化学发光法测定蜂蜜中诺氟沙星残留含量

采用化学发光法对蜂蜜中诺氟沙星残留含量进行测定.结果表明:硫酸介质浓度为、23浓度为0.002 mol/L、Ce(IV)浓度为0.01 mol/L、SDS浓度为0.01 mol/L时,相对发光值△I与诺氟沙星在0~1.2×10-6g/m L浓度范围内呈良好线性关系,相对标准偏差为3.16%,平均回收率为92.4%和96.2%.该法操作简便,结果准确、可靠.     

单纯形优化法用于流动注射式化学发光分析

本文将改进单纯形优化法应用于 Cr(Ⅲ)—鲁米诺—H_2O_2流动注射式化学发光体系,并就实验最佳条件进行了初步研究。给出了四种影响因素一泵速、Luminol 浓度、H_2O_2浓度及溶液 PH 值的最佳工作区域,同时对其因素效应进行了分析评价。实验证明单纯形优化法比正交试验法及固定因素法具有显著优越性。     

化学发光法测定镀铬废液及自来水中Cr（Ⅲ）

痕量Cr(Ⅱ)对H_2O_2在碱性介质中氧化鲁米诺的反应具有催化作用,反应过程中会发出波长为425 nm的光线,发光强度与Cr(Ⅱ)的含量成比例关系,据此可测定Cr(Ⅲ)。该反应过程可表示为     

静态注射化学发光法测定水体中的苯二酚

为了对苯二酚进行高灵敏度的检测,本文对化学发光法进行了研究.在酸性介质中甲酸对高锰酸钾-苯二酚氧化发光反应有很好的增敏作用,基于此,建立了静态注射化学发光检测苯二酚的分析方法.所建立方法的标准曲线的浓度范围为0.12-0.60 mg/L,该方法显示了良好的相对标准偏差(0.4207%～1.4649%)、良好的回收率(97.7%～112.5%)以及极好的线性相关系数(F=0.9972).利用该方法测定了不同河水中苯二酚的浓度,相关的定量指标良好.所建立的对苯二酚的化学发光法便捷、高灵敏,适合于环境保护领域对水体进行苯二酚污染物的检测,具有实用意义.     

光化学-化学发光法的建立及其对某些食品中亚硫酸盐的测定

通过光化学反应产生的碘与溶液中的亚硫酸盐发生反应,再利用鲁米诺化学发光体系测量剩余量的碘,从而建立光化学-化学发光偶合体系,应用于白葡萄酒、白糖和冰糖等食品中亚硫酸盐的分析,相对标准偏差在5％以内,回收率在90％～110％之间。     

海洋真菌抗氧化活性物质的初步研究

采用化学发光法对81株分离自深海沉积物的真菌和93株红树林的内生真菌进行抗氧化活性物质的筛选.结果表明,供测菌株中有7株深海真菌、1株红树林内生真菌对于活性氧具有抑制作用,占供测菌株的4.60%.在7株深海真菌中有3株对羟基自由基和过氧化氢均表现出了较好的抑制作用.进一步采用化学发光法和DPPH法追踪上述3株深海真菌(114、115、134)发酵产物的水溶性聚糖和有机相中的抗氧化活性物质,发现有机相表现出较好的抗氧化活性,3株真菌的IC50分别是:1.92、55.55和11.23μg/mL(.OH);1.45、13.79和72.29μg/mL(H2O2);112.45、58.87和169.39μg/mL(DPPH);而水相中的水溶性聚糖也具有不同程度的抗氧化活性.海洋真菌是产生抗氧化活性物质的重要资源.     

化学发光法测定蜂蜜中金霉素残留含量

采用化学发光法对蜂蜜中金霉素残留含量进行测定.结果:NaIO4为0.05 mol/L,H2O2为0.03 mol/L时,相对发光值△I与金霉素在相对低浓度0～8×10-7 g/mL和相对高浓度10×10-7～100×10-7g/mL范围内呈良好线性关系,相对标准偏差为2.12％,平均回收率为96.2％和97.6％.该法...     

诗与"在"--海德格尔诗学的阐释

海德格尔对荷尔德林诗歌的阐释，目的是进行诗与思的对话，归根结底还是探讨存在。诗与“在”的关系，是海氏诗学框架的核心内容，诗与“在”的关系又进一步引申为艺术与真理的关系，本从真理如何被遮蔽的问题入手，试图读解海德格尔诗学的内涵。艺术是无蔽的真理显明的一种方式，诗是危机的拯救，语言是存在的家园。海德格尔对诗与在的探讨最后又转入了对语言的探讨，无法走出语言的牢笼。只有在实践中，把艺术变成为社会变革的一个因素，才可以解放被传统理性压迫的力量，显现艺术的真理，确立艺术的价值。     

Regulation of canonical Wnt/β-catenin pathway in the nucleus

Canonical Wnt/β-catenin pathway plays a central role in development, homeostasis, as well as tumorigenesis. The regulation of the pathway involves various and complicated mechanisms, including the extracellular, intracellular and endonuclear regulation. As the key component of the pathway, the Lefl/Tcfs-β-catenin complex is also the key target of regulation in the nucleus. In the current review, we are going to summarize the regulators in the nucleus which can modify the transcrip- tional activity of the Wnt/β-catenin pathway.     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

论信托财产的人格性

信托财产是信托关系的基本要素,由于信托的特殊性,信托财产与传统民法的财产有很大区别,正确给信托财产定位,是信托业得以健康发展的核心问题。信托财产的特性在于其人格性,而这种人格性的赋予是以交易成本最小化为动因,尽管信托财产人格性设计对受益人的利益有偏袒,但从社会成本而言,其目的在于促使交易成本最小化,当然,对信托财产的人格性不能绝对化,由于利益平衡的需求,往往在特定情况下对信托财产予以人格否认。     

卤素离子在多晶铜电极表面的微分电容研究

本文通过测量金属晶体电极表面的微分电容研究了金属电极表面在金属与水溶液界面上的吸附能力,以及金属与吸附质之间的相互作用。文中论述了多晶铜电极在(0.5-x)mNaClO_4+xmNaBr的一系列不同x值的溶液中的微分电容测量值及微分电容-电位曲线,证明了F~-和ClO_4~-离子在多晶铜电极表面是非常弱的吸附,Br~-离子在多晶铜电极表面具有特定的吸附,每条电容-电位曲线有一个凸起的峰。在峰所对应的位能值,金属表面对阴离子的吸附能力强,证实金属-吸附质之间的相互作用强,吸附的阴离子在过渡层中散射导电电子的能力也强。对于相同阴离子和金属的体系,其微分电容与吸附质的浓度、电压、溶液的pH值和表面的非均匀性等因素密切有关。研究证明,金属晶体电极表面在电解质溶液中的微分电容的变化规律类似于表面电反射信号的强弱变化规律,微分电容大小取决于金属-吸附质之间的电荷转移程度。     

气体对阴离子表活剂压裂液破胶实验研究

阴离子表活剂压裂液是新型清洁压裂液,原油和地层水对其破胶机理与实验研究已相当充分,但气体对其破胶作用至今研究很少.为解决阴离子表活剂压裂液在压裂应用中的障碍,研究采用一套实用的实验流程,评价了天然气、氮气、二氧化碳三种常见气体对阴离子表活剂压裂液的影响.实验证明,三种不同的气体对阴离子表活剂压裂液的降粘幅度存在较大的差别,其中,二氧化碳气体对阴离子清洁压裂液降粘幅度最大,可使交联液体彻底破胶,天然气对阴离子型表活剂压裂液降粘幅度较小,氮气对阴离子压裂液的粘度几乎没有影响,氮气和天然气可以使液体泡沫化,从而有利于返排.实验结果为优化压裂设计提供了依据,可有效提高现场压裂施工成功率.     

多腔速调管主要性能指标简化分析

介绍了速调管在我国的发展现状和几种不同结构的多腔速调管的主要特性比较,并给出了小信号条件下速调管的各种主要特性的简化分析方法.在这种简化分析方法中,把多腔速调管看作是几个双腔速调管的级联,并且没有考虑非线性、空间电荷效应和相对论效应等带来的影响,目的是阐述基本原理和基本分析方法.     

DEM/CFD modelling of the deposition of dilute granular systems in a vertical container

Deposition of granular materials into a container is a general industrial packing process. In this study, the deposition behaviour of dilute granular mixtures consisting of two types of particles that were of the same particle size but different particle densities in the presence of air was numerically analyzed using a coupled discrete element method （DEM） and computational fluid dynamics （CFD）. Bilayer granular mixtures with light particles at bottom and heavy particles at top were first simulated. It was found that the presence of air significantly affected the flow behaviour of the bilayer mixtures. For the system with a relatively low initial void fraction, the air entrapped inside the container escaped through the dilated zones induced due to the friction between the powder bed and wall surfaces. The escaping air streams entrained light particles that were originally located at the bottom of the granular system. Consequently, these light particles were migrated to the top of the granular bed at the end of deposition process. More light particles were migrated when the deposition distance was increased. For the system with a high initial void fraction, some light particles penetrated into the top layer of heavy particles and created a mixing zone. Deposition of random mixtures with different initial void fractions was also investigated and the influence of initial void fraction on the segregation behaviour was explored as well. It was found that the increase of void fraction promoted segregation during the deposition in air. It was demonstrated that, for granular mixtures consisting of particles of different air sensitivities, the presence of air had a significant impact on the mixing and segregation behaviour during the deposition.     

Using new fusion operations to improve trust expressiveness of subjective logic

Subjective logic provides a means to describe the trust relationship of the real world.However,existing fusion operations it offers treat fused opinions equally,which makes it impossible to deal with the weighted opinions effectively.A.Jφsang presents a solution,which combines the discounting operator and the fusion operator to produce the consensus to the problem.In this paper,we prove that this approach is unsuitable to deal with the weighted opinions because it increases the uncertainty of the consensus.To address the problem,we propose two novel fusion operators that are capable of fusing opinions according to the weight of opinion in a fair way,and one of the strengths of them is improving the trust expressiveness of subjective logic.Furthermore,we present the justification on their definitions with the mapping between the evidence space and the opinion space.Comparisons between existing operators and the ones we proposed show the effectiveness of our new fusion operations.