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1.
以Fe3(CO)12为母体制备担载金属簇催化剂的表面化学 …   总被引:1,自引:0,他引:1  
以表面浸渍的方法制备了以Fe3(CO)12为母体,SY分子筛为载体的担载型Fe3/SY催化剂。采用TPD-IR,UV-DRS、XPS,TPD-GC等技术综合研究了Fe3(CO)12与SY载体间的相互作用,在真空中的热分解以及Fe3/SY上CO吸附、CO和H2共吸附的动态过程。IR结果表明,Fe3(CO)12与载体之间存在着较强的相互作用,并由此使得簇结构得到稳定,脱羰过程中存在着结构的转变。XPS  相似文献   

2.
浅谈高校人事档案收集渠道和方式ABRIEFDISCUSSIOINONMEDIUMSANDSTYLESOFTHEPEROSNNELARCHIVESCOLLECTIONOFCOLLEGES/UNIVERSITIES翁巧英WenQiaoying(浙江水产学...  相似文献   

3.
THECURRENTDENSITYDEPENDENCEOFACTIVATIONENERGYINHIGH-TcSUPERCONDUCTORHgBa_2Ca_2Cu_3O_(8+x)INLOWCURRENTDENSITYTHECURRENTDENSITYDE...  相似文献   

4.
已知在加氢汽油介质中Ni(naph)2-Al(i-BU)3-(BF3.OEt2+n-C8H17OH)体系为胶体催化剂。本工作应用FT-IR谱结合Tyndall效应,电导率,UV-Vis,ESR谱对催化剂各组分的相互作用进行研究。  相似文献   

5.
STRANGEANTIBARYONPRODUCTIONDATAANDREDUCTIONOFSTRANGENESSSUPPRESSIONINSULPHUR┐NUCLEUSCOLLISIONSAT200AGeVSaBenhao1,2,3,5TaiAn41...  相似文献   

6.
两种冬青学名的订正邹惠渝(森林资源与环境学院)关键词冬青;学名;订正中国分类号S718.49REVISIONONSCIENTIFICNAMESOFTWOSPECIESOFHOLLY(AQUIFOLIACEAE)¥ZouHuiyu(CollegeofF...  相似文献   

7.
提出了一种滴定强酸性含Fe3+及Fe2+体系中游离酸(其游离酸浓度>1mol/L)的新方法。实验证明,将K2C2O4作为掩蔽剂时,利用过量的KIO3与过量的Na2S2O3在酸性溶液中的氧化还原反应可以测定体系中的游离酸。当体系中存在Fe2+时,可利用KMnO4(在强酸性下)或H2O2(在弱酸性下)的预氧化来消除Fe2+的干扰。在加入过量的K2C2O4(C2O42-与Fe3+的摩尔比值为30)和过量的KIO3及Na2S2O3的条件下,其化学反应可以在30min内完成。采用I2回滴法测定游离酸,测试结果的精密度高,测定结果的相对偏差小于3%  相似文献   

8.
LARGEPIEZORESISTANCEANDPRESSURE┐INDUCEDMETAL┐SEMICONDUCTORTRANSISTIONINTHEPEROVSKITE┐LIKELa┐Ar┐Mn┐OZhangNing1),2)DingWeiping...  相似文献   

9.
刚性无机粒子对PDMS/PU共混体系增强改性研究(Ⅰ)   总被引:1,自引:0,他引:1  
采用刚性无机粒子(SIO2)填充不相容聚二甲基硅氧烷/聚氨酯(PDMS/PU)共混体系.重点研究了SiO2表面处理剂种类、SiO2填充量对不同结构的PDMS/PU共混体系力学性能的影响关系.研究结果表明:SiO2经过适当偶联剂表面处理后,能显著地提高PDMS/PU(M)、PDMS/PU(P)共混物的力学性能,其抗张强度分别由3.4MPa、4.5MPa提高到12.3MPa和9.0MPa.  相似文献   

10.
研究了在聚氯乙烯(PVC)中,Sb_2O_3-ZnSn(OH)_6,Sb_2O_3-ZnNH_4PO_4,ZnSn(OH)_6-ZnNH_4PO_4二元体系的协同阻燃性能,以及Sb_2O_3-ZnSn(OH)_6-ZnNH_4PO_4三元系的阻燃性能,采用混料回归实验设计,导出了三元系氧指数与阻燃剂含量关系的数学模型,经计算机计算并绘制出了氧指数等值图,该体系中Sb_2O_3-ZnSn(OH)_6,Sb_2O_3-ZnNH_4PO_4复配具有正的协同作用,而ZnSn(OH)_6-ZnNH_4PO_4复配则表现为负的协同作用。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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