磁场对纤维素酶的性及构象的影响

以羧甲基纤维素钠（CMC）为底物评价纤维素酶的活性,研究了不同条件下静磁场对酶的活性及构象的影响。9℃,pH4.0条件下磁化,其活性及荧光光谱均不同明显变化;但若改变反应时的pH,可使活性增加达16.4%;并发现磁处理后的酶有滞后效应及可逆性,较高温度下,磁化处理酶液,其活性及构橡均发生不同程度的变化,且对其抑制动力学 混合型抑制模式;其构象变化也基本上随失活的增加荧光强度增大。     

磁场影响固定化葡萄糖异构酶活性的研究

采用丹麦Novo公司测固定化葡萄糖异构酶 (SweetzymeT)活力的反应体系 ,用半胱氨酸 -咔唑法评价酶的活性 ,研究了磁场在不同条件下对酶活力的影响。实验发现 :在不同磁化时间、温度、磁场强度和pH条件下磁化底物 ,使其活性增加可达 2 8 6 % ,并且具有可逆性 ,但磁化固定化酶或磁场作用于酶—底物反应体系 ,未见酶活力的明显变化。     

磁场对纤维素酶的活性及构象的影响

以羧甲基纤维素钠（CMC）为底物评价纤维素酶的活性,研究了不同条件下静磁场对酶的活性及构象的影响。9℃,pH4．0条件下磁化,其活性及荧光光谱均不见明显变化;但若改变反应时的pH,可使活性增加达16.4％;并发现磁处理后的酶有滞后效应及可逆性。较高温度下,磁化处理酶液,其活性及构橡均发生不同程度的变化,且对其抑制动力学表现为混合型抑制模式;其构象变化也基本上随失活的增加荧光强度增大。     

磁场影响GOD催化活性的初步探讨

本文成功地研制了ＰＶＣ葡萄糖氧化酶（ＧＯＤ）柱，用流动装置和Ｉ电极探讨了磁场对ＧＯＤ活性的影响：密闭条件下磁化，ＧＯＤ活性有所降低，敞开条件下则活性有所增强，并对其结果进行了初步探讨。     

胶束催化N,N—二甲基甲酰胺碱性水解反应

根据胶束催化反应的相分离模型和相关的假定建立了适用于底物浓度（Ｓ）≥胶束浓度（Ｍ）时的胶束催化反应动力学方程,在４０℃下用热动力学模拟热谱曲线法,在表面活性剂（ＣＴＡＢ,ＳＤＳ,Ｂｒｉｊ３５）胶束溶液中研究了Ｎ,Ｎ－二甲基甲酰胺碱性水解反应,应用该方程求得胶束催化反应动力参数ｋｍ,ｋ２ｍ结合常数Ｋ１,ＣＴＡＢ,ＳＤＳ和Ｂｒｉｊ３５胶束对该反应有催化作用,讨论了上述胶束对该反应有催化作用的原因。     

磁场对脂肪酶催化活性的影响

研究了磁场对发生在液-液两相界面上的酶促反应的影响.4℃时磁化酶溶液,短时间内酶活性显著提高,0.1T的磁场作用1h可使酶活力提高76.1%,随着作用时间的增长,酶活性逐渐降低.pH值、温度均对酶的磁效应有明显的影响;酶的磁效应存在着滞后效应;磁化水也可明显提高酶的催化活性,经0.485T的磁场作用的水可使酶活性提高将近1倍.     

外磁场对玉米幼苗脂质过氧化的影响

用场强为１０００，１４００，１８００ＧＳ的磁场处理玉米（ＺｅａｍａｙＬ．）种子，采收二、三叶期幼苗做为试验材料，以极谱氧电极法测超氧化物歧化酶（ＳＯＤ）活性，滴定法测过氧化氢酶（ＣＡＴ）活性，比色法测丙二醛（ＭＤＡ）和谷胱甘肽（ＧＳＨ）含量．结果表明，经磁场处理种子后，玉米幼苗的叶及根中ＭＤＡ含量降低，ＳＯＤ和ＣＡＴ活性提高，ＧＳＨ含量增高．揭示了外磁场可削弱玉米幼苗脂质过氧化作用     

基于响应面法的交变磁场磁化除垢条件优化

为了揭示交变磁场作用下磁化时间和钙离子初始浓度对磁化除垢效果的影响规律,以磁化碳酸钙溶液的表面张力和电导率为响应目标,基于响应面法对磁化时间和钙离子初始浓度进行优化。结果表明:磁化时间和钙离子初始浓度的交互作用对磁化碳酸钙溶液的电导率影响显著,但对碳酸钙溶液的表面张力影响不显著;当磁化时间为52.50 min,钙离子初始质量浓度为1 336.24 mg/L时,磁化碳酸钙溶液的表面张力最优值为73.60 mN/m;当磁化时间为45.00 min,钙离子初始质量浓度为1 164.71 mg/L时,磁化碳酸钙溶液的电导率最优值为0.32 S/m。     

磁场处理对CaCl_2溶液中水分子结构的影响

为了探究磁场用于水处理的机理,该文从分子有序度以及氢键生成-破坏的热力学平衡角度综合研究磁场对CaCl2溶液中水分子结构的影响。选取0.5 T的固定磁场将溶液以一定流速循环通过,检测溶液的表面张力以及核磁共振(NMR)氧核的半峰宽,计算表面熵值以及自由水分子比率的变化。实验结果表明:随磁化时间的增加表面张力和熵值减小,半峰宽增加,自由水分子的比例降低;磁化后液体有序度增加,分子间氢键作用增加,水分子团簇的平均尺寸增大;循环磁化会改变CaCl2溶液的水分子结构。     

基于分子磁化率性质的电磁流量计误差

采用电磁学和结构化学原理剖析了用于石油"三采"聚合物液流的电磁流量计计量误差原因,从分子磁化性质的角度解释了由于不同溶液的磁化率性质不同所造成的电磁流量计计量误差的现象.结合公式和实验说明了不同溶液在电磁流量计励磁磁场的作用下发生磁化而导致电磁流量计原励磁磁场强度发生变化的误差机理.通过论证和实验证明,不同磁化率性质的溶液在通过励磁磁场时将会不同程度的改变原磁场强度,因此不同溶液在同一电磁流量计磁场的作用下其感应电动势的响应值是不同的.     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

An Analysis of Catherine＇s Character——Wuthering Heights

Wuthering Heights, Emily Bronte＇s only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.     

Lower Paleozoic oil relationships within Williston Basin, Canada

The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with