具有良好可再生性的新型二氧化硅磁性氧化石墨烯纳米复合材料

Graphene oxide (GO) wrapped Fe₃O₄ nanoparticles (NPs) were prepared by coating the Fe₃O₄ NPs with a SiO₂ layer, and then modifying by amino groups, which interact with the GO nanosheets to form covalent bonding. The SiO₂ coating layer plays a key role in integrating the magnetic nanoparticles with the GO nanosheets. The effect of the amount of SiO₂ on the morphology, structure, adsorption, and regenerability of the composites was studied in detail. An appropriate SiO₂ layer can effectively induce the GO nanosheets to completely wrap the Fe₃O₄ NPs, forming a core-shell Fe₃O₄@SiO₂@GO composite where Fe₃O₄@SiO₂ NPs are firmly encapsulated by GO nanosheets. The optimized Fe₃O₄@SiO₂@GO sample exhibits a high saturated adsorption capacity of 253 mg·g?1 Pb(II) cations from wastewater, and the adsorption process is well fitted by Langmuir adsorption model. Notably, the composite displays excellent regeneration, maintaining a ~90% adsorption capacity for five cycles, while other samples decrease their adsorption capacity rapidly. This work provides a theoretical guidance to improve the regeneration of the GO-based adsorbents.     

微波预处理对复杂铜矿磨矿及浮选动力学的影响

The effect of CaCO₃, Na₂CO₃, and CaF₂ on the reduction roasting and magnetic separation of high-phosphorus iron ore containing phosphorus in the form of Fe₃PO₇ and apatite was investigated. The results revealed that Na₂CO₃ had the most significant effect on iron recovery and dephosphorization, followed by CaCO₃, the effect of CaF₂ was negligible. The mechanisms of CaCO₃, Na₂CO₃, and CaF₂ were investigated using X-ray diffraction (XRD), scanning electron microscopy and energy dispersive spectrometry (SEM–EDS). Without additives, Fe₃PO₇ was reduced to elemental phosphorus and formed an iron–phosphorus alloy with metallic iron. The addition of CaCO₃ reacted with Fe₃PO₇ to generate an enormous amount of Ca₃(PO₄)₂ and promoted the reduction of iron oxides. However, the growth of iron particles was inhibited. With the addition of Na₂CO₃, the phosphorus in Fe₃PO₇ migrated to nepheline and Na₂CO₃ improved the reduction of iron oxides and growth of iron particles. Therefore, the recovery of iron and the separation of iron and phosphorus were the best. In contrast, CaF₂ reacted with Fe₃PO₇ to form fine Ca₃(PO₄)₂ particles scattered around the iron particles, making the separation of iron and phosphorus difficult.     

不同硅饱和系数水榴石的碳酸化分解动力学

Carbonated decomposition of hydrogarnet is one of the vital reactions of the calcification–carbonation method, which is designed to dispose of low-grade bauxite and Bayer red mud and is a novel eco-friendly method. In this study, the effect of the silica saturation coefficient (x) on the carbonation of hydrogarnet was investigated from the kinetic perspective. The results indicated that the carbonation of hydrogarnets with different x values (x = 0.27, 0.36, 0.70, and 0.73) underwent two stages with significantly different rates, and the kinetic mechanisms of the two stages can be described by the kinetic functions R3 and D3. The apparent activation energies at Stages 1 and 2 were 41.96–81.64 and 14.80–34.84 kJ/mol, respectively. Moreover, the corresponding limiting steps of the two stages were interfacial chemical reaction and diffusion.     

一种超重力燃烧合成制备高性能高熵合金的新方法

A new method of high-gravity combustion synthesis (HGCS) followed by post-treatment (PT) is reported for preparing high-performance high-entropy alloys (HEAs), Cr_0.9FeNi_2.5V_0.2Al_0.5 alloy, whereby cheap thermite powder is used as the raw material. In this process, the HEA melt and the ceramic melt are rapidly formed by a strong exothermic combustion synthesis reaction and completely separated under a high-gravity field. Then, the master alloy is obtained after cooling. Subsequently, the master alloy is sequentially subjected to conventional vacuum arc melting (VAM), homogenization treatment, cold rolling, and annealing treatment to realize a tensile strength, yield strength, and elongation of 1250 MPa, 1075 MPa, and 2.9%, respectively. The present method is increasingly attractive due to its low cost of raw materials and the intermediate product obtained without high-temperature heating. Based on the calculation of phase separation kinetics in the high-temperature melt, it is expected that the final alloys with high performance can be prepared directly across master alloys with higher high-gravity coefficients.     

窄板坯结晶器内连铸工艺参数对钢液流场的影响

Computational simulations and high-temperature measurements of velocities near the surface of a mold were carried out by using the rod deflection method to study the effects of various operating parameters on the flow field in slab continuous casting (CC) molds with narrow widths for the production of automobile exposed panels. Reasonable agreement between the calculated results and measured subsurface velocities of liquid steel was obtained under different operating parameters of the CC process. The simulation results reveal that the flow field in the horizontal plane located 50 mm from the meniscus can be used as the characteristic flow field to optimize the flow field of molten steel in the mold. Increases in casting speed can increase the subsurface velocity of molten steel and shift the position of the vortex core downward in the downward circulation zone. The flow field of liquid steel in a 1040 mm-wide slab CC mold can be improved by an Ar gas flow rate of 7 L·min?1 and casting speed of 1.7 m·min?1. Under the present experimental conditions, the double-roll flow pattern is generally stable at a submerged entry nozzle immersion depth of 170 mm.     

电渣重熔脱硫技术研究进展

Electroslag remelting (ESR) gives a combination of liquid metal refining and solidification structure control. One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production is desulfurization. It involves two patterns, i.e., slag–metal reaction and gas–slag reaction (gasifying desulfurization). In this paper, the advances in desulfurization practices of ESR are reviewed. The effects of processing parameters, including the initial sulfur level of consumable electrode, remelting atmosphere, deoxidation schemes of ESR, slag composition, melting rate, and electrical parameters on the desulfurization in ESR are assessed. The interrelation between desulfurization and sulfide inclusion evolution during ESR is discussed, and advancements in the production of sulfur-bearing steel at a high-sulfur level during ESR are described. The remaining challenges for future work are also proposed.     

利用皮秒激光烧蚀制备非球形铝纳米颗粒

We report the picosecond laser ablation of aluminum targets immersed in a polar organic liquid (chloroform, CHCl₃) with ~2 ps laser pulses at an input energy of ~350 μJ. The synthesized aluminum nanoparticles exhibited a surface plasmon resonance peak at ~340 nm. Scanning electron microscopy images of Al nanoparticles demonstrated the spherical morphology with an average size of (27 ± 3.6) nm. The formation of smaller spherical Al nanoparticles and the diminished growth could be from the formation of electric double layers on the Al nanoparticles. In addition to spherical aluminum nanoparticles, triangular/pentagonal/hexagonal nanoparticles were also observed in the colloidal solution. Field emission scanning electron microscopy images of ablated Al targets demonstrated laser induced periodic surface structures (LIPSSs), which were the high spatial frequency LIPSSs (HSF-LIPSSs) since their grating period was ~280 nm. Additionally, coarse structures with a period of ~700 nm were observed.     

Mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al2O3?Na2O system during high-temperature sintering

The mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al₂O₃?Na₂O system during the high-temperature sintering process were systematically investigated using DSC?TG, XRD, SEM?EDS, FTIR, and Raman spectra, and the crystal structure of Na₄Ca₃(AlO₂)₁₀ was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na₄Ca₃(AlO₂)₁₀, CaO·Al₂O₃, and 12CaO·7Al₂O₃, and the content of Na₄Ca₃(AlO₂)₁₀ could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na₄Ca₃(AlO₂)₁₀ occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na₄Ca₃(AlO₂)₁₀ was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na₄Ca₃(AlO₂)₁₀ was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.     

含细夹层的分矿充填层中流动特性的可视化

Ore particles, especially fine interlayers, commonly segregate in heap stacking, leading to undesirable flow paths and changeable flow velocity fields of packed beds. Computed tomography (CT), COMSOL Multiphysics, and MATLAB were utilized to quantify pore structures and visualize flow behavior inside packed beds with segregated fine interlayers. The formation of fine interlayers was accompanied with the segregation of particles in packed beds. Fine particles reached the upper position of the packed beds during stacking. CT revealed that the average porosity of fine interlayers (24.21%) was significantly lower than that of the heap packed by coarse ores (37.42%), which directly affected the formation of flow paths. Specifically, the potential flow paths in the internal regions of fine interlayers were undeveloped. Fluid flowed and bypassed the fine interlayers and along the sides of the packed beds. Flow velocity also indicated that the flow paths easily gathered in the pore throat where flow velocity (1.8 × 10?5 m/s) suddenly increased. Fluid stagnant regions with a flow velocity lower than 0.2 × 10?5 m/s appeared in flow paths with a large diameter.     

量子辛型群O（Spq（6））的一种实现

通过Uq（sp（6））的最高权模的自然表示理论,给出了量子辛型群O（Spq（6））的所有定义关系式。     

q形变量子群Rq（sl（2））的有限维单模

主要讨论单李代数U（sl（2））的一类新的q形变量子群Rq（sl（2））,Uq（sl（2））可以看作Rq（sl（2））的一个子代数.在复数域k上且q是本原的d次单位根的条件下给出Rq（sl（2））的有限维单表示的分类.     

Uq（Sp（2n））-模同构R= οf^-οP中 的简化

给出了Uq（Sp（2n））-模同构R= οf^-οP中 的一个简化表达式 ′,即 ′=1×1＋∑ht（μ）≥2 μ≠τ（μ）（q^-1-q）Fμ ×Eτ（μ）＋∑ht（μ）≥1（-1）^ht（μ）（1 -q^-2）qμFμ×Eμ＋∑μ=τ（μ）^μ≥α1（q^-2-1）（1 ＋qμ）Fμ×Eμ.     

Hopf*-代数的Ore扩张

对Hopf*-代数的Ore扩张何时保持*-结构给出了充分必要条件.讨论了群代数、量子群"ax+b"以及量子群Uq(sl(2))上的Hopf*-结构和Ore扩张.     

量子矩阵代数Mq(2)上有限维单模的一种分类

用初等的类似于量子群Uq(sl2)上有限维单模的分类方法, 给出了量子矩阵代数Mq(2)上有限维单模的一种分类。结果表明, 当q不是单位根时, Mq(2)上有限维单模仅有1维单模, 当q为r次单位根时(r为奇数), Mq(2)上所有单模都是有限维的, 且仅有1维与r维单模。     

量子群Uq(f(K,(K)))的弱Ore扩张及其弱Hopf代数结构

构造了一个新代数结构Uq(f(K,(K))),由满足一定关系的元E,F,K,(K)生成的结合代数,通过对其上的结构以及基本性质的讨论证明了Uq(f(K,(K)))是诺特环k[K,(K)]的弱Ore扩张,从而证明了Uq(f(K,(K)))是诺特环,并且进一步在弱Hopf代数意义下给出了Uq(f(K,(K)))具有弱Hopf代数结构的充要条件.     

量子包络代数Uq（sl2）的代数自同构

令Ｕｑ表示一个有限维单李代数ψ的普遍包络代数的量子化。文献「１」描述了代数Ｕｑ（ψ）的所有Ｈｏｐｆ－代数自同构。文献「２」确定Ｕｑ（ψ）的所有变形代数自同构，所谓变形代数自同构是指底下的单李代数ψ的自同构的形变。文中将确定代数Ｕｑ（ｓｌ２）的所有代数自同构。从而表明Ｕｑ（ｓｌ２）的所有代数自同构都是变形代数自同构。     

Ug（sl2）上的范畴O的一点注记

有学者研究了有限维半单李代数上的范畴O表示，受此启发，本文定义了Uq（sl2）上的范畴O，并且证明出范畴O是一个既是Noether范畴，又是一个Artin范畴，然后给出Uq（sl2）的中心特征标的定义，并利用它讨论了范畴O的分解，得到了一些有意义的结果。     

利用部分纠缠的量子信道确定性地实现N→1和1→N的受控量子远程旋转

提出利用部分纠缠的量子信道确定性地实现多个发送者1个接受者和1个发送者多个接受者的受控量子远程旋转方案.首先考虑利用两个(N?M?1)粒子部分纠缠的Greenberger-Horne-Zeilinger(GHZ)态确定性地实现N个发送者在M个监控者的控制下确定性地将她们的旋转分别传给远处接受者的操作(N→1).然后考虑在一个(2K?M?1)粒子部分纠缠的Einstein-Podolsky-Rosen(EPR)-GHZ态或K个(M+2)粒子部分纠缠的GHZ态辅助下,发送者随意地将她的旋转分为N份(NK)并在M个监控者的控制下确定性地将它们分别传给远处N个接受者的操作(1→N).方案中,量子旋转的发送者或接受者或监控者的正定算符值测量(POVM)起着关键作用,我们给出了它们的数学表式.值得注意的是,用非理想的量子信道可确定性地实现N→1或1→N的量子远程旋转.这些方案可用于量子秘密共享,量子选举等,它们具极强的保密性.     

硅量子点表面掺氮的电子结构计算

本文在量子点表面掺入氮原子,用第一性原理方法模拟计算硅量子点（111）面上的电子结构.本文主要解决两个问题：（1）比较研究六种不同大小的量子点结构掺杂和未掺杂氮原子情况下的带隙宽度和电子态密度变化;（2）分别用广义梯度近似（GGA）和局域密度近似（LDA）两种不同的算法计算六种量子点结构的带隙宽度和态密度,并比较GGA和LDA算法的特点.计算结果发现：带隙随着量子点的尺度变小而展宽,这符合量子受限规律;在量子点表面掺杂氮原子会减小带隙宽度;重要的是发现LDA算法对局域态更加敏感.