溶剂多参数分类方法的应用探讨

按照溶剂多参数分类方法,通过不同类型溶剂中进行的诸如互变异构、顺反异构、光化学等有机反应的溶剂效应及紫外光谱吸收峰的溶剂效应的关系,用溶剂参数ET(30)、ε、n2D0进行了表征,结果表明具有很好的相关性.     

噻唑杂环偶氮分散染料的溶剂效应

测试了两个噻唑杂环偶氮分散染料在十五种溶剂中的电子光谱,发现化合物的可见吸收光谱吸收带的(?)_(max)~(UV)不仅与溶剂的折射率n有关,而且与溶剂的介电常数ε有关,即与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和ε-1/ε+2-n~2-1/n~2+2存在着良好的线性关系。     

扰动KdV方程解的先验估计

对于带微扰的KdV方程u_t+6uu_x+u_xx=εR(u)，(ε＞0)，在初值u₀(x)∈C∞(-∞,+∞)，当|x|→∞时指数衰减的条件下，分别构造出带两种不同扰动项的KdV方程的扰动孤立波解满足的能量关系式，并运用能量分析方法对扰动的孤立波解进行先验估计，得到如下结论：(1)R(u)=δ(εt)u, δ(s)∈C［0,+∞)，δ(0)=0，时，解在-∞＜x＜+∞，0≤εt≤T内一致有界；(2)R(u)=-Δ(εt)u_xxx，Δ(0)=0，Δ(s)∈C¹［0,+∞), 解在-∞＜x＜+∞，0≤εt≤T，0≤ε≤ε₁内一致有界。     

扰动KdV方程解的先验估计

对于带微扰的KdV方程u_t+6uu_x+u_xx=εR(u),(ε＞0),在初值u₀(x)∈C∞(-∞,+∞),当|x|→∞时指数衰减的条件下,分别构造出带两种不同扰动项的KdV方程的扰动孤立波解满足的能量关系式,并运用能量分析方法对扰动的孤立波解进行先验估计,得到如下结论：(1)R(u)=δ(εt)u, δ(s)∈C［0,+∞),δ(0)=0,时,解在-∞＜x＜+∞,0≤εt≤T内一致有界;(2)R(u)=-Δ(εt)u_xxx,Δ(0)=0,Δ(s)∈C¹［0,+∞), 解在-∞＜x＜+∞,0≤εt≤T,0≤ε≤ε₁内一致有界。     

具有桥链七甲川菁染料的合成及其电子吸收光谱

合成了三个具有桥链的七甲川菁染料。研究染料结构对最大吸收波长的影响,并测定了染料在18种溶剂中的吸收光谱,发现染料的V_(max)~(ab)分别与溶剂的n~2-1/2n~2+1、(ε-n~2)(2ε+n~2)/ε(n+2)~2和((ε-1)/(ε+2))-((n~2-1)/(n~2+2))存在着良好的钱性关系。     

乙醇-水混合溶剂中尿苷酸浓度与溶液密度的关系

获取尿苷酸溶析结晶动力学参数须测定其溶液浓度变化，针对密度法浓度在线测量技术，研究了乙醇-水混合溶剂中尿苷酸(Uridine-5’-monophosphate)质量浓度与溶液密度的关系。20℃条件下，测定了尿苷酸在不同质量分数乙醇．水混合溶剂中的溶解度和溶液密度，以及混合溶剂质量分数一定时的尿苷酸质量浓度和溶液密度。实验结果表明：乙醇一水混合溶剂中，溶液体积与尿苷酸质量浓度具有较高的相关性，可以拟合得到三元溶液体系尿苷酸质量浓度与溶液密度的变化关系式。     

溶剂效应对对苯醌CO键伸缩振动费米共振的影响

测量了对苯醌在13种溶剂中的红外光谱,用Bertran变换溶剂法验证了费米共振规律.利用KBM方程和电子给体-受体等溶剂效应模型,解释了变换溶剂法研究费米共振的机理,并给出费米共振光谱强度比(R)与溶剂介电常数(ε)的关系.     

二阶线性微分方程在李群之下的不变式

本文讨论线性二阶(常的与偏的)微分方程(非抛物型的),按照李群定义其不变式,证明了关系式λ(x,ε)(?)_o(x,x_o;ε)=λ(x_o,ε)W_o(x,x_o;ε),(?)及当h=i,1≤i≤m_1时,J_h(x,y;x_o,y_o;ε)=J_1.1(x,x_o;ε)当h=m_1+k,1≤k≤m_2时,J_h(x,y;x_o,y_o;ε)=J_2,k(y,y_o;ε)。     

毛细管气相色谱法检测替加环素中有机溶剂残留

建立了毛细管气相色谱法测定替加环素原料药中7种有机残留溶剂的分析方法．采用ZB-624熔融石英毛细管柱（30m×0．53mm×3μm）,FID检测器,以二甲基亚砜为溶剂．其中甲醇、异丙醇、异丙醚、二氯甲烷、四氢呋喃与甲苯的测定采用顶空进样法,柱温40℃保持9min,以20℃／min升温至200℃,保持1min;N,N-二甲基甲酰胺的测定采用直接进样法,柱温100℃保持5min,以20℃／min升温至200℃．结果表明各残留溶剂均能得到有效分离,在所考察的浓度范围内呈良好的线性关系（r=0．9989～0．9999）,平均加样回收率在92．4％～104．8％（RSD=1．41％-5．6％）之间,定量限为0．15—10．19μg／mL,3批样品中7种残留溶剂的量均符合我国药典要求．该方法可用于替加环素原料药中残留溶剂的检测和质量控制．     

溶剂效应对对苯醌C=O键伸缩振动费米共振的影响

测量了对苯醌在13种溶剂中的红外光谱, 用Bertran变换溶剂法验证了费米共振规律. 利用KBM方程和电子给体-受体等溶剂效应模型, 解释了变换溶剂法研究费米共振的机理, 并给出费米共振光谱强度比(R)与溶剂介电常数(ε)的关系.      

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

Call for Papers

<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with     

Journal of Donghua University ( English Edition) Contents of Volume 31

正~~     

Brief Introduction to “Journal of Jilin University( Science Edition) ”

<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has