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1.
作者首次发现了Si3N4-MgO-CeO2系陶瓷在烧结过程中玻璃相自动析晶这一独特现象.对于Si3N4-MgO-CeO2系陶瓷在1450℃,MgO-CeO2就会与Si3N4颗粒表面的SiO2反应形成硅酸盐液相,冷却后则成为玻璃相保留在烧结体中;当烧结温度高于1550℃时,作者发现,CeO2仍留在玻璃相中,但MgO会自动析晶出来,其结果是大大减少了烧结体中严重影响其高温性能的玻璃相的含量,对于提高烧结氮化硅陶瓷的高温性能有重要作用  相似文献   

2.
超高压烧结Si3N4陶瓷断口形貌与韧性的研究   总被引:1,自引:1,他引:0  
研究不同制作条件下Si3N4陶瓷断口形貌与韧性的关系,当温度在1160~1340℃烧结时断口平面凹凸不平起伏很大,具有较好的韧性.当加入烧结助剂总量达质量百分数9%时,过多的烧结助剂会形成低熔点化合物存在于片层组织之间,降低了Si3N4陶瓷的强度与韧性.  相似文献   

3.
综述了SiC颗粒弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp含量对材料显微结构和力学性能的影响,对SiCp弥散强化Si3N4基陶瓷材料的强化效果和强化机理进行了初步的分析  相似文献   

4.
综述了SiC闰弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨。将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析,通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp一地  相似文献   

5.
ZrO2对Si3N4陶瓷烧结性能的影响   总被引:2,自引:0,他引:2  
对添加ZrO伯Si3N4陶瓷烧结性能的研究表明,一方面ZrO2可作为一种烧结助剂,促进液相烧结;另一方面它也以四方相形式弥散分布于Si3N4晶粒间,以提高材料的强韧性,试验结果表明:常压烧结下,ZrO2的质量分数为0.18时,材料强韧性最好。  相似文献   

6.
自韧化氮化硅陶瓷研究   总被引:4,自引:0,他引:4  
对热压烧结自韧化Si3N4陶瓷的工艺参数诸如助烧剂量,烧结时间和温度等与材料显微组织,相组成及力学性能间的关系进行了研究。在致密化前提下且烧剂量较少时,有利于材料显微组织的均匀化和力学性能的提高。  相似文献   

7.
Si3N4-MgO-CeO2陶瓷烧结过程中的致密化与相变   总被引:3,自引:0,他引:3  
氮化硅陶瓷有极大的应用潜力,但由于其强共价键,很难烧结致密化。采用了一种新的MgO-CeO2复合烧结助剂,利用X射线衍射、透射电镜等手段研究了MgO-CeO2复合烧结助剂对氮化硅陶瓷致密化和相变过程的影响,结果发现对Si3N4-MgO-CeO2陶瓷,在1450℃就会有大量液相出现,1500~1550℃为快速致密化阶段,而α-Si3N4→β-Si3N4相变主要发生在1550~1600℃,相变过程滞后于致密化过程。常压烧结Si3N4-MgO-CeO2陶瓷,强度达948MPa,因此,MgO-CeO2是一种非常有效的氮化硅的烧结助剂。  相似文献   

8.
测定了销-盘式热压Si3N4/3Cr2W8V钢摩擦副在室温干摩擦磨损条件下的摩擦系数及Si3N4销的磨损系数,对陶瓷销的磨损面进行了SEM显微形貌观察,X射线分析;并探讨了陶瓷销的磨损机理。研究结果表明:Si3N4陶瓷的磨损以微区脆性断裂为主要机理。  相似文献   

9.
测定了销-盘式热压Si3N4/3Cr2W8V钢摩擦副在室温干摩擦磨损条件下的的摩擦系数及Si3N4销的磨损系数.对陶瓷销的磨损面进行了SEM显微形貌观察、X射线分析;并探讨了陶瓷销的磨损机理.研究结果表明:Si3N4陶瓷的磨损以微区脆性断裂为主要机理.  相似文献   

10.
重点研究了Al2O3 /ZrSiO4 富铝体系反应烧结制备过程中的晶相变化,以及Al2O3/SiO2 比对反应烧结的影响,进而研究了添加Cr2O3 对反应烧结的影响.研究表明,在反应烧结过程中,莫来石的生成明显滞后于ZrSiO4 的分解;在相同温度下,ZrSiO4 的分解程度随Al2O3 的加入量的增加而提高.添加Cr2O3 使莫来石的稳定生成温度提高,此外,Cr2O3 的引入有助于Al2O3 向莫来石中的固溶  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

18.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

19.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

20.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

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