具有良好可再生性的新型二氧化硅磁性氧化石墨烯纳米复合材料

Graphene oxide (GO) wrapped Fe₃O₄ nanoparticles (NPs) were prepared by coating the Fe₃O₄ NPs with a SiO₂ layer, and then modifying by amino groups, which interact with the GO nanosheets to form covalent bonding. The SiO₂ coating layer plays a key role in integrating the magnetic nanoparticles with the GO nanosheets. The effect of the amount of SiO₂ on the morphology, structure, adsorption, and regenerability of the composites was studied in detail. An appropriate SiO₂ layer can effectively induce the GO nanosheets to completely wrap the Fe₃O₄ NPs, forming a core-shell Fe₃O₄@SiO₂@GO composite where Fe₃O₄@SiO₂ NPs are firmly encapsulated by GO nanosheets. The optimized Fe₃O₄@SiO₂@GO sample exhibits a high saturated adsorption capacity of 253 mg·g?1 Pb(II) cations from wastewater, and the adsorption process is well fitted by Langmuir adsorption model. Notably, the composite displays excellent regeneration, maintaining a ~90% adsorption capacity for five cycles, while other samples decrease their adsorption capacity rapidly. This work provides a theoretical guidance to improve the regeneration of the GO-based adsorbents.     

微波预处理对复杂铜矿磨矿及浮选动力学的影响

The effect of CaCO₃, Na₂CO₃, and CaF₂ on the reduction roasting and magnetic separation of high-phosphorus iron ore containing phosphorus in the form of Fe₃PO₇ and apatite was investigated. The results revealed that Na₂CO₃ had the most significant effect on iron recovery and dephosphorization, followed by CaCO₃, the effect of CaF₂ was negligible. The mechanisms of CaCO₃, Na₂CO₃, and CaF₂ were investigated using X-ray diffraction (XRD), scanning electron microscopy and energy dispersive spectrometry (SEM–EDS). Without additives, Fe₃PO₇ was reduced to elemental phosphorus and formed an iron–phosphorus alloy with metallic iron. The addition of CaCO₃ reacted with Fe₃PO₇ to generate an enormous amount of Ca₃(PO₄)₂ and promoted the reduction of iron oxides. However, the growth of iron particles was inhibited. With the addition of Na₂CO₃, the phosphorus in Fe₃PO₇ migrated to nepheline and Na₂CO₃ improved the reduction of iron oxides and growth of iron particles. Therefore, the recovery of iron and the separation of iron and phosphorus were the best. In contrast, CaF₂ reacted with Fe₃PO₇ to form fine Ca₃(PO₄)₂ particles scattered around the iron particles, making the separation of iron and phosphorus difficult.     

不同硅饱和系数水榴石的碳酸化分解动力学

Carbonated decomposition of hydrogarnet is one of the vital reactions of the calcification–carbonation method, which is designed to dispose of low-grade bauxite and Bayer red mud and is a novel eco-friendly method. In this study, the effect of the silica saturation coefficient (x) on the carbonation of hydrogarnet was investigated from the kinetic perspective. The results indicated that the carbonation of hydrogarnets with different x values (x = 0.27, 0.36, 0.70, and 0.73) underwent two stages with significantly different rates, and the kinetic mechanisms of the two stages can be described by the kinetic functions R3 and D3. The apparent activation energies at Stages 1 and 2 were 41.96–81.64 and 14.80–34.84 kJ/mol, respectively. Moreover, the corresponding limiting steps of the two stages were interfacial chemical reaction and diffusion.     

一种超重力燃烧合成制备高性能高熵合金的新方法

A new method of high-gravity combustion synthesis (HGCS) followed by post-treatment (PT) is reported for preparing high-performance high-entropy alloys (HEAs), Cr_0.9FeNi_2.5V_0.2Al_0.5 alloy, whereby cheap thermite powder is used as the raw material. In this process, the HEA melt and the ceramic melt are rapidly formed by a strong exothermic combustion synthesis reaction and completely separated under a high-gravity field. Then, the master alloy is obtained after cooling. Subsequently, the master alloy is sequentially subjected to conventional vacuum arc melting (VAM), homogenization treatment, cold rolling, and annealing treatment to realize a tensile strength, yield strength, and elongation of 1250 MPa, 1075 MPa, and 2.9%, respectively. The present method is increasingly attractive due to its low cost of raw materials and the intermediate product obtained without high-temperature heating. Based on the calculation of phase separation kinetics in the high-temperature melt, it is expected that the final alloys with high performance can be prepared directly across master alloys with higher high-gravity coefficients.     

窄板坯结晶器内连铸工艺参数对钢液流场的影响

Computational simulations and high-temperature measurements of velocities near the surface of a mold were carried out by using the rod deflection method to study the effects of various operating parameters on the flow field in slab continuous casting (CC) molds with narrow widths for the production of automobile exposed panels. Reasonable agreement between the calculated results and measured subsurface velocities of liquid steel was obtained under different operating parameters of the CC process. The simulation results reveal that the flow field in the horizontal plane located 50 mm from the meniscus can be used as the characteristic flow field to optimize the flow field of molten steel in the mold. Increases in casting speed can increase the subsurface velocity of molten steel and shift the position of the vortex core downward in the downward circulation zone. The flow field of liquid steel in a 1040 mm-wide slab CC mold can be improved by an Ar gas flow rate of 7 L·min?1 and casting speed of 1.7 m·min?1. Under the present experimental conditions, the double-roll flow pattern is generally stable at a submerged entry nozzle immersion depth of 170 mm.     

电渣重熔脱硫技术研究进展

Electroslag remelting (ESR) gives a combination of liquid metal refining and solidification structure control. One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production is desulfurization. It involves two patterns, i.e., slag–metal reaction and gas–slag reaction (gasifying desulfurization). In this paper, the advances in desulfurization practices of ESR are reviewed. The effects of processing parameters, including the initial sulfur level of consumable electrode, remelting atmosphere, deoxidation schemes of ESR, slag composition, melting rate, and electrical parameters on the desulfurization in ESR are assessed. The interrelation between desulfurization and sulfide inclusion evolution during ESR is discussed, and advancements in the production of sulfur-bearing steel at a high-sulfur level during ESR are described. The remaining challenges for future work are also proposed.     

利用皮秒激光烧蚀制备非球形铝纳米颗粒

We report the picosecond laser ablation of aluminum targets immersed in a polar organic liquid (chloroform, CHCl₃) with ~2 ps laser pulses at an input energy of ~350 μJ. The synthesized aluminum nanoparticles exhibited a surface plasmon resonance peak at ~340 nm. Scanning electron microscopy images of Al nanoparticles demonstrated the spherical morphology with an average size of (27 ± 3.6) nm. The formation of smaller spherical Al nanoparticles and the diminished growth could be from the formation of electric double layers on the Al nanoparticles. In addition to spherical aluminum nanoparticles, triangular/pentagonal/hexagonal nanoparticles were also observed in the colloidal solution. Field emission scanning electron microscopy images of ablated Al targets demonstrated laser induced periodic surface structures (LIPSSs), which were the high spatial frequency LIPSSs (HSF-LIPSSs) since their grating period was ~280 nm. Additionally, coarse structures with a period of ~700 nm were observed.     

Mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al2O3?Na2O system during high-temperature sintering

The mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al₂O₃?Na₂O system during the high-temperature sintering process were systematically investigated using DSC?TG, XRD, SEM?EDS, FTIR, and Raman spectra, and the crystal structure of Na₄Ca₃(AlO₂)₁₀ was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na₄Ca₃(AlO₂)₁₀, CaO·Al₂O₃, and 12CaO·7Al₂O₃, and the content of Na₄Ca₃(AlO₂)₁₀ could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na₄Ca₃(AlO₂)₁₀ occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na₄Ca₃(AlO₂)₁₀ was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na₄Ca₃(AlO₂)₁₀ was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.     

含细夹层的分矿充填层中流动特性的可视化

Ore particles, especially fine interlayers, commonly segregate in heap stacking, leading to undesirable flow paths and changeable flow velocity fields of packed beds. Computed tomography (CT), COMSOL Multiphysics, and MATLAB were utilized to quantify pore structures and visualize flow behavior inside packed beds with segregated fine interlayers. The formation of fine interlayers was accompanied with the segregation of particles in packed beds. Fine particles reached the upper position of the packed beds during stacking. CT revealed that the average porosity of fine interlayers (24.21%) was significantly lower than that of the heap packed by coarse ores (37.42%), which directly affected the formation of flow paths. Specifically, the potential flow paths in the internal regions of fine interlayers were undeveloped. Fluid flowed and bypassed the fine interlayers and along the sides of the packed beds. Flow velocity also indicated that the flow paths easily gathered in the pore throat where flow velocity (1.8 × 10?5 m/s) suddenly increased. Fluid stagnant regions with a flow velocity lower than 0.2 × 10?5 m/s appeared in flow paths with a large diameter.     

甘肃丹霞地貌初探

甘肃丹霞地貌分布广泛,是一种很有价值的旅游地貌资源。与典型的丹霞地貌相比,尚可区分出一种岩性不够坚硬、但有上复坚硬顶盖保护的类丹霞地貌,文中分析了省内丹霞地貌形成的基本条件、特征、类型、发育过程及内外动力在其形成过程中的作用等。     

沙坪坝地区城市地貌分类与制图

以重庆市沙坪坝地区1:20000城市地貌试验样图为例,试图就城市地貌的分类原则,编图思想及其图面内容作较为详细的介绍.     

流域地貌发育与地貌灾害

本文从流域地貌发育的背景出发，分析了引起地貌灾害的主要因素，指出了在流域中不同的区域中可能出现的各种地貌灾害形式及其形成的主要影响因素。     

北雄南秀 竞相并放——论中国山水画与地理环境的关系

浏览中国山水画史,你会发现历史上每个朝代著名的山水画家对山川景物都有着深入的了解和真切的感受。如画北方山石的荆浩、关仝、范宽等,画南方山石的董源、巨然、黄公望等彼此都有着不同的笔墨语言,对于山石结构有着不同的理解,也有着不同的表现。在地理环境范畴内,南北的地形地貌、气候各不相同。这对南北方山水画派的形成起着至关重要的作用。     

从板块构造论中国宏观地貌

本文运用板块构造学说,在综合前人研究成果的基础上,着重对中国宏观地貌的形成、演变、展布、区域组合及地貌分类,试作概略性的论述.     

山东丹霞地貌初探

丹霞地貌具有较高的科研和旅游价值,鉴于目前在对山东丹霞地貌探讨较少的状况下,对地区丹霞地貌形成的地质背景、地貌特征等进行了初步分析;分析结果表明：地貌是在沂沭断裂带作用下,在白垩纪形成的沉积碎屑岩,经后期内外力作用形成的,具有较大的开发、研究价值.     

Granite landform characteristics, distribution and evolution patterns in Huangshan Mt.

The various types of granite landforms in the Huangshan Mt. are distributed in a concentric pattern. The remaining parts of the planation surface are in the center; domical peaks, castle peaks, pointed peaks, and ridges are arranged from the center to the periphery accordingly. This reveals that knick points are still near the center and the center area is the common divide of the radial water system. It is inferred that the granite bodies in the Huangshan Mt. were exposed to erosion in Miocene and Pliocene, and the planation surface was also formed then. After the slight uplift in late Pliocene, a light-incised surface was formed. Then, in early Quaternary, there were intense uplifts and incisions so that deep incised surface was formed. The above process is still in progress, and results in high peaks and deep gorges outside of the center area. However, due to the limited catchment area in the center, headward erosion is mild, and the current landforms in the Huangshan Mt. can be maintained for a long time.     

下石家庄水库地貌及地层岩性分析

在工程地质勘测所获得资料的基础上,对下石家庄水库地貌与地层岩性进行了分析与评价。     

从《说文》看我国古代对于流水地貌的认识

在当今的科技史、地质史和多种《地貌学》的教材中,忽略了《说文》中蕴藏的地貌学知识。文章找出了《说文》包含的44个表示流水地貌的字词,并且按照岩性分了流水作用、河谷地貌和沟谷地貌三个类别进行了阐释。     

绵阳市境地貌基本特征

绵阳市是四川省辖市。由于市境所处地理位置的特殊性，其地貌特征与我国地貌轮廊的基本特征十分相似。本文通过对该市境所处的不同地理位置分析，阐述其地貌基本特征的形成