Nd isotopic disequilibrium between minerals and Rb-Sr age of the secondary phengite in eclogite from the Yangkou area, Qingdao, eastern China

There are two generations of white micas in retrograded coesite-bearing eclogite from the Yangkou area near Qingdao, eastern China. The secondary phengite developed along the folliations in eclogite is the majority of the white micas. Nd and Sr isotopic disequilibriums between garnet and retrograded omphacite as well as secondary phengite have been observed. Consequently, the Rb-Sr ages ((193 ± 4) Ma―(195 ± 4) Ma) given by the tie lines of the secondary phengite + garnet or whole rock may predate the formation time of the phengite. The Rb-Sr age of (183 ± 4) Ma given by the secondary phengite + retrograde omphacite is much closer to the formation time of the phengite indicating the retrograde age of eclogite instead of a cooling age of eclogite at 500℃.     

三氧化二钕催化合成尼泊金丁酯

研究了以三氧化二钕作固体催化剂合成尼泊金丁酯,通过正交实验讨论了影响催化酯化反应的各种因素,确定了该酯化反应最佳条件。催化剂用量仅为尼泊金酯重量的５％ ,醇酸摩尔比为４∶１,反应时间为４ｈ,温度为１２℃,酯收率达８１２％     

The Sr, Nd isotopic composition of lamprophyres in Laowangzhai gold orefield, Yunnan Province

Lamprophyres are widely spread over the Laowangzhai gold orefield in northern Mt. Ailao structure zone, Yunnan Province. Lamprophyres in the orefield are temporally and spatially related to gold mineralization. Lamprophyres in the orefield have anomalous Sr and Nd isotopic compositions, e.g. the 87Sr/ 86Sr ratios (0.706 665-0.707 960, the 87Sr/ 86Sr ratio of sample YLW-44 is 0.709 041) are higher than the modern value of the original mantle (0.704 5), the 143Nd/ 144Nd ratios (0.512 463-0.512 551) are lower than the modern value of the original mantle (0.512 638), and the calculated values ε Sr>0 (28.1-63.7) and ε Nd<0 (-1.34--3.07). The results of investigation indicate that lamprophyres in the Laowangzhai gold orefield with anomalous Sr and Nd isotopic compositions would not be produced as a result of contamination of the primary magma with the isotopic features of MORB by the crust materials high 87Sr/ 86Sr ratios and low 143Nd/ 144Nd ratios in the processes of rising or in the magma chamber, but the result of metasomatism of source mantle.     

Determination on ^87Sr/^86Sr ratio and stratigraphic dating of single-grain foraminifera

Information on palaeoocean and palaeoclimate can be recorded in foraminifera, and formation ages of the fo- raminifera are nevertheless essential for such study of pa- laeoenvironment. The growth rate of seamount ferroman- ganese crusts is normally very l…     

川东北宋家洞石笋氧碳同位素及锶含量突变分析

通过对宋家洞石笋SJ3的氧碳同位素及锶含量进行Mann-Kendall test突变分析,得出以下结论:(1)氧同位素值记录了末次冰盛期向Heinrich Event 1时期的转变;(2)碳同位素值和锶含量记录了由H1冷期向BФlling-AllerФd暖期的转变;(3)碳同位素值和锶含量指示了在19.8～15.3ka时当地的东亚夏季风和冬季风呈正相关关系,在15.3～14.8 ka呈负相关关系,表明石笋SJ3记录了古气候环境的冷干、暖湿变化,且不同气候指标对环境变化的敏感度不同。     

混合元素掺杂对Sr_2MgSi_2O_7蓝色长余辉发光材料的影响

采用溶胶-凝胶法合成了不同元素混合掺杂Sr2MgSi2O7系列蓝色长余辉发光材料,并对其发光性能进行研究,探讨掺杂元素对材料发光性能的影响规律性.激发发射光谱实验表明其峰均为宽带峰,最大发射峰位于466nm附近,是由典型的Eu2+的4f5d-4f跃迁导致的.所合成的Eu2+,Dy3共掺杂发光材料Sr2MgSi2O7余辉时间可达8hrs以上,具有合适的能级陷阱0.76eV.     

无铅压电陶瓷(Sr2-xCax)2Bi4Ti5O18制备及其压电性能研究

采用固相合成法制备了铋层状无铅压电陶瓷Sr2-xCaxBi4Ti5O18(SCBT)(O≤x≤0.2).利用XRD对900℃合成出的粉体进行了表征,结果显示粉体相结构是Aurivillius结构相.通过SEM形貌分析可以看出1 160℃保温2 h烧结出的陶瓷为片状结构.研究结果表明SCBT陶瓷的居里温度、矫顽场随钙含量的增加而增加.     

MgO修饰的γ-Al2O3作为燃烧催化剂La0.8Sr0.2CoO3载体的研究

以γ-Al2 O3 为第一载体 ,Mg O为修饰物 ,在修饰过程中加入络合剂聚乙烯醇 ( PVA)制备复合载体 ,以稀土复合氧化物 La0 .8Sr0 .2 Co O3 为活性组分 ,采用浸渍蒸干法得到负载型催化剂 ,用 XRD、BET法、二甲苯完全氧化等手段 ,测定了复合载体及催化剂的相关性能 .结果表明 :加入 PVA可有效减小复合载体的晶粒至纳米量级 ,提高其比表面积 ,降低修饰物 Mg O的用量 ,其相应催化剂的活性也得到改善 .     

稀土氧化物（Nd2O3）催化合成乙酸乙酯

本探讨了用稀土氧化物Nd2O3作催化剂,以冰乙酸和乙醇为原料合成乙配乙酯,通过对各种酸醇比、催化剂用量、不同反应时间的试验,找到比较合适的反应条件。     

Geochronology and Nd and Pb isotope characteristics of gabbro dikes in the Luobusha ophiolite, Tibet

We report a combined internal and whole-rock Sm-Nd isochron age, and Nd and Pb isotopic data for gabbro dikes of the Luobusha ophiolite in Tibet. The Sm-Nd isochron of data for two whole rocks and plagioclase and clinopyroxene separates from one of the rocks yields a Middle Jurassic age of (177±31) Ma (with an initial ε_Nd(t) = +8), which provides a significant bound on the time of formation of the Luobusha ophiolite. The Nd and Pb isotopic characteristics of the dike indicate an Indian-Ocean-type isotopic affinity, and we conclude that the Luobusha ophiolite formed in an oceanic setting during the Middle Jurassic.     

2.5 Ma以来黄土高原灵台剖面黄土-古土壤87Sr/86Sr比值的变化

研究提出了2．5MaB．P．以来黄土高原灵台剖面黄土-古土壤序列的酸不溶物^87Sr/^86Sr、Rb/Sr、Zr/Rb、平均粒径和磁化率的变化曲线．黄土和古土壤酸不溶物^87Sr/^86Sr、Rb/Sr、Zr/Rb和磁化率的变化具有类似的阶段性．研究证明，黄土和古土壤酸不溶物^87Sr/^86Sr比值是化学风化强度的替代指标。Zr/Rb是物理风化强度的替代指标．自2．5MaB．P．以来大陆化学风化强度在总体上呈下降趋势,而物理风化强度呈上升趋势．     

甘肃北山桥湾北花岗岩体的年代学、地球化学及其地质意义

为加深对北山晚古生代构造演化的认识, 选取位于甘肃北山南带、敦煌地块北缘的桥湾北花岗岩体进行年代学、地球化学研究。桥湾北角闪石花岗岩体锆石LA-ICP MS年龄为303.7±2.4 Ma, ε_Hf(t)为-1.2~5.8, ε_Nd(t)相对较高(-0.40~-0.06), (⁸⁷Sr/⁸⁶Sr)_i =(0.704524~0.705062)。 桥湾北花岗岩体K₂O含量为4.09%~5.58%, 属高钾钙碱性岩石, A/CNK值在0.92~1.04之间, 为I型花岗岩; 微量元素较富集LILE, 相对亏损HFSE, 有明显的Nb, Ta负异常。岩体具相对富集的微弱分馏的轻稀土元素, 重稀土元素分馏不明显, 基本没有Eu异常。由Hf, Nd同位素及地球化学特征判断, 桥湾北花岗岩体为壳幔混合成因, 其形式可以是底侵的幔源岩浆再分异, 上升过程中遭受地壳物质混染。根据区域构造背景及岩石学、地球化学特征, 可以认为桥湾北岩体是北山南带后碰撞过程岩浆活动的产物, 反映出在晚石炭世北山地区的碰撞拼贴已经完成。     

Nd isotopic characteristics of post-Archean sediments from the Eastern Nanling Range： Evidence for crustal evolution

A systematic Sm-Nd isotopic study was carried out for sediments and metasediments of different ages from Mesoproterozoic to early Mesozoic era in southwestern Fujian, Eastern Nanling Range. The results show that Nd model age (tDM) and εNd(t) value of most sediments are closely similar to those of Paleoproterozoic Mayuan Group, indicating that they may mainly be the recycling product of Paleoproterozoic crustal materials. However, the Nd model age significantly decreases with a corresponding increase in the εNd(t) value at Neoproterozoic (ca. 0.8-0.7 Ga) and Late Paleozoic (ca. 0.25 Ga), respectively. This is manifested by prominent vales and apexes on the diagrams of tDM VS. tStr. (stratum age) and εNd(t) VS. tstr. The decrease in tDM and the increase in εNd(t) are explained as a result of the significant incorporation of juvenile crustal materials that originated from depleted mantle due to strong lithospheric extension during both periods. It appears that tectonic magmatism in the Neoproterozoic and the Late Paleozoic is of prominent importance in affecting the geochemical nature of sediments in South China.     

超声波法复合纳米Nd_2O_3/TiO_2的光性能研究

以Nd2O3和TiO2为原料,采用超声波共振法合成了不同掺杂量、不同煅烧温度的纳米Nd2O3/TiO2光催化剂.对所制样品进行XRD、FT-IR、SEM表征;以有机染料罗丹明B为降解物来进行光催化性能实验的研究.结果表明稀土Nd3+掺杂纳米TiO2能细化晶粒,抑制金红石相生成;在550℃下煅烧,n(Nd3+):n(TiO2)=0.2%的催化剂,加入协同催化剂30%的双氧水后,不仅降低基元反应活化能,而且是氧化剂具有捕获电子的能力,使催化反应在实验室中无灯源照射,催化时间6h,降解率达到93%.     

Petrogenesis of keratophyes in the Pingshui Group, Zhejiang: Constraints from zircon U-Pb ages and Hf isotopes

Zircon LA-ICP-MS U-Pb ages and Hf isotopic as well as whole-rock geochemical data are reported for keratophyes in the Pingshui Group, Zhejiang. The results are used to discuss their petrogenesis and geological significance. The keratophyes were dated at 904±8 to 906±10 Ma. These intermediate-felsic rocks are characterized by high LREE contents and depletion of HREE and HFSE (e.g., Nb, Ta, Ti, P), resembling arc-derived rocks. The keratophyes exhibit positive εHf(t) values of 8.6 to 15.4, consistent with the...     

琼中古-中元古代变质基性火山岩地球化学特征

琼中斜长角闪(片麻)岩为变质的古-中元古代基性火山岩,属于高铝和低钛的高钾钙碱性玄武岩系.其LILE和LREE明显富集,HFSE相对亏损,具有典型岛弧玄武岩特征.微量元素、Sm-Nd同位素组成还揭示其岩浆源区偏离原始地幔,但未受成熟地壳物质的明显污染,是消减带上部地幔楔与俯冲洋壳析出的流体二元混合物部分熔融的产物.古-中元古宙时期,海南地块可能经历了由拉张到挤压的地球动力学转变,早期拉张阶段形成琼西洋脊型和过渡型拉斑玄武岩,中晚期强烈俯冲作用形成琼中岛弧高钾钙碱性玄武岩,该俯冲期与华南统一地块古-中元古宙板块俯冲时期相对应.     

Petrogenesis of Paleoproterozoic Luyashan charnockitic rocks in Shanxi Province: Constraints from Geochemistry and Nd isotope

Luyashan charnockite pluton mainly consists of monzonite, adamellite, charnockite and syenogranite, which are characterized by the enrichment of TiO2, P2O5, K2O, Zr, Nb, Y, Pb, La, Ce, Ba and a higher K2O/Na2O and depletion of MgO, CaO, Mg#, Th, U and lower Sr/Ba and Rb/Ba. The negative correlations between Zr, Nb, Ce and SiO2 are distinct from I-type granites. Iso-topically Luyashan charnockite plutons are relatively uniform in Nd isotope, displaying initial εNd(t) (-5.93 to -6.97) and Nd depleted mantle model ages (2.67 Ga to 2.78Ga). These features indicate that Luyashan charnockitic magma derived from pre-existing late Archean crustal sources and the partial melting of mafic granulites probably under exceptionally high temperature with CO2-rich fluid. The garnet is a main residual phase during the partial melting. The original dry charnockitic magma experienced crystal fractionation of pyroxene, plagioclase, apatite and ilmenite during early crystallization. The geochemical evidence suggests that the Luyashan charnockitic magma was probably generated in the post-collision thermal relaxation and uplift tectonic setting after the main collision ( - 1850 Ma) between the Eastern and Western continental blocks.