黑碳气溶胶研究新进展

黑碳气溶胶是气溶胶的重要组成部分,在大气物理、大气化学、大气光学、大气光化学等过程中具有重要作用。近年来研究表明,黑碳气溶胶对于全球变暖、区域气候变化有重要贡献,黑碳气溶胶可能是影响全球变暖的第二大重要因子,其作用仅次于CO2。因此,应控制黑碳的排放。考虑到黑碳气溶胶在全球变暖、区域气候、环境与健康等方面的作用,研究和评价黑碳气溶胶的作用已十分必要和迫切。     

东亚高空大气气溶胶的分布及沙尘输送特征研究

利用长达20 年的SAGEⅡ(stratospheric aerosol and gas experimentⅡ) 资料, 研究了东亚地区5.0 ～15.0 km 高空气溶胶多年时空分布特征和变化趋势, 并研究了东亚沙尘活动对高空及下游的气溶胶输送。发现东亚高空气溶胶水平分布呈现上中下3 层不同的分布特征, 下层 5. 0 ～8. 5 km 高值区对应气溶胶源区青藏高原和西北沙漠地区;中层 9. 0 ～10. 0 km 高值区对应温带气旋高发的中纬度地区;上层 10. 5 ～15. 0 km 表现为低纬气溶胶含量显著高于高纬地区。高空各层气溶胶的空间分布受天气系统的影响具有明显的季节变化。近10 年来东亚高空气溶胶呈减少趋势, 平均光学厚度约下降了0. 016。另外还发现沙尘活动与 5. 0 ～11. 5 km 范围内的气溶胶显著相关, 反映沙尘活动影响的高度范围可以达到整个对流层。定义沙尘暴高空影响指数, 用来分析东亚沙尘暴对下游地区的影响, 发现随着时间推移沙尘逐渐向东移动, 在约 12 天之后可以到达大西洋。     

Speciation of the elements and compositions on the surfaces of dust storm particles： The evidence for the coupling of iron with sulfur in aerosol during the long-range transport

The speciation of the elements on the surface of the particles collected during dust storm and non-dust storm in Beijing and Inner Mongolia was studied by XPS. The major species of iron on the surface were oxides, sulfate, silicate,FeOOH and minor part sorbed on SiO2/Al2O3. Sulfate is the dominant species of sulfur on the surface. SiO2 and Al2O3 are the main components of Si and Al on the surface respectively.One of the most important findings was that the Fe(Ⅱ) (FeS and FeSO4) produced could account for up to 44.3% and 45.6% of the total Fe on the surface in the aerosol sample collected at that night and next day of the “peak” time of the dust storm occurring on March 20, 2002, while Fe2(SO4)3,one of the Fe(Ⅲ) species on the surface decreased from 67.1% to 49.5% and 48.0% respectively. Both S and Fe enriched on the surface of aerosol particles. Fe(Ⅱ) accounted for 1.3%-5.3% of total Fe in bulk aerosol samples during dust storm. These results provided strong evidence to support the hypothesis of the coupling between iron and sulfur in aerosols during the long-range transport, which would have important impact on the global biogeochemical cycle.     

我国春季大气沙尘气溶胶分布和短波辐射效应的数值模拟

利用已建立的区域气候模式与大气化学模式耦和的模拟系统 ,在气候模式中引入了起沙机制 ,同时建立了与气候模式连接的沙尘气溶胶输送模式 ,模拟沙尘的输送、扩散、沉降等过程 .通过对 1 998年 4月的模拟 ,分析得到中国地区沙尘气溶胶的主要源区分布情况、沙尘的浓度分布特点和光学厚度特征 ,并且将一次沙尘暴个例与同期卫星观测的气溶胶指数分布做了对比 .进一步模拟了沙尘气溶胶辐射效应 ,发现沙尘气溶胶能减少地面的辐射净收入 ,使南方的大气辐射收入减少 ,使北方的大气辐射收入增加 .由于沙尘气溶胶对辐射的削弱使地面气温有显著降低     

Dust storms and loess accumulation on the Tibetan Plateau：A case study of dust event on 4 March 2003 in Lhasa

Whether the Tibetan Plateau is a significant dust source area is of great importance, because this is related to the understanding of sources, accumulation and environmental effects of dusts on the Tibetan Plateau and inthe Far East-Pacific Ocean regions as well as to the evointion of coupling of the Tibetan Plateau and atmaspbere-oeean-continent exchange. Synoptic dynamics and remote sensing tracing of a dust storm on 3 to 5 March, 2003 in Lhasa onSouth Tibet demonstrate that the Tibetan Plateau possessesall factors and conditions of generating dust storms. Accompanied with this dust storm is a strong ascending stream onthe Plateau which has raised various sizes of durst particlesinto different levels. The lifted coarse particles were largelyfallen down and accumulated as loess on the eastern TibetanPlateau, and the fine particles were translated by the westerly jet and subsided in the northern Pacific Ocean. The spa-tial-temporal distribution of dust-storms between years 1961and 2000 ou the Plateau shows that duststorms mainly occurin winter and early spring with high frequency, and tile pathof dust storm moves gradually from south to north, which isclosely coupled with the northward moving of the westerlyjet from winter to spring over the Tibetan Plateau. Com-pared with other twelve dust source areas in China. the Ti-betan Plateau is one of the key dust souree areas for thelong-distance transport because its high occurring frequencyand elevation cause fine particles easily to be lifted into thezone of the westerly jet.     

U-Pb ages of zircon grains reveal a proximal dust source of the Xiashu loess,Lower Yangtze River region,China

Deciphering the eolian sources is critical to understand the paleo-significance of the Quaternary eolian deposits （the Xiashu loess） in the lower reaches of the Yangtze River. Both a local source from the fluvial sediments of the Yangtze River and a distal source from the northern deserts similar to that of the loess on the Chinese Loess Plateau （CLP） have been proposed. Recent researches show great advantages of detrital zircon ages as a source tracer for Asian dust based on the laser ablation U-Pb isotopic dating technique. This work presents the U-Pb ages of zircon grains extracted from the Xiashu loess. The results indicate that the Xiashu loess has a very different age distribution of zircon grains from that of the loess on the CLP as well as the materials in the arid lands of the Asian Interior. Instead, the zircon ages of the Xiashu loess are indistinguishable from the fluvial sediments of the Yangtze River, indicating the dominance of proximal dust source. Proximal source of the Xiashu loess implies that extensive eolian processes might have existed in the currently wet South China, possibly in response to the full glacial conditions after the middle Pleistocene transition of global climate.     

Analysis of carbon isotopes in airborne carbonate and implications for aeolian sources

Methods were developed to determine the mass ratios of carbon isotopes in trace amounts of aerosol carbonate. A Finnigan MAT 252 mass spectrometer fitted with an on-line Kiel device was to determine the ^13C/^12C ratio in CO2 produced from the carbonate. A study using these methods was conducted to characterize the carbonate carbon isotopes in aerosol samples collected in Xi‘an on dusty and normal days during March and April 2002. Results of the study demonstrate that insights into the origin of the dust can be deduced from its isotopic composition. That is, the δ^13C ofcarbonate for dust storm samples ranged from -1.4‰ to -4.2‰, and this is consistent with sandy materials in dust source regions upwind. In contrast, for non-dusty days δ^13C ranged from -7.5% to -9.3‰, which is more similar to fine particles emitted from local surface soils. Comparisons of dust storm aerosols with surface soils from source regions and with aerosol samples collected downwind indicate that the δ^13C values did not change appreciably during longrange transport. Therefore, carbon isotopes have the potential for distinguishing among source materials, and this approach provides a powerful new tool for identifying dust provenance.     

全球变暖背景下内蒙古地区沙尘暴频次变化的预估

构建一个基于BP神经网络的统计模型,利用CMIP5模式中历史情景和未来情景的预估数据,重建1860—2100年内蒙古地区春季沙尘暴频次(分辨率达到日尺度)序列.在此基础上,研究内蒙古地区沙尘暴未来长期变化特征.结果表明,在未来情景RCP2.6和RCP8.5中,与历史时期(1860—2005年)相比,内蒙古地区沙尘暴频次...     

Estimation of the rational water area for controlling wind erosion in the dried-up basin of the Ebinur Lake and its effect detection

The Ebinur Lake region was described as a ＂Green Labyrinth＂ in ＂Xinjiang Map Records： Records of Rivers＂ published in 1910, however, the ecology and environment in the region have been seriously degenerated due to the impacts of human activities during the recent 40 years. A dried-up lake basin with an area of 107.4 km^2 forms in its northwestern part, is covered by unconsolidated silt deposit without vegetation, and has become one of the main dust sources of dust weathers in north Xinjiang, and the dust with an annual amount of 4.8×10^6 t is blown out of the region by strong winds from the Alataw mountain-gap where there are 164 days occurring strong winds in a year. The rational water area and inflow of the Ebinur Lake for improving the ecology in the lake region and effectively controlling wind erosion in the dried-up lake basin are estimated using the water balance equation after analyzing the current ecological problems and the relationship between the granular composition of deposit in the dried-up lake basin and the dust weathers, and the ecological effects in recent years are monitored. It is considered that the water area of the Ebinur Lake for improving the ecology in the lake region and effectively controlling wind erosion in the dried-up lake basin should be 800 km^2at least, and the annual volume of surface runoff and groundwater recharging the lake should be over 7.92×10^8 m^3.     

Size distribution and element composition of dust aerosol in Chinese Otindag Sandland

Dust aerosol is one important component of atmos-pheric aerosols, and plays important roles in the Earth’s climate system and the biogeochemical cycle. Large amounts of dust aerosols produced from windblown soils and deserts are emitted annually into the atmosphere and transported over long distance to downwind land and ocean areas[1]. The deserts and desertification soils in northern China are important sources of East Asia dust aerosols. It is estimated that 800 Mt of dust aerosols emit-t…     

Dust direct radiative effects on the earth-atmosphere system over east Asia: Early spring cooling and late spring warming

Focusing on three dust storms occurring in spring 2001,we developed a detailed aerosol parameterization scheme and integrated it in a radiative transfer model to characterize possible impacts of solar altitude angle on dust direct radiative effects over China desert regions and the North Pacific,using actual daily solar altitude angles.Increasing solar altitude angle from early spring (or winter) to late spring (or summer) leads to increase of positive clear sky radiative forcing,and decrease of negative radiative forcing due to dust aerosols at the top of the atmosphere.Because solar altitude angle increases from early to late spring,dust-clear sky radiative forcing may change from negative to positive at the top of atmosphere,showing a change from cooling to heating of the earth-atmosphere system over high-albedo deserts and nearby regions.Over low-albedo ocean negative clear sky radiative forcing by dust may decrease,suggesting a change from strong to weak cooling on the earth-atmosphere system.The impacts of solar altitude angle on cloudy sky radiative forcing due to dust are similar to those of clear sky.Impacts of low cloud on dust radiative forcing are the same as increasing surface albedo.This causes the transition of dust cooling effects into heating effects over deserts to occur earlier,and causes decrease of negative radiative forcing over the ocean and even cause a change from weak negative radiative forcing to weak positive forcing over local areas.Even in the same East Asian desert regions and nearby areas,the strength and sign of the radiative forcings depend on storm dates and thus solar altitude angle.The nearer to early spring (or winter) a dust storm occurs,the easier it leads to negative radiative forcing at the top of atmosphere,which indicates cooling effects on the earth-atmosphere system.In contrast,the nearer to late spring (or summer) a dust storm occurs,the easier it leads to positive radiative forcing at the top of atmosphere,showing heating effects.Over East Asian deserts and nearby regions,dust layers may be regarded as cooling sources in early spring (winter) and warming sources in late spring (summer).     

色度分析在沙尘气溶胶成分分析中的应用

摘要：运用色度分析的方法分析不同月份降尘的组成．计算结果与通过元素分析方法的较一致,说明这种方法用于分析降尘的成分是可行的．与元素分析方法相比较,这一方法的优点在于能够计算不同月份降尘的组成,而元素分析法只能计算整体值．计算结果显示：兰州市冬季(11～2月)大气降尘以污染物为主要成分,所占比例为77．78％．这一期间污染物的沉降量占全年的57．5％．兰州市沙尘暴影响最为严重的时期为春季的3,4月份,其这一期间的沙尘降尘量占到了全年沙尘沉降量的48．9％,在当月降尘中沙尘所占比例分别为67．7％和71．7％．     

兰州皋兰山顶春季大气气溶胶的监测与分析

对兰州皋兰山顶春季大气气溶胶连续采样,得到了大气背景、浮尘、扬沙、沙尘暴等不同天气条件下的气溶胶质量浓度．通过沙尘天气的过程分析,得到不同沙尘天气条件下,TSP浓度的时间变化规律．与兰州大学小二楼顶的监测数据进行比较分析,可以看出兰州市的污染状况和TSP的时空分布．通过各类沙尘天气不同粒径气溶胶粒子的浓度分析,发现气溶胶粒子粒径的分布规律和气溶胶来源不同．