Recovery of iron from copper slag by deep reduction and magnetic beneficiation

Aiming at recovering iron from high-iron-content copper slag, this article introduced a combination technology of deep reduction and magnetic beneficiation, investigated the iron recovery efficiency and optimized the technical conditions. When coke powder with 86wt% fixed carbon was used as a reductant, iron was successfully extracted from the copper slag. Under the optimized condition of the coke powder content of 14wt%, the calcium-to-silicon mass ratio (Ca/Si) of 0.2, the roasting temperature of 1300℃, the roasting time of 3 h, the grinding time of 20 min, and the magnetic field intensity of 61 kA·m?1, the iron recovery rate of the copper slag can reach 91.82%, and the extracted iron powder has an iron grade of 96.21%. With the characteristics of high iron grade and low impurity content, the extracted iron powder can be used as high-quality raw materials of weathering steel.     

Preparation of composite abrasives by electrostatic self-assembly method and its polishing properties in Cu CMP

The adsorption characteristics of cationic polyelectrolyte poly dimethyl diallyl ammonium chloride （PDADMAC） and anionic polyelectrolyte poly （sodium-p-styrenesulfonate） （PSS） on benzoguanamine formal- dehyde （BGF） particles are investigated. The charging characteristics of BGF particles are changed and con- trolled using electrostatic self-assembly method. A variety of PE,-BGF/SiO2 composite abrasives are obtained. The as-prepared samples are analyzed by zeta potential analysis, transmission electron microscope （TEM） and thermogravimetric （TG） analysis. The composite abrasive slurries are prepared for copper polishing. The poli- shing results indicate that it is SiO2 abrasives, not only coated SiO2 abrasive on polymer particles but also free SiO2 abrasive in slurry, that offer the polishing action. The material removal rates of copper polishing are 264 nm/min, 348 nm/min and 476 nm/min using single SiO2 abrasive slurry, PE0-BGF/SiO2 mixed abrasive slur- ry and PE3-BGF/SiO2 composite abrasive slurry, respectively. The surface roughness Ra of copper wafer （with 5μm×5μm district） is decreased from 0.166 μm to 3.7 nm, 2.6 nm and 1.5 nm, and the surface peak-valley values Rrv are less than 20 nm, 14 nm and 10 nm using these kinds of slurries, respectively. Key words ： chemico-mechanical polishing; polishing slurry; composite abrasives ; polyelectrolyte ; copper     

Exploration on ecological regulation of the reservoirs

Reservoir regulation process in the Yangtze River basin is mainly divided into two types of flood regulation and initiating benefit regulation. The present reservoir management system and operation mode are mainly for dealing with or coordinating of flood control and benefit initiation as well as benefit distribution among various beneficial functions. From the view point of river ecosystem protection, the current regulation mode has two kinds of problems ： firstly, most of the reservoir regulation plans do not consider ecosystem protection at downstream of dams and needs of environment protection in reservoir areas; secondly, integrated regulation or management of water resources is ignored. It is very necessary to improve reservoir regulation mode, bearing problems faced by regulation of the Three Gorges reservoir and issues related to cascade development and regulation in Tuojiang and Minjiang River basins in mind. In accordance with the concept of scientific development, and the philosophy of ＂ensuring a healthy Yangtze River and promoting the harmony between human and water＂, taking flood control, benefit initiation and eco-system as a whole, this paper put forward the basic consideration to improve reservoir regulation as follows ： on the basis of requirements of ecosystem protection at downstream of dams and needs of environment protection in reservoir areas, we should bring the functions of reservoir such as flood control and benefit initiation into full play, control the negative influence to the ecosystem at downstream of dams and the environment in reservoir areas in an endurable scope, and restore the ecosystem and the environment step by step. This paper put forward the relevant regulation process aiming at the idiographic problems such as protection of ecosystem at downstream of dams and environment in reservoir areas, protection of aquatic wildlife species and fish species, regulation of sediment and protection of wetland.     

Influence of Al on the magnetostriction of Fe-Ga polycrystal alloys under compressive stress

Fe₈₀Ga_20?xAl_x (x = 0, 6, 9, 14) ingots were prepared from high purity elements using a vacuum induction system. X-ray diffraction patterns show that the alloys are A2 disordered structures. The influence of the partial substitution of Ga in Fe-Ga alloys with Al on their magnetostrictive properties was investigated, and the effects of different heat treatment conditions on the magnetostriction and microstructure of the alloy rods were also examined. The saturation magnetostriction value of Fe₈₀Ga₂₀ can reach to 240·10?6 under a compressive stress of 20 MPa. The Fe₈₀Ga₁₁Al₉ alloy has many good properties, such as low hysteresis, high linearity of the magnetostriction curve, and low saturated magnetic field, which make it a potential candidate for magnetostrictive actuator and transducer applications. It is found that subgrains have little influence on the magnetostriction of Fe-Ga alloys.     

Low Cost Fabrication of Parallel Grid Electrode Group for Carbon Nanotube Field Emission Display

Based on simple screen printing technique,the parallel grid electrode group was developed. One grid electrode included the left and the right branch electrodes,which were formed with the solidified silver slurry on grid substrate. Under one anode pixel,the left and the right branch electrodes would control respectively the electron emission of two independent carbon nanotube （CNT） field emitters on the same cathode electrode. With the parallel grid electrode group, the capacitance effect between grid-cathode electrodes would be reduced due to the decreased grid electrode fabrication area. And the service life of field emission display （FED） could be prolonged owing to the existence of spare branch electrode. Using CNT as field emitter,the FED with parallel grid electrode group was fabricated,which possessed better grid control performance, high luminescence image brightness, and low fabrication cost. The turn-on electric-field was 2. 13 V /mm and the maximum field emission current had reached 1 506. 2 mA.     

Subsurface macro-inclusions and solidified hook character in aluminum-killed deep-drawing steel slabs

Subsurface macro-inclusions and hooks are detrimental to the surface quality of deep-drawing steel sheets. However, little is known about the relationship between macro-inclusions and hooks. Thus, in this work, two ultralow carbon (ULC) steel slabs and two low carbon (LC) aluminum-killed steel slabs were sampled to study the relationship between hooks and subsurface macro-inclusions, which were detected on the cross-sections of steel samples with an area of 56058 mm2 using an automated scanning electron microscopy/energy-dispersive X-ray spectroscopy system. Results show that subsurface inclusions larger than 200 μm were almost entrapped by hook structures, whereas the location of other inclusions smaller than 200 μm had no obvious dependence on the location of solidified hooks. Furthermore, the number density (ND) of subsurface inclusions larger than 200 μm decreased from 0.02 to 0 cm-2 in ULC steel as the mean hook depth decreased from 1.57 to 1.01 mm. Similar trends were also observed in LC steel. In addition, the detected inclusions larger than 200 μm were concentrated in the region near the slab center (3/8 width-5/8 width), where hook depths were also larger than those at any other locations. Therefore, minimizing the hook depth is an effective way to reduce inclusion-induced sliver defects in deep-drawing steels.     

Effects of basicity and MgO content on the viscosity of the SiO2-CaO-MgO-9wt%Al2O3 slag system

The effects of basicity and MgO content on the viscosity of SiO2-CaO-MgO-9wt%Al2O3 slags with basicity from 0.4 to 1.0 and MgO content from 13wt%to 19wt%were investigated using the rotating cylinder method. A correlation between the viscosity and the slag structure was determined by Fourier transform infrared （FTIR） spectroscopy. It is indicated that the complex network structure of the slag melt is depolymerized into simpler network units with increasing basicity or MgO content, resulting in a continuous decrease in viscosity of the slag. The viscosity is strongly dependent on the combined action of basic oxide components in the slag. Under the present experimental conditions, increasing the basicity is found to be more effective than increasing the MgO content in decreasing the viscosity of the slag. At higher temperatures, the increase of basicity or MgO content does not appreciably decrease the viscosity of the slag, as it does at lower tem-peratures. The calculated activation energy of viscous flow is between 154 and 200 kJ＆#183;mol-1, which decreases with an increase in basicity from 0.4 to 1.0 at a fixed MgO content in the range of 13wt%to 19wt%.     

The principle of minimization of the equivalent load for design of launching vertical shiplift

Launching vertical shiplift is a type of shiplifts which have the advantages in characteristics of dynamics and statics, safety and simplicity in operation. But their applications are limited as the scales of mechanical equipments are too large. This paper puts forward the principle of minimization of the equivalent load for the general layout design of launching vertical shiplifts, based on the analysis of the load probability of the main hoists and their key mechanical equipments. The principle aims at determining the optimal weight of counterweight so that the equivalent loads of the main hoists of shiplifls are minimized, and larger ships are permitted to pass through. The theory and method presented in this paper have been applied in the design of the first step and third step shiplifts of the Goupitan Hydro Power Station. This has resulted in the breakthrough of the design and manufacture of launching vertical shiplifts so that the ships with tonnage of 500 t can pass through hydro dams for this type of shiplifts, comparing with the largest launching shiplift in Yantan Hydro Power Station with the 250 t shiplift.     

Influence of Te doping on the dielectric and optical properties of InBi crystals grown by directional freezing

Stoichiometric pure and tellurium (Te) doped indium bismuthide (InBi) were grown using the directional freezing technique in a fabricated furnace. The X-ray diffraction profiles identified the crystallinity and phase composition. The surface topographical features were observed by scanning electron microscopy and atomic force microscopy. The energy dispersive analysis by X-rays was performed to identify the atomic proportion of elements. Studies on the temperature dependence of dielectric constant (?), loss tangent (tanδ), and AC conductivity (σ_ac) reveal the existence of a ferroelectric phase transition in the doped material at 403 K. When InBi is doped with tellurium (4.04 at%), a band gap of 0.20 eV can be achieved, and this is confirmed using Fourier transform infrared studies. The results thus show the conversion of semimetallic InBi to a semiconductor with the optical properties suitable for use in infrared detectors.     

Comparison and Performance Analysis of Heat Storage Equipment in Solar Heating System

Solar heating system is widely used recently.Heat storage equipment is the guarantee for steady performance of solar heating system.A design of latent heat storage exchanger with submerged coil was introduced with the structure,working principle,and the main advantages.This heat exchanger was integrated into solar heating system as the heat storage equipment.Advantage comparison of the designed heat exchanger in solar heating system with hot water tank was carried out.The analysis results show that the latent heat storage exchanger is superior to hot water tank obviously.The heat exchanger performance parameters and variations of these parameters are got:(1)with the increase of phase change material(PCM)volume ratio,heat storage equipment volume ratio decreases;(2)heat storage efficiency has the same varying tendency with outdoor and air temperature;while the bigger PCM volume ratio is,the weaker the effect of outdoor air temperature on heat storage efficiency is;(3)heat storage capacity and heat storage efficiency increase together;when PCM volume ratio is big,heat storage efficiency is high and the system can begin operating efficiently and quickly;(4)with the increase of heat storage capacity,life cycle operation cost(LCOC)of system increases gradually in high speed;but with the increase of PCM volume ratio,the difference between the two systems LCOCs becomes smaller and smaller;(5)the reasonable range of PCM volume ratio is 0.5-0.7.Temperature characteristic analysis shows that,with the filled PCM,heat storage medium temperature presents several segments at different time,under conditions of different heat storage capacity and different PCM state.     

Design and Performance Analysis of Small Denture Machining Equipment

The research and application on small denture machining equipment are great breakthrough for modern dental restoration technology.In this paper,a small denture machining equipment made of two spindles with four-axis was designed based on machining characteristics and functional analysis.Position accuracy and re-position accuracy were measured by accuracy instrument.In order to test its machining capacity,some typical microstructure parts,such as straight channel,hemispherical surface,and molars coronal,were selected for high speed milling.It was obtained that the denture machining equipment met the machining requirements with high quality and efficiency,according to the acquisition and analysis of form and position errors,surface roughness,and 3-D profile.     

Application of System Dynamics in Analyzing the Cultivated Land-Water Resources Carrying Capacity in Bijie Prefecture, China

The cultivated land-water resources carrying capacity(CL-WRCC)with the method of system dynamics(SD)were analyzed.Bijie prefecture of Guizhou province served as a case in this study.Bijie prefecture is one of the least-developed areas in China.In Bijie,the physical and chemical characteristics of karst as well as the rapid economic development lead to the scarcities of cultivated land-water resources(CL-WR).On the basis of analysis on the subsystems of Bijie CL-WRCC system,the fundamental feedback structure of CL-WRCC was presented by causal loop diagram.Considering the three aims("poverty alleviation and development,ecological construction,and population control")of Bijie as the major goals,Bijie CL-WRCC SD model was developed.Three scenarios,resource-saving and environment-friendly development-oriented scenario(Scenario 1),fast economic development-oriented scenario(Scenario 2),and coordinated development-oriented scenario(Scenario 3),were investigated.Simulation results indicate that Scenario 3 which takes social economic development,environment protection,and cultivated landwater resources utilization into account,is the best alternative scenario.It can promote the coordination development of society,economy,cultivated land,water resources,and environment.In this study,the technological support and the decision-making for the rational use of CL-WR are provided not only in Bijie,but also in other similar regions of China.     

Development strategy of efficient bio-methane system by focused utilization of distributed biomass

Bio-methane, as a promising renewable green energy, the component and thermal value of which are very close to that of natural gas, indicates an enormous resource potential and could be employed as the al- ternative of fossil energy through the development of agro-industrial integration and efficient bio-methane sys- tem. Establishment of high efficient agro-industrial integrated bio-methane system is an important component of the renewable energy system and also a significant way of emission reduction.     

Strategy research on new urban space development and new deepwater terminal in Hengsha

From a strategic perspective, the paper presents a forward-looking thinking supported by interdisci- plinary of modern logistics, estuary and coast, environment and ecology, economic management and mathematical statistics. It leads to a reasonable solution to space expansion by reclamation. Construction of new deepwater terminal is the best usage of land resources and can strengthen the status of Shanghai as an international shipping center, thus support the preparation and strategic decision of future urban development of Shanghai.     

Polycaprolactone grafting of cellulose nanocrystals in ionic liquid [BMIM]Cl

A polycaprolactone-graffed cellulose nanocrystal （PCL-g-CN） was prepared in ionic liquid and characterized by Fourier transform infrared spectrum （FT-IR）, X-ray diffraction （XRD）, and transmission electron microscopy （TEM）. A peak assigned to the carbonyl group appears at 1 730 cm-1 in the FT-IR of PCL-g-CN, which confirms that the grafting reaction is suc- cessfully completed. The morphologies of PCL-g-CNs still main- tain rod-like structure according to the TEM images. XRD results show that the crystal type of the PCL-g-CNs changed from cellu- lose I to cellulose II. The reasons for crystal transition of CNs turn out to be combined effects of anion and cation in ionic liquid with CNs.     

Microstructure, crystallography and nucleation mechanism of NANOBAIN steel

The microstructure of bainite ferrite in NANOBAIN steel transformed at different temperatures was investigated by scanning electron microscopy, transmission electron microscopy, electron back-scattered diffraction, and vickers hardness tester in detail. It is found that the average width of bainitic ferrite (BF) plates can be refined to be thinner with the reduction of temperature (473–573 K), and the bainitic ferrite plates can reach up to 20–74 nm at 473 K. Crystallographic analysis reveals that the bainitic ferrite laths are close to the Nishiyama-Wasserman orientation relationship with their parent austenite. Temperature shows a significant effect on the variant selection, and a decrease in temperature generally weakens the variant selection. Thermodynamic analyses indicates that the Lacher, Fowler and Guggenheim (LFG) model is more suitable than the Kaufman, Radcliffe and Cohen (KRC) model dealing with NANOBAIN steel at a low temperature range. The free energy change ΔGγ→BF is about ?1500 J·mol?1 at 473 K, which indicates that nucleation in NANOBAIN steel is the shear mechanism. Finally, the formation of carbon poor regions is thermodynamically possible, and the existence of carbon poor regions can greatly increase the possibility of the shear mechanism.     

Cache performance optimization of irregular sparse matrix multiplication on modern multi-core CPU and GPU

This paper focuses on how to optimize the cache performance of sparse matrix-matrix multiplication （SpGEMM）.It classifies the cache misses into two categories：one is caused by the irregular distribution pattern of the multiplier-matrix,and the other is caused by the multiplicand.For each of them,the paper puts forward an optimization method respectively.The first hash based method removes cache misses of the 1 st category effectively,and improves the performance by a factor of 6 on an Intel 8-core CPU for the best cases.For cache misses of the 2nd category,it proposes a new cache replacement algorithm,which achieves a cache hit rate much higher than other historical knowledge based algorithms,and the algorithm is applicable on CELL and GPU.To further verify the effectiveness of our methods,we implement our algorithm on GPU,and the performance perfectly scales with the size of on-chip storage.     

A study on the characterization of smoke movement in shafts with different fire source positions

In this study, experimental and numerical simulation methods were combined to simulate the changing course of the temperature and velocity fields in nine different fire scenes. The characteristics of smoke movement in shafts with different fire source position factors （h/H） were quantitatively investigated, and the non-dimensional fitting function between the fire source position factors and the maximum temperature was deduced. The results showed that the location of the neutral plane moved upward as the fire source rose, and all the generated smoke spread to the upper areas; however, there was barely any smoke in the lower areas. The maximum temperature was inversely proportional to the fire source position factor; the higher the source position is, i.e. the higher the ra- tio factor is, the lower the maximum temperature is in the shaft. The experimental verification of the fire dynamics simulator （FDS） showed good results.     

Full-scale model tests and nonlinear analysis of prestressed concrete simply supported box girders

Full-scale model tests were carried out on a 30 m span prestressed concrete box girder and a 20 m span prestressed concrete hollow slab. Failure models were prestressed reinforcement tensile failure and crashing of roof concrete, respectively. The ductility indexes of the box girder and hollow slab were 1.99 and 1.23, respectively, according to the energy viewpoint. Based on the horizontal section hypothesis, the nonlinear computation procedure was established using the limited banding law, and it could carry out the entire performance analysis including the unloading, mainly focusing on the ways to achieve the unloading curves computation through stress-strain, moment-curvature and load-displacement curves. Through the procedure, parameters that influence on the bearing capacity, deformation performance and ductility of the structures were analyzed. Those parameters were quantity of prestressed reinforcement and tension coefficients of prestressed reinforcement. From the analysis, some useful conclusions can be obtained.