Zircon SHRIMP U-Pb age of garnet olivine pyroxenite at Hujialin in the Sulu terrane and its geological significance

Abundantbasic-ultrabasicbodiescropoutintheDabie-Suluultrahighpressure(UHP)metamorphicbeltandoccurasgroupandband.Muchresearchworkhasbeencarriedoutonthebasic-ultrabasicbodiesandmadeagreatprogressespeciallyonmineralogy.ThediscoveryofmineralassemblagesofUHPmetamorphismandexsolvedlamellaesuggestthattherocksmaycomefromthedeepmantleorwasonceemplacedintotheshallowlevelofthecrustandthensubductedtothemantledepthsduringsub-ductionofthecrust[1—13].However,theiroriginandtec-tonicsettingarestillacontrov…     

黑龙江金厂金矿花岗斑岩锆石地球化学、U-Pb年代学及地质意义

为确定与金厂金矿成矿有关的岩浆类型、活动时限和构造背景,采用LA-ICP-MS技术对研究区花岗斑岩开展了锆石U-Pb年龄及原位微区微量元素测定。结果表明:锆石环带发育,wTh/wU值>0.4,具有岩浆锆石特征;锆石年龄分布于220Ma和103～123Ma 2个区间,代表了2期岩浆事件;对2种锆石分别命名为捕获岩浆锆石和新生岩浆锆石;锆石的地球化学和年龄信息显示捕获岩浆锆石的原岩为早三叠世花岗岩;锆石微量元素信息暗示花岗斑岩是早三叠世花岗岩高度熔融结晶分异、侵位于浅部氧化环境而形成,这一过程导致新生岩浆锆石负Eu异常程度降低。新生锆石加权平均年龄为(113.5±3.8)Ma,与成矿年龄一致,据此认为早白垩世的岩浆事件是金厂金矿成矿事件的直接原因,成矿背景为太平洋板块俯冲后的岩石圈伸展。     

鲁米诺-铁氰化钾流动注射化学发光体系研究

采用流动注射-化学发光(FI-CL)联用技术系统研究了19种酚类化合物对鲁米诺-铁氰化钾(lumi-nol-K3Fe(CN)6)体系化学发光的影响,发现其大部分能抑制或增强体系化学发光强度,且抑制或增强化学发光强度的能力与化学发光体系溶液的介质、pH值以及酚类化合物的浓度、分子结构等有关;根据化学发光光谱和紫外-可见吸收谱,讨论了体系化学发光强度抑制或增强的机理,推测抑制或增强可能是由于酚类化合物的氧化反应及瞬时产物影响了鲁米诺化学发光反应通道;若联接分离技术,鲁米诺-铁氰化钾流动注射化学发光体系具有同时测定数个酚类有机化合物的潜力.     

化学发光成像分析法检测健康食品中的褪黑激素

基于在碱性介质中,褪黑激素对H2O2与MoO42-反应产生的微弱化学发光信号有较强的增敏作用,利用高灵敏度、高分辨率的成像分析仪检测发光信号,建立了一种简单、高通量的检测褪黑激素的分析方法并将该方法用于健康食品脑白金中褪黑激素含量的测定。     

Zircon LA-ICPMS study and petrogenesis simulation of Dahuabei pluton in the Wulashan area,Inner Mongolia

Dahuabei pluton in the Wulashan area,Inner Mongolia,is an alkaline and peraluminous granitic pluton.LA-ICPMS U-Pb dating of zircons indicates that this pluton crystallized at 330±10 Myr.The pluton did not experience apparent zircon fractionation.The consistent temperatures between Zr saturation (765℃) and the average zircon-rutile Ti equilibrium (780℃),together with zircon ages and their CL images,indicated that there were no inherited zircons in this pluton.Through the simulation of the dry-system crystallization process of magma cooling at 200 MPa and 1100-709℃,the phase diagram and composition evolution tendency of different phases were obtained.The magma reached its liquidus at 1069℃.Sanidine was the first crystallized phase;at 709℃ the residual magma was less than 4%,and the range of 1069-719℃ should be the most suitable approach to the real condition.It is shown that at least some part of the pluton underwent such isobaric equilibrium crystallization processes during its crystallization.     

秦皇岛柳江盆地混合花岗岩的锆石U-Pb定年

目的确定秦皇岛柳江盆地基底混合岩的年龄。方法在锆石阴极荧光内部结构研究的基础上,进行LA-ICP-MS锆石原位U-Pb定年。结果获得柳江盆地基底混合岩化作用发生的年代为2570-2 560 Ma。结论冀东地区华北地台的基底在2 560 Ma的晚太古代已经发育成熟。     

LA-ICP-MS zircon U-Pb dating for high-pressure basic granulite from North Qinling and its geological significance

Inrecentyears,discoveriesofhightoultrahighpressuremetamorphicrocksatthenorthandsouthsidesoftheQinlingGroupinthenorthernpartoftheQinlingMountains(hereafterNorthQinling)haveattractedfocusattentionofgeologistsworldwide.Thenorthhigh-pressure(HP)metamorphicbelt,distributedintheareafromGuanpotoShuanghuaishunorthwardtoShizipin,LushCountyinHenanProvince,consistsmainlyofeclogiteoutcroppedaslenticularmassesofdifferentsizesinthegneissesoftheQinlingGroupclosetothesouthsideofZhuyangguan-Xiaguanfault…     

激素类化合物对纳米金-酸性高锰酸钾体系化学发光影响

采用流动注射-化学发光(FI-CL)联用技术研究了己烯雌酚、硫酸特布他林对纳米金-酸性高锰酸钾体系化学发光的影响,发现该2种激素化合物能增强体系化学发光强度,并且增强化学发光强度能力与高锰酸钾及溶液的介质硫酸浓度、金浓度以及蠕动泵的转速等因素有关.基于2种激素化合物对体系化学发光的增强考察了其分析应用的可能性,若联接分离技术,纳米金-酸性高锰酸钾流动注射化学发光体系具有同时测定激素类化合物的潜力.讨论了化学发光强度增强的机理.     

Oscillating chemiluminescence in rhodamine B-induced Belousov-Zhabotinsky reaction catalyzed by Ce（IV）

It was found that rhodamine B could induce oscillating chemiluminescence （OCL） from the Ce4＋-catalyzed Belousov-Zhabotinsky reaction. This new OCL system, i.e., rhodamine B-malonic acid-bromate- Ce（IV）-sulfuric acid, exhibited two clearly distinguished emission peaks in each oscillation period. The initial concentrations of the reactants strongly influenced the oscillation pattern. For the study of the CL mechanism, a platform for a versatile and simultaneous potential and CL measurement was estab- lished to compare the potential oscillation with the CL oscillation behavior of this system. The CL spectra, UV-visible absorption spectra and time-resolved fluorescence spectra of this OCL system were studied. A possible, simplified mechanism for the OCL is proposed. It is suggested that the generation of the two CL peaks is likely due to the oxidation of the intermediate of rhodamine B by Ce（IV） and Br2, respectively. This work provided a new method and platform to research the complex chemical oscilla- tions.     

The thermal history of the miarolitic granite at Xincun, Fujian Province, China

The thermal history of the late Mesozoic miarolitic granite has been studied based on zircon U-Pb dating, whole rock Rb-Sr dating and K-Ar dating of muscovite, biotite and K-feldspar from the same rock sample. From the beginning of zircon crystallization to the closure of K-Ar system of biotite, the granite body had a slow cooling rate (11.0℃/Ma) and an ascending rate (0.07 mm/a). From the end of this stage to the closure of K-Ar system of K-feldspar, the granite body increased its cooling rate (45℃/Ma) and ascending rate (0.36 mm/a). The thermal history of the Xincun granite with a slow cooling rate at the early stage and a fast cooling rate at the late stage may have been related to the fact that the Fujian coastal area had very high geothermal gradient in the late Mesozoic and evident decrease in geothermal gradient in the early Cenozoic.     

在没有共存氧化剂时亚硫酸盐对鲁米诺化学发光的影响及其分析应用

亚硫酸盐在碱性条件下，产生化学发光，罗丹明6G可起增敏作用，在优化的实验条件下，亚硫酸盐的测定范围为0.05-2μg/mL，检出限为0.04μg/mL，对0.5μg/mL的亚硫酸盐进行11次测定，其RSD为2.1%。将本法用于酒中亚硫酸盐测定。结果令人满意。     

Genesis of zircon and its constraints on interpretation of U-Pb age

Zircon U-Pb dating is the most commonly used method for isotopic geochronology. However, it has been a difficult issue when relating zircon U-Pb ages to metamorphic conditions in complex metamorphic rocks. Much progress has been made in the past decade with respect to the genesis of zircon and its constraints on interpretation of U-Pb age. Three methods have been proposed to link zircon U-Pb age to metamorphic conditions: ( i ) internal structure; ( ii ) trace element feature; (iii) mineral inclusion composition. Magmatic zircon shows typical oscillatory zoning and/or sector zoning, whereas metamorphic zircon has internal structures such as no zoned, weakly zoned, cloudy zoned, sector zoned, planar zoned, and patched zoned ones. Zircons formed in different geological environments generally have characteristic internal structures. Magmatic zircons from different rock types have variable trace element abundances, with a general trend of increasing trace element abundances in zircons from ultramafic through mafic to granitic rocks. Zircons formed under different metamorphic conditions have different trace element characteristics that can be used to relate their formation to metamorphic conditions. It is an effective way to relate zircon growth to certain P-T conditions by studying the trace element partitioning between coexisting metamorphic zircon and garnet in high-grade metamorphic rocks containing both zircon and garnet. Primary mineral inclusions in zircon can also provide unambiguous constraints on its formation conditions. Therefore, interpretation of zircon U-Pb ages can be constrained by its internal structure, trace element composition, mineral inclusion and so on.     

Fluid inclusions hidden in coesite-bearing zircons in ultrahigh-pressure metamorphic rocks from southwestern Sulu terrane in eastern China

Fluidinclusionstudiesarepowerfultoolsfordeci-pheringthefluidevolutionandfluid-rockinteractionin-volvingultrahigh-pressure(UHP)metamorphismofcrustalrocksatmantledepths.Thecompositionandprop-ertiesoffluidinclusionscanreflectthephysico-chemicalconditionsofthefluidsduringplatesubduction,UHPmetamorphismandexhumation.However,UHPmeta-morphicrockscommonlyexperiencedconsiderablede-compressionrelatedtotherapidexhumationprocess.Thishascausedtheinternalpressureoftheinclusionstrappedinthemetamorphicmin…     

In-situ trace element analyses of zircons from Dabieshan Huangzhen eclogite: Trace element characteristics of eclogite-facies metamorphic zircon

The internal structures of zircons in eclogite from Huangzhen have been studied by cathodoluminescence(CL) microscopy. Two growth stages were distinguished:protolith magmatic cores and metamorphic overgrowthrims. These different domains were analyzed for trace ele-ments using LAM-ICP-MS. The protolith and theovergrowth zircons have different trace elements charac-teristics. The trace element contents of protolith zircons arehigh and very variable. The overgrowth zircons show a typi-cal trace element feature of equilibrium with garnet, e.g. lowcontents of HREE (132.2-197.6 ?g/g) and small differentialdegree of HREE ((Yb/Gd)CN=8.6-11.9). The contents of Nb,Ta and the ratio of Nb/Ta are lower in the metamorphic do-mains (0.5-1.4 ?g/g, 0.7-1.5 ?g/g, 0.3-1.3, respectively)than in the protolith domains (3.8-19.7 ?g/g, 2.7-12.1 ?g/g,1.0-4.6, respectively). This is the first time to give the evi-dence that the metamorphic zircon equilibrates with therutile, which formed during the peak metamorphic stage.The REEs and other trace elements data demonstrate that the metamorphic zircons overgrow in the eclogite-facies con-ditions. The trace element composition of zircon can there-fore give new ways to constrain their formation conditions.     

流动注射化学发光同时测定利福平和异烟肼

提出了一种基于人工神经网络的流动注射化学发光同时测定利福平(RFP)和异烟肼(INH)的新方法:在碱性条件下RFP和INH均可定量还原N-溴代丁二酰亚胺(NBS)产生化学发光,而二者的反应动力学光谱不同.通过测量不同反应时间的化学发光强度,用人工神经网络(ANN)建立校正模型并进行预测可同时测定RFP和INH.相比较已报道的同时测定RFP和INH的方法,本方法具有灵敏度高,简单快速等优点,并已成功地用于药物合剂中RFP和INH的同时测定.     

鲁米诺电生化学发光（ECL）系统研究初探

文章描述了一个新的鲁米诺电生化学发光流动系统。通过微铂电极流动池,H_2O_2被还原为OH~-,以维持鲁米诺化学发光所要求的pH条件。文章对鲁米诺化学发光机理进行了初步探讨,并详细研究了ECL的最佳条件。该系统明显降低了反应噪声,优于混合反应系统,可作为液相色谱间接测定检测器。     

ZnONPs增敏流动注射化学发光法检测雨水中的H2O2

基于ZnO纳米颗粒(ZnO nanoparticles,ZnO NPs)增敏luminol-H_2O_2化学发光,结合流动注射技术,研究建立一种简单、快速、灵敏地测定雨水中微量H_2O_2的方法。考察pH,ZnO NPs、luminol和H_2O_2浓度对化学发光的影响。在优化条件下,H_2O_2浓度在0.06~20μmol/L范围内,H_2O_2浓度的对数(lg c)和化学发光峰面积的对数(lg A)具有良好的线性关系,检出限(LOD)为0.016μmol/L(3σ)。将此方法应用于雨水中微量H_2O_2的测定,回收率为95%~102%,RSD(n=11)为2.41%。     

Identification of 3.5 Ga detrital zircons from Yangtze craton in south China and the implication for Archean crust evolution

The LA-ICP-MS U-Pb dating of hundreds of detrital zircon grains from the Sinian sandstones of Liantuo formation and tillites of Nantuo formation at Sanxia area in Yichang identified 3319?3508 Ma zircon grains. Their ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U ages show excellent agreement (concordia degree 99%?100%). Their CL images exhibit well-developed oscillatory zoning and the Th/U ratios are within 0.46?0.76, implying that they are igneous zircons which formed during middle-early Archean. These zircons are the oldest ones discovered in Yangtze craton until now. However, the detrital zircons with ages older than 3.3 Ga in the metamorphic rocks of Kongling group were not found by further investigation, which suggests the presence of crust older than high-grade metamorphic Kongling terrain in Yangtze craton.     

电力系统新型非线性励磁控制器

提出了一种非线性控制器的设计方法，所得到的新型励磁控制器是非线性的，由完全线性化（ＣＬ）补偿器和鲁棒最优输出反馈控制器组成，经过单机无穷大母线系统及多机等值模型的数字仿真和单机无穷大母线系统的动模实验，证实新型控制器在提高输电系统稳定性方面具有一系列突出的优越性。     

活性氯—过氧化氢氧化光泽精发光的研究

通过研究光泽精—H_2O_2和光泽精—ClO~-—H_2O_2化学发光反应的动力学曲线、吸收光谱以及化学发光光谱,提出了光泽精—ClO~-—H_2O_2化学发光反应的机理.还就温度和反应试剂的浓度对化学发光强度的影响进行了试验和讨论.