Recent high-resolution glaciochemical record from a Dasuopu firn core of middle Himalayas

A 16.8 m firn core of middle Himalayas was recovered on the col of Dasuopu glacier in August 2006, being 7000 m above sea level. A total of 317 samples were measured for stable oxygen isotope ratios （6180） and major ion concentrations （Na＋, NH＋, K＋, Mg2＋, Ca2＋, Cl-, SO4^2-, and NO3^-. The firn core dating and seasonal partitioning were carried out based on the marked seasonal variations along the stable oxygen isotopes and crustal species （Ca2＋, Mg2＋） profiles. The multi-parameters and high-resolution glaciochemical data set of Dasuopu firn core recorded the detailed chemical characteristics of pre cipitation in high-elevation region, middle Himalayas, since 1991 A.D., which mainly originated from the crustal and anthropogenic sources, while the sea-salt contribution was minor. The seasonal variability of major ion concentrations was dominated by the seasonal alternation of the prevalent air mass, atmospheric circulation situation and precipitation regime. Linear regression analysis indicated that most of the variance in annual ionic fluxes can be explained by a linear dependence on snow accumulation rate.     

Precipitation variability in central Himalayas and its relation to Northern Hemisphere temperature

Agriculture, industry and hydroelectric power in south Asia are heavily dependent on the performance of the summer (June to September) monsoon rainfall, which provides 75—90% of the annual rainwater over most parts of the area. A weak monsoon year generally corresponds to low crop yields. And strong monsoon usually produces abundant crops, although too much rainfall may produce devastating floods. However, modeling efforts to forecast the monsoon have met with only moderate success[1]. Prev…     

The seasonal variations of δ~(18)O , Cl~- , Na~+ , NO_3~- and Ca~(2+) in the snow and firn recovered from Princess Elizabeth Land, Antarctica

Snow and firn samples recovered from two snow pits (2.5 and 4.5m deep) and one 50-m firn core along the route of the 1996/1997 Chinese First Antarctic Inland Traverse Expedition in Princess Elizabeth Land, East Antarctica, have been measured for chemical composition and oxygen isotope ratio. In the two snow pits, the variations of NO3- are partly in phase with that of δ18O, while the variations of Cl~ and Na+ are in inverse phase with that of δ18O. The variations of CI- , Na+ , NO3- and δ18O show obvious seasonal variations and annual stratag-raphy. However, with the depth increasing, the seasonal variations of δ18O are gradually smoothed below 3 m (corresponding to about 10-year mass accumulation) in depth while the seasonal variations of Cl- , Na+ and NO3- are kept fairly well in the whole profile of the 50-m firn core (corresponding to about 250-year mass accumulation). The results provide a useful tool for dating the snow stratum in this region. On the contrary, no obvious seasonal variations of Ca2 + are found in the profiles.     

Southwest monsoon changes indicated by oxygen isotope of ostracode shells from sediments in Qinghai Lake since the late Glacial

The δ 18O records of ostracode shells in sediments of core QH-2000 from Qinghai Lake can be used as a better proxy to reflect monsoon changes. Low monsoon precipitation between 17.5 and 11 cal. ka BP is indicated by positive δ 18O values averaging 2.37‰. A fast shift in δ 18O from positive at 11 cal. ka BP to negative at 10 cal. ka BP indicates sharp increase of monsoon precipitation. An interval of generally high monsoon precipitation is observed between 10 and 6 cal. ka BP with δ 18O values averaging -2.15‰. Decrease of monsoon precipitation between 6 and 2.5 cal. ka BP is indicated by positive δ 18O values. δ 18O keeps positive values averaging 3.0‰ between 2.5 and 0 cal. ka BP suggesting low high monsoon precipitation. The climatic changes indicated by δ 18O records of ostracode shells in sedi- ments of core QH-2000 from Qinghai Lake and our broader regional comparison show that the climate in Qinghai Lake since the late Glacial is probably controlled by southwest monsoon other than southeast monsoon.     

Water isotope variations in the snow pack and summer precipitation at July 1 Glacier, Qilian Mountains in northwest China

This paper presents the stable isotope data of the snow pack and summer precipitation collected at the July 1 Glacier, Qilian Mountains in northwest China and analyses their relationships with meteorologi- cal factors. On an event scale, there is no temperature effect on the δ 18O values in the summer pre- cipitation, whereas the amount effect is shown to be clear. By tracing the moisture transport history and comparing the precipitation with its isotopic composition, it is shown that this amount effect not only reflects the change in moisture trajectory, which is related to the monsoon activities, but is also associated with the cooling degree of vapor in the cloud, the evaporation of falling raindrops and the isotopic exchange between the falling drops and the atmospheric vapor. As very little precipitation occurs in winter, the snow pack profile mainly represents the precipitation in the other three seasons. There are low precipitation δ 18O ratios in summer and high ratios in spring and autumn. The Meteoric Water Line (MLW) for the summer precipitation is δ D = 7.6 δ 18O 13.3, which is similar to that at Delingha, located in the south rim of the Qilian Mountains. The MWL for the snow pack is δ D = 10.4 δ 18O 41.4, showing a large slope and intercept. The deuterium excess (d) of the snow pack is positively correlated with δ 18O, indicating that both d and δ 18O decrease from spring to summer and increase from early autumn to early spring. This then results in the high slope and intercept of the MWL. Sea- sonal fluctuations of d in the snow pack indicate the change of moisture source and trajectory. During spring and autumn, the moisture originates from continental recycling or rapid evaporation over rela- tively warm water bodies like Black, Caspian and Aral Seas when the dry westerly air masses pass over them, hence very high d values in precipitation are formed. During summer, the monsoon is responsi- ble for the low d values. This indicates that the monsoon can reach the western part of the Qilian Mountains.     

Synoptic-scale variation of δ18O in summer monsoon rainfall at Lijiang, China

Based on the daily δ~(18)O data in June―September 2003 at Lijiang and the daily mean NCEP/ NCAR reanalysis data, synoptic-scale variation of δ~(18)O in summer monsoon rainfall was investigated. The 'precipitation amount effect' is obvious for the daily δ~(18)O variation, whereas the 'temperature effect' is insignificant. Alternate occurrences of active phase and break phase of the southwest monsoon probably influence the synoptic-scale δ~(18)O variation prominently. Moreover, the isotopic composition in precipitation during the late monsoon months is presumably influenced significantly by recycling of monsoon precipitation. Both the above factors disturb the 'amount effect' of isotopic variation in the monsoon region. This study also indicates that the synoptic-scale rainfall δ~(18)O variation at Lijiang in summer is domi-nated by the Indian monsoon depression (low pressure) system at large scale. These results are important for further studying the 'amount effect' and reconstructing paleoclimate in the monsoon region.     

Oxygen isotope variation in the water cycle of the Yamzho lake Basin in southern Tibetan Plateau

Given the potential use of stable isotope in the paleoclimate reconstruction from lacustrine records as well as in the local hydrology cycle, it is crucial to understand the processes of stable isotope evolution in catchment in the Tibetan Plateau region. Here we present a detailed study on the water oxygen isotope based on 2 years observation including precipitation, river water and lake water in the Yamzho Lake, south of the Tibetan Plateau. Temporal variation of local precipitation 5180 shows an apparent ＂monsoon cycle＂. In monsoon season, 5180 in waters is lower. In non-monsoon season, δ^18O in precipitation and lake water is higher and higher river δ^18O exists in spring, probably reflecting the effect of land surface evaporation, together with the higher δ^18O values in spring precipitation. It is also found that the surface lake water δ^18O varies seasonally and annually. The lower lake water δ^18O in the late summer is apparently related to the summer monsoon precipitation. The mean δ^18O value of lake water in 2007 is 1.2‰ higher than that in 2004, probably due to the less monsoon precipitation in summer of 2007, as can be confirmed from the precipitation data at the Langkazi meteorological data. It is also found that an obvious shift of vertical lake water δ^18O reflects the fast mixture of lake water. δ^18O values of lake water are over 10‰ higher than those of precipitation and river water in this region due to the evaporation fractionation. The modeled results show that the evaporation process of the lake water is sensitive to relative humidity, and the present lake water δ^18O reflects a relative humidity of 51% in the Yamzho Lake. It shows that the lake will take 30.5 years to reach present lake water δ^18O given a large shift in the input water δ^18O. The modeled results also reveal that surface lake water temperature and inflow δ^18O have slight effect on the isotopic balance process of lake water in the Yamzho Lake.     

Climatic significance of δ18O records from precipitation on the western Tibetan Plateau

Analysis of daily precipitation samples for stable oxygen isotopes （δ^18O） collected at the Shiquanhe and Gerze （Gaize, Gertse） stations in the Ngari （Ali） region on the western Tibetan Plateau indicates that air temperature affects the δ^18O variations in precipitation at these stations. In summer, Shiquanhe and Gerze show strongly similar trends in precipitation δ^18O, especially in simultaneous precipitation events. Moreover, both stations experienced low δ^18O values in precipitation during the active monsoon period, resulting from the southwest monsoon （the summer phase of the Indian monsoon）. However, during the break monsoon period （during the summer rainy season, when the monsoon circulation is disrupted）, δ^18O values in summer precipitation remain relatively high and local moisture recycling generally controls the moisture sources. Air temperature correlations with δ^18O strengthen during the non-monsoon period （January--June, and October--December） due to continental air masses and the westerlies. In addition, evaporation also influences the δ^18O variations in precipitation. The observed temporal and spatial variations of δ^18O in precipitation on the western Tibetan Plateau and adjacent regions show that the late May and early June-the late August and early September time frame provides an important period for the transportation of moisture from various sources on the Tibetan Plateau, and that the region of the West Kunlun-Tanggula Ranges acts as a significant climatic divide on the Plateau, perhaps for all of western China.     

The δ18O variation of a stalagmite from Qixing Cave, Guizhou Province and indicated climate change during the Holocene

A stalagmite from Qixing Cave, Guizhou Province was dated with the TIMS U-series method and its oxygen isotope composition was analyzed. On the basis of the ages and the variations of the δ¹⁸O of the stalagmite, the climate change of the last 7.7 ka has been reconstructed in this area: 7.7–5.8 ka, summer monsoon maximum period; 5.8–3.8 ka summer monsoon weakening period; 3.8–0.15 ka, weakened summer monsoon and high amplitude climate fluctuations period. We put forward that the increasing trend of δ¹⁸O of the stalagmite reflected not only the weakening of the summer monsoon, which was caused by the decreasing of solar radiation in the Northern Hemisphere, but also the possibly decreasing contribution of the southwest monsoon to the rainfall of this area. These results are consistent with the output of the numerical climate-model modeling. The high amplitude fluctuation of the δ¹⁸O may imply the quick shift of the contributions of different moisture sources to the precipitation in this area.     

Indian monsoon influences altitude effect of δ~(18)O in precipitation/river water on the Tibetan Plateau

The δ^18O variation in precipitation acquired from 28 stations within the network of Tibetan Observation and Research Platform （TORP） is studied, with the focus on the altitude effect of δ^18O in river water during monsoon precipitation in an effort to understand the monsoon influence on isotopic composition in annual river water. It is found that δ^18O in precipitation on the Plateau is influenced by different moisture sources, with significant Indian monsoon influence on δ^18O composition in plateau precipitation and river water. The δ^18O of water bodies in the monsoon domain is generally more depleted than that in the westerly domain, suggesting gradual rainout of southwesterly borne marine moisture in the course of long-distance transportation and lifting over the Himalayas. The lapse rate of δ^18O in river water with altitude is the largest during monsoon precipitation, due to the increased temperature vertical gradient over the southern Plateau region controlled by monsoon circulation. The combination of δ^18O in river water in monsoon （wet） and non-monsoon （dry） seasons shows a larger lapse rate than that in non-monsoon （dry） season alone. As the altitude effect of δ^18O in precipitation and river water on the Tibetan Plateau results from the combined effect of monsoon moisture supply and westerly moisture supply, the δ^18O composition and its altitude effect on the Plateau during monsoon seasons should be considered in the reconstruction of paleoelevation of the Tibetan Plateau.     

Determination and geological implication of O-Si isotope of the sediment core in the CC area, the Pacific Ocean

Conclusions  

Mechanisms of peroxynitrite-induced [Ca2+]i increase in single neuronal cell

The mechanism of peroxynitrite (ONOO⁻)-induced [ca²⁺]_i increase in single MN9D cell (Dopaminergic neuroblastoma cell line) was studied by using Fura-2 microfluorometric technique. The results show that ONOO⁻ caused a rapid increase of [Ca²⁺]_i when ONOO₋ was puffed to the cell. Removing Ca²⁺ from the bath or using calcium channel antagonist (CdCl₂, Nifedipine) greatly inhibited the [Ca²⁺]_i increase induced by ONOO⁻¹, suggesting that the opening of L-Ca²⁺ channel makes a great contribution to the [Ca²⁺]_i increase. The effect of sulfhydryl reductive agent (DTT) on ONOO⁻-induced [Ca²⁺]_i increase suggests that ONOO⁻-activating L-Ca²⁺ channel is partly related to its oxidative speciality.     

Recent temperature increase recorded in an ice core in the source region of Yangtze River

Interests on climate change in the source region of Yangtze River have been raised since it is a region with the greatest warming over the Tibetan Plateau (TP). A 70-year history of precipitation δ~(18)O has been recovered using an ice core record retrieved in a plat portion of the firn area in the Guoqu Glacier (33°34′37.8″N, 91°10′35.3″E, 5720 m a.s.l.), Mt. Geladaindong (the source region of Yangtze River), in November, 2005. By using a significant positive relationship between ice core δ~(18)O record and summer air temperature (July to September) from the nearby meteorological stations, a history of summer air temperature has been reconstructed for the last 70 years. Summer temperature was relatively low in 1940s and high in 1950s to the middle of 1960s. The lowest temperature occurred in the middle of 1970s. Temperature was low in 1980s and dramatically increased since 1990s, keeping the trend to the begin-ning of the 21st century. The warming rate recorded in the ice core with 0.5℃/10 a since 1970s is much higher that that in the central TP and the Northern Hemisphere (NH), and it becomes 1.1℃/10 a since 1990s which is also higher than these from the central TP and the NH, reflecting an accelerated warm-ing and a more sensitive response to global warming in the high elevation region.     

Preliminary evidence indicating Dome A （Antarctica） satisfying preconditions for drilling the oldest ice core

Lowest temperature and snow accumulation rate are preconditions for retrieving the oldest ice core from the polar ice sheets. The 10-m depth firn temperature at Dome A, the summit of the Antarctic Ice Sheet, recorded by an automatic weather station （AWS） was -58.3℃ in 2005 and -58.2℃ in 2006, respectively. The 10-m firn temperature is an approximation of the annual mean air temperature （AMAT）, and this is the lowest AMAT that has been recorded on the surface of the Earth. The stable isotopic ratios （δ^18O and δD） of surface snow at Dome A are also lower than at other ice sheet domes along the East Antarctic Ice Divide such as Dome C, Dome F, Dome B and Vostok. These facts indicate that Dome A is the ＂pole of cold＂ on the Earth. The total amount of snow accumulation rate in 2005 and 2006 was only 0.16 cm, equaling 0.016 m water equivalent per year, the lowest precipitation ever recorded from Antarctica. Preliminary evidences indicate that Dome A is a candidate site for recovering the oldest ice core.     

Modern stalagmite oxygen isotopic composition and its implications of climatic change from a high-elevation cave in the eastern Qinghai-Tibet Plateau over the past 50 years

An oxygen isotope record of a stalagmite from Huanglong Cave in the eastern Qinghai-Tibet Plateau dated with 230Th and 210Pb methods provides variations of the Asian monsoon with an average resolu-tion of 1 year over the past 50 years. This study shows that the δ18O of dripwater in the cave represents the annual mean δ18O of local meteoric precipitation and the stalagmites were deposited in isotopic equilibrium. A comparison of the stalagmite δ18O record with instrumentally meteorological data indi-cates that shifts of the δ18O are largely controlled by the amount effect of meteoric precipitation con-veyed through the southwest monsoon(the Indian monsoon) and less affected by temperature. Therefore,the variations of δ18O record reflect the changes in monsoon precipitation on inter-annual time scales under the influence of the southwest monsoon. Like many other stalagmite δ18O records in the Asian monsoon regions,the δ18O record of the stalagmite from Huanglong Cave also reveals a gradually enriched trend during the past 50 years,i.e. relatively enriched in 18O. This trend may indicate the decline of the Asian monsoon intensity which is consistent with the decrease of monsoon indices. The weakening of the modern Asian monsoon well matched with the temperature changes in strato-sphere,which may illustrate that the weakening of the monsoon mainly results from the lowering of solar radiation.     

Transmission of oxygen isotope signals of precipitation-soil water-drip water and its implications in Liangfeng Cave of Guizhou,China

According to systemically monitoring results of oxygen （hydrogen） isotope compositions of precipitation, soil waters, soil CO2, cave drip waters and their corresponding speleothems in Liangfeng Cave （LFC） in Guizhou Province, Southwest China, it is found that local precipitation is the main source of soil waters and drip waters, and that the amplitudes of those δ18O values of three waters （precipitation, soil water and drip water） decrease in turn in the observed year, which are 0‰ to -10‰, -2‰ to -9‰ and -6‰ to -8‰, respectively. Moreover, the δ18O values for three waters show a roughly simultaneous variation, namely, that those values are lighter in the rainy seasons, weightier in the dry seasons, and that the average δ18O value of drip waters is about 0.3‰ weightier than that of precipitation, which is modified by surface evaporation processes. We also find that oxygen isotope equilibrium is reached or neared in the formation processes of speleothems in LFC system, and that it is feasible to reconstruct paleotemperature and paleoprecipitation by using δ18O values of speleothems. However, it should be noted that surface evaporation would affect the oxygen isotope values in the study area.     

Variations of organic carbon isotopic composition and its environmental significance during the last glacial on western Chinese Loess Plateau

The last glacial period is characterized by a cold and dry climate with low atmospheric CO2 concentration. The relatively arid climate and low CO2 concentration are favorable to the growth of C4 plants, but the low temperature limits the development of th…     

Increasing atmospheric pollution revealed by Pb record of a 7 000-m ice core

Concentrations of Pb in Dasuopu ice core in the Qinghai-Tibetan Plateau have been directly measured by ICP-MS at pg/g level. The Pb profile shows a very significant increase in modern times due to anthropogenic input. The use of leaded gasoline in the South Asian countries may be a main source of Pb in this region. The input of Pb to the Dasuopu Glacier is mainly supplied by Indian summer monsoon moisture which traverses the pass at the head of the Dasuopu Glacier.     

Variability of snail growing season at the Chinese Loess Plateau during the last 75 ka

Knowledge of seasonal climate change is one of the key issues facing Quaternary paleoclimatic studies and estimating seasonal climate change is difficult,especially changes such as seasonal length on glacial-interglacial timescales.The stable isotope composition from seasonal land snail shells provides the potential to reveal seasonal climatic features.Two modern land snail species,cold-aridiphilous Pupilla aeoli and thermo-humidiphilous Punctum orphana,were collected from different climatic zones in 18 localities across the Chinese Loess Plateau,spanning 11 degrees of longitude and covering a range of 1000 km2.The duration of the snail growing season(temperature ≥10℃) was shorter(202 ± 6 d) in the eastern Loess Plateau compared with in the western Loess Plateau(162 ±7 d).The δ13C of P.aeoli shells was ?9.1‰ to ?4.7‰ and ?5.0‰ to 0.3‰ for δ18O.For P.orphana,the δ13C ranged from ?9.1‰ to ?1.9‰ and ?8.9‰ to ?2.9‰ for δ18O.Both the δ13C and δ18O differences between the two snail species were reduced from the east to the western Loess Plateau(2.8‰ to 0.2 ± 1.1‰ for δ13C and 4.7‰ to 2.9 ± 1.3‰ for δ18O).These isotopic differences roughly reflect the difference in the growing season lengths between the east and west Loess Plateau indicating that the duration of the snail growing season shortens by 15 d or 19 d if the difference decreases by 1‰ in δ13C or δ18O,respectively.Thus,the difference in δ13C and δ18O between both snail species can be used to reveal the length of the snail growing season in the past.Based on our investigation,the length of the snail growing seasons from the Xifeng region during the last 75 ka was reconstructed.During the mid-Holocene(8-3 ka),the mean isotopic difference from both snail species reached maximum values of 2.6 ± 0.7‰ and 2.1 ± 1.4‰ for δ13C and δ18O,respectively.This was followed by MIS 3 that ranged from 2.5 ± 0.4‰ for δ13C and 1.6 ± 0.8‰ for δ18O.The Last Glacial Maximum changed by only 0.2‰ and 0.4‰ for δ13C and δ18O,respectively.Therefore,we estimate that the duration of the snail growing seasons to be ～200 ± 10 d during the mid-Holocene,190 ± 6 d in MIS 3 and 160 ± 3 d during the last glacial period.     

Origin of summer monsoon rainfall identified by δ18O in precipitation

A negative correlation between δ^18O in monsoon precipitation and f, the ratio of precipitable water in monsoon region to that in water source area, is hypothesized. Using the Rayleigh model, a new method for identifying origin of summer monsoon rainfall is developed based on the hypothesis. In order to validate the method, the isotopic data at New Delhi, a typical station in the southwest monsoon region, and Hong Kong, a typical station in the southeast monsoon region, were collected and analyzed for case studies. The case studies indicate that the water source areas of the monsoon rairdall at the two stations identified by the method are accordant with the general atmosphere circulation patterns. The method developed in this paper is significantly important for tracing the origin of summer monsoon precipitation.