晶硅薄膜晶体管的电流和电容分析模型

提出一种用于电路模拟的基于表面势的多晶硅薄膜晶体管(poly-Si TFTs)的电流和电容分析模型.采用非迭代方法计算poly-Si TFTs表面势随端电压的变化,从而大大地提高了上述模型的计算效率.基于表面势的解析计算和薄层电荷方法,提出了包括小尺寸效应和翘曲效应的电流电压模型.同时,文中还提出了基于电荷的电容模型.电流和电容模型在线性区和饱和区都是连续和准确的,不需要没有物理意义的光滑处理.与实验数据的比较发现,模型和实验数据符合得较好,这也证明了所提出模型的准确性.并且,该模型适用于电路仿真器.     

氧化钽/氧化铝薄膜的阻变特性和突触特性

通过微电子加工工艺,制备出具有ITO/TaO_x/AlO_x/Ti结构的双介质层阻变存储器.器件中引入的氧化铝介质层有效地减小了器件的运行电流,降低了高/低阻态间切换所需的功耗,并增大了高/低阻态电阻比值.研究表明,器件的高低态电阻与其切换电压均有良好的稳定性和均匀性,且器件表现出可靠的擦写性能与保持性能.进一步研究表明,器件高阻态导电受肖特基发射机制主导,低阻态导电受空间电荷限制机制主导.器件还具有连续可调的电阻渐变行为,利用反复电脉冲刺激下的器件电阻变化来表征突触的权值,可以模拟突触行为.     

功率LED柔性封装结构的设计与热特性分析

根据功率LED的柔性封装要求,提出了基于贴片式(SMD)封装的功率型LED柔性封装结构。对各层结构进行了优化设计,采用有限元分析(FEA),模拟了柔性封装结构LED的热场分布。对比研究了柔性LED与传统封装结构LED的热特性,并对弯曲状态下柔性衬底材料对芯片的应力进行了分析。结果表明,采用金属Cu箔衬底的柔性封装结构,其散热特性较好;Cu/超薄玻璃复合衬底替代Cu箔衬底,可以减少弯曲的应力,减少幅度达到2.5倍,散热特性基本相同。SMD柔性封装的LED不仅具有较好的热稳定性,且具有柔性可挠曲特性,其应用潜力很大。     

柔性压阻碳复合膜的制备及其特性

为研究柔性力敏传感器,以碳纳米粉为导电相,硅橡胶和有机树脂为绝缘相,在聚酰亚胺基底材料上制备了一种新型的柔性碳复合膜,其金属电极和引线用MEMS工艺制备。实验研究表明:在0～1MPa范围内这种碳复合膜的导电特性随正向应变发生显著变化;在0～0.7MPa范围内表现近似线性的压阻关系,并具有良好的温度稳定性。用这种碳复合膜制备的力敏元件不受被测物体表面形状的限制,可以被广泛应用于各种规则和不规则曲面的挤压应力测量。     

软质聚氨酯泡沫阴燃前热解特性及动力学分析

采用差示扫描量热-热重分析(DSC-TGA)同步热分析仪和中温差热分析仪(DTA)对软质聚氨酯泡沫(FPUF)在不同O2浓度下的热解特性、热解动力学及其对阴燃的影响进行研究。结果表明:聚氨酯泡沫热解主要分为2个阶段。第一阶段主要是FPUF分解产生异氰酸酯和多元醇,第二阶段主要为多元醇的分解。当O2体积分数从0增加到50%时,第一阶段热解起始温度和活化能变化很小,第二阶段最大质量分数损失速率对应温度从385℃降低到300℃,活化能从170 kJ/mo1降低到80 kJ/mo1。聚氨酯热解过程中不同类型反应的活化能大小顺序为:多元醇热解活化能聚氨酯热解活化能多元醇氧化活化能。多元醇氧化反应产生的热量是聚氨酯泡沫阴燃时的主要热量来源。因此,O2浓度增加通过加快热解速率、降低反应所需温度和增加放热量来促进阴燃的建立和传播。     

Study on temperature characteristics of organic light-emitting diodes based on tris-（8-hydroxylquinoline）-aluminum

Both single-layer and double-layer organic light-emitting devices based on tris-（8-hydroxylquino- line）-aluminum （AIq3） as emitter are fabricated by thermal vacuum deposition. The electroluminescent characteristica of these devices at various temperatures are measured, and the temperature characteristics of device performance are studied. The effect of temperature on device current conduction regime is analyzed in detail. The results show that the current-voltage （I-V） characteristics of devices are in good agreement with the theoretical prediction of trapped charge limited current （TCLC）. In addition, both the charge carrier mobility and charge carrier concentration in the organic layer increase with the rise of temperature, which results in the monotonous increase of AIq3 device current. The current conduction mechanisms of two devices at different temperatures are identical, but the exponent m in current-voltage equation changes randomly with temperature. The device luminance increases slightly and the efficiency decreases monotonously due to the aging of AIq3 luminescent properties caused by high temperature. A tiny blue shift can be observed in the electroluminescent （EL） spectra as the temperature increases, and the reduction of device monochromaticity is caused by the intrinsic characteristics of organic semiconductor energy levels.     

Preparation of photoanode and its application to flexible dye-sensitized solar cells

A TiO2 slurry was prepared by hydrothermal treating mixture of commercial TiO2 (P25),ethanol and distilled water in an autoclave.A flexible photoanode and dye-sensitized solar cell (DSSC) was fabricated on an ITO-coated poly (ethylene naphthalate) sheet (ITO/PEN) substrate by a doctor-blade technique.The sample was characterized with SEM,UV-vis,FTIR,and the photoelectric properties of the DSSC were measured.The influence of preparation conditions on the properties of the flexible DSSC was investigated.It is...