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1.
在低温Ar和O2基质隔离条件上分别测定了asym-N2O4的红外光谱。利用量经学从计算,在MP2水平上以6-31G^*和6-311G^*为基组,得到了asym-N2O4的结构参数和振动频率,结合计算结果,对实验观察到的asym-N2O4吸收峰进行了归属。采用355nm脉冲激光光解的方法,分别测定了在Ar和O2基质中asym-N2O4光解的产物,并对反应机理进行了讨论。  相似文献   

2.
采用振荡培养方法,研究了松密环菌ns1的生理生化特性,结果表明,松密环菌以葡萄糖为碳源,(NH4)2SO4和(NH4)H2PO4为氮源,C、N质量比为10:1和16:1以及PH5-5.5,培养摇床转速80-10r/min,矿物质和生长因子的需要,在25-27℃培养下96h时最佳,其菌丝体产量最高, 为2-325g/L。  相似文献   

3.
超高压脉冲综合治理SO2,NOx和CO2气体   总被引:3,自引:0,他引:3  
应用超高压脉冲电晕放电在ns数量级内产生“爆炸”式的巨大能量,使反应器内的SO2、NOx、CO2分子获得了活化能,几乎全部成为活化分子,在定向反应作用下分解成气体分子O2、N2和固体微粒S、C。在180℃的常压条件下气体分解率均在75% ̄90%。  相似文献   

4.
氮素形态及配比与大白菜体内硝酸盐的积累   总被引:1,自引:0,他引:1  
水培结果表明:氮素用量为210.6mg/l时,随NO3-N浓度的降低和NH4-N浓度的增加,地上干重显著降低,抑制体内硝酸盐、K、Mg、Cu的积累.有利于Fe、Zn的积累。随NO3-N浓度的降低和CO(NH2)2-N浓度的增加,地上干重有明显的单峰值,抑制体内硝酸盐、Mg、Mn的积累,有利于Fe的积累。在NO3-N:CO(NH2)-N为50:50(%)时,地上干重最大,并且硝酸盐含量符合绿色大白菜的基本规格。  相似文献   

5.
报道了偶氮化合物p-H21C10O-C6H4-N→‖N-C6H4-COOCh,亚胺化合物p-H21C10O-C6H4-CH→‖N-C6H4-COOCh,酯类化合物p-H21C10O-C6H4-COOCh,(Ch as the abbreviation of cholesteryl group)的合成,结构鉴定,以及DSC和偏光显微镜对其介晶性研究的结果,并对中心桥键对介晶性的影响进行了讨论。  相似文献   

6.
利用YAG脉冲激光器(脉宽为10ns,波长为1.06μm)对砷注入长波碲镉汞样品进行激光退火,分析离子注入及激光退火引起的样品电学性质的变化;通过对电导率-迁移率谱的研究,发现激光退火能够消除辐射损伤,并激活注入杂质。  相似文献   

7.
使用合成的钡镁锰矿(TODOROKITE)、碱硬锰矿(HOLLANDITE)型的MnO2及电解MnO2修饰碳膏电极,报告了它们在+1.0V ̄-1.0V电压范围和0.1M KCl溶液中的循环伏安图。Todorokite和hollandite的循环伏安图相似,都没有显明的电流峰。而电解MnO2的循环伏安图中,有两个阳极峰(+0.1V,+0.5VvsSCE)两个阴极峰(0.0V,-0.15V vs SX  相似文献   

8.
N2O2型Sc hiff碱配体和锰(Ⅲ)配合物的合成与光谱表征   总被引:1,自引:1,他引:0  
报道了8 个水杨醛及邻香草醛与二胺缩合生成的Schiff碱与锰(Ⅲ)的配合物:[Mn(salpn)Cl],[Mn(salipn)Cl],[Mn(vanipn)Cl],[Mn(salen)(H2O)]ClO4,[Mn(vanen)(H2O)2]2(ClO4)2(H2O)2,[Mn(vanipn)(H2O)2]2(ClO4)2(H2O)2,[Mn(salen)(NCS)],[{Mn(osalphen)(NCS)}{Mn(salphen)(NCS)(DMF)}](其中sal为水杨醛,van 为邻香草醛,en 为乙二胺,pn 为1,3丙二胺,ipn 为1,2丙二胺,ophen 为邻苯二胺).对所有的配合物进行了元素分析.对配合物中的ν(C= N),δ1(CH3,CH2),δ2(CH3,CH2),ν(C- N),ν(C= C),ν(Mn- O)以及DMF和ClO-4 、NCS- 的振动吸收进行了归属.紫外光谱测试表明,配合物中存在着芳环的π→π,金属到配体的CT电荷转移跃迁,C= N的π→π以及d→π跃迁.磁距测定表明,配合物的中心离子为d4 锰(Ⅲ)高自旋的电子结构.  相似文献   

9.
通过与热氧化n-MOSFET’s 比较,调查了N2 O氮化 (N2ON) n-MOSFET’s 在最大衬底电流IB m ax和最大栅电流IG m ax 应力下的低温热载流子效应.结果表明,N2ON 器件在低温就像在室温一样呈现出大大抑制的热载流子应力感应退化的特性;低温下产生的浅能级陷阱增强了器件的退化,N2 O 的氮化也大大减少了浅能级陷阱的产生.  相似文献   

10.
使用合成的钡镁猛矿(TODOROKITE),碱硬猛矿(HOLLANDITE)型的MnO2及电解MnO2修饰碳膏电极,报告了它们在+01V~-01V电压范围和01MKCl溶液中的循环伏安图。Todorokite和holandite的循环伏安图相似,都没有显明的电流峰。而电解MnO2的循环伏安图中,有两个阳极峰(+01V,+05VvsSCE)两个阴极峰(00V,-015VvsSCE)。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

15.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

18.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

19.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

20.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

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