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1.
The electromagnetic properties of Ba2Co1.8Cu0.2Fe12O22 (Co2Y) and Ba3Co2Fe23.4Zn0.6O41 (Co2Z) were studied by measuring microwave scattering parameters. In the transmission spectra of Ba2Co1.8Cu0.2Fe12O22, a forbidden band emerges due to ferromagnetic resonance, and the permeability will turn to negative in the vicinity of the ferromagnetic resonance frequency. In the complex permittivity spectra of Ba3Co2Fe23.4Zn0.6O41, the negative permittivity can be obtained due to dielectric resonance. Therefore, Co2Y and Co2Z can be used to construct left-handed materials possessing negative permeability and negative permittivity simultaneously.  相似文献   

2.
用水热法制备Li4Ti5O12@TiO2复合材料与同样方法制备的尖晶石型Li4Ti5O12进行对比.对2种材料采用扫描电子显微镜、X射线衍射仪、光电子能谱仪(XPS)进行表征;N2吸附-脱附曲线进行比表面积分析;恒电流充放电测试和电化学交流阻抗(EIS)技术进行电化学性能分析.结果表明Li4Ti5O12@TiO2和Li4Ti5O12均呈颗粒状,粒径分别约为50和70 nm.XPS分析显示Li4Ti5O12@TiO2中的Ti为+4价态.电化学测试结果显示Li4Ti5O12复合了锐钛型TiO2...  相似文献   

3.
制备方法对稀土Gd掺杂SnO2/Sb电催化电极性能的影响   总被引:3,自引:0,他引:3  
分别采用浸渍法、 溶胶-凝胶法, SnCl4·5H2O, Sb 2O3 Gd(NO3)3为 原料, 制备了稀土Gd掺杂SnO2/Sb涂层电催化电极. 以苯酚为目标有机物, 考 察了电极的电催化氧化性能, 初步探讨了电极结构与电催化特性之间的关系. 采用SEM, XRD, XPS和EDX等手段对不同方法制备电极的表面形貌、 晶体结构、 电极表面涂层的 元素化学结合态及元素组成进行了表征与分析. 结果表明, 溶胶-凝胶法制备的电极为纳 米涂层电极, 表面裂纹较少, 晶体发育完全, 有利于SnO2, Gd2 O3和 吸附氧的表面聚集, 进而提高了电催化电极的性能.  相似文献   

4.
采用混胶法将铝溶胶与钛溶胶相混合制备出纳米级γ-Al2O3/TiO2复合载体,然后用共浸渍法制备出不同钒含量的V/γ-Al2O3-TiO2催化剂,并对其活性进行评价,结果发现5%V2O5/γ-Al2O3-TiO2催化剂对乙醇和乙醛等具有良好的催化氧化性能.通过XRD等技术对催化剂进行了表征,合理解释了V/γ-Al2O3-TiO2催化剂有较高活性的原因.  相似文献   

5.
用溶胶-凝胶法制备钛(Ti)掺杂BiFeO3纳米颗粒(Ti-BiFeO3), 研究不同煅烧温度对Ti掺杂BiFeO3结构调控及光催化性能的影响, 用X射线衍射(XRD)、 扫描电子显微镜(SEM)、 能谱分析(EDS)、 紫外-可见(UV-Vis)光谱技术对颗粒的相结构、 形貌、 原子比例、 光催化性能等进行测试及分析, 并以罗丹明-B为目标降解物, 对Ti掺杂BiFeO3光催化性能进行研究. 结果表明: Ti掺杂BiFeO3样品在不同煅烧温度均出现Bi2Fe4O9相; 煅烧温度可对Bi2Fe4O9的含量进行调控, 在650 ℃煅烧样品中含有适量的Bi2Fe4O9相, 能有效提高Ti掺杂BiFeO3的光催化活性, 且具有较高的降解活性, 60 min内降解效率达85%.  相似文献   

6.
分别对Al-TiO2,Al-V2O5,Al-V2O5-TiO2及Al-V2O5-TiO2-CaO体系的热力学和动力学进行了研究.结果表明:采用铝粉直接还原TiO2,V2O5粉末制备Ti-6Al-4V合金是可行的.加入CaO会降低体系单位质量反应热,需要补热才能维持反应进行.Al还原TiO2的反应在951℃发生,表观活化能E1为166.47kJ/mol,反应级数n1为0.3982;Al还原V2O5的反应在946℃发生,表观活化能E2为392.72kJ/mol,反应级数n2为1.0618.Al粉还原V2O5和TiO2制备Ti-6Al-4V合金体系的反应在1019℃左右发生,表观活化能E3为173.56kJ/mol,反应级数n3为0.4722;加入CaO后,反应在979℃左右发生,体系表观活化能升高但反应级数降低.这四个体系均属于液-固反应体系.  相似文献   

7.
Mg5Al2.4Zr1.7O12 metastable phase was successfully synthesized from analytical-grade MgO, α-Al2O3, MgAl2O4, and ZrO2 under an N2 atmosphere. The sintering temperature was varied from 1650 to 1780℃, and the highest amount of Mg5Al2.4Zr1.7O12 appeared in the composite material when the sintering temperature was 1760℃. According to our research of the formation mechanism of Mg5Al2.4Zr1.7O12, the formation and growth of MgAl2O4 dominated when the temperature was not higher than 1650℃. When the temperature was higher than 1650℃, MgO and ZrO2 tended to diffuse into MgAl2O4 and the Mg5Al2.4Zr1.7O12 solid solution was formed. When the temperature reached 1760℃, the formation of Mg5Al2.4Zr1.7O12 was completed. The effect of MgAl2O4 spinel crystals was also studied, and their introduction into the composite material promoted the formation and growth of Mg5Al2.4Zr1.7O12. A highly dispersed MgO-MgAl2O4-ZrO2 composite material was prepared through the decomposition of the Mg5Al2.4Zr1.7O12 metastable phase. The as-prepared composite material showed improved overall physical properties because of the good dispersion of MgO, MgAl2O4, and ZrO2 phases.  相似文献   

8.
The non-carbothermic zinc pyrometallurgical processing of electric arc furnace (EAF) dust was investigated on a laboratory scale. The main objective of this process was to convert highly stable zinc ferrite (ZnFe2O4), which accounts for more than half of total zinc in the EAF dust, into ZnO and Ca2Fe2O5 by CaO addition. The EAF dust was mixed with CaO powder in various ratios, pressed into pellets, and heated in a muffle furnace in air at temperatures ranging from 700 to 1100℃ for a predetermined holding time. All ZnFe2O4 was transformed into ZnO and Ca2Fe2O5 at a minimum temperature of 900℃ within 1 h when sufficient CaO to achieve a Ca/Fe molar ratio of 1.1 was added. However, at higher temperatures, excess CaO beyond the stoichiometric ratio was required because it was consumed by reactions leading to the formation of compounds other than ZnFe2O4. The evaporation of halides and heavy metals in the EAF dust was also studied. These components could be preferentially volatilized into the gas phase at 1100℃ when CaO was added.  相似文献   

9.
以共沉淀法制备钠离子层状氧化物正极材料NaNi0.4Mn0.4Fe0.2O2,采用Al3+有效控制和平衡共沉淀反应的过程.考察了加入Al元素带来的热力学耦合效应及对正极材料电化学性能的影响.结果表明,在Mn2+,Ni2+和Fe2+离子共存的环境中,由于Al3+更高的过饱和度和更负的吉布斯自由能变(ΔG)所产生的热力学耦合效应,显著改变了溶液离子之间的沉淀驱动力,加速Ni2+和Mn2+的沉淀并抑制Fe3+的沉淀.Na[Ni0.4Mn0.4Fe0.20.995Al0.005O2正极材料表现出优异的电化学性能,这归因于引入Al3+制备得到高质量的前驱体([0.4MnCO3·0.4NiCO3·0.2Fe(OH)30.995·0.005Al(OH)3).  相似文献   

10.
以钡铁氧体(BaFe12O19)为微波吸收剂、聚乳酸(PLA)为基体,经过球磨、单螺杆熔融挤出制备BaFe12O19/PLA复合线材,利用熔融沉积成型(FDM)制备出BaFe12O19/PLA复合材料.分别利用XRD、SEM和矢量网络分析仪对所制备的不同比例的BaFe12O19/PLA复合材料进行物相研究、微观形貌分析和电磁性能表征.拉伸测试结果表明:随着BaFe12O19含量的提升,BaFe12O19/PLA复合材料的力学性能持续下降,当BaFe12O19含量在20%时,拉伸强度和断裂延伸率较纯PLA分别下降了15.69%、36.83%;当BaFe12O19含量在30%时,拉伸强度和断裂延伸率出现了较大幅度的下降,分别为41.28%、66...  相似文献   

11.
A novel red long-lasting phosphor, (Y1−x Gd x )2O3:Eu3+, Sm3+, Si4+, Mg2+, was synthesized by the co-precipitation method using oxalate precipitation as the precursor. X-ray diffraction (XRD), scanning electronic microscopy (SEM), integrated thermal analyzer (TG), and photoluminescence spectra (PL) as well as the ST-900PM weak light photometer were used to study the synthesis conditions, morphology, luminescence properties, and the decay time of the phosphor. The XRD results show that the products synthesized at 1400°C for 4 h have good crystallization without any detectable impurity phases. Based on the PL spectra, the optimal conditions are as the following. The molar ratios of Y3+ to Gd3+ and Eu3+ to Sm3+ are 2:8 and 3:1, respectively, and the contents of Mg2+ and SiO2 are 5mol% and 3mol%, respectively. The decay time monitored by the ST-900PM weak light photometer is 7200 s, increasing 44% and 100%, respectively, compared with the Eu3+ and Sm3+ single-doped phosphors. The results indicate that the energy transfer is from Sm3+ to Eu3+ ion, and Sm3+ is a good sensitizer to Eu3+.  相似文献   

12.
Gd2O3:Eu3+ downconversion luminescent powder was prepared using the homogeneous precipitation method. Its optical properties were analyzed and it was introduced into a dye-sensitized solar cell (DSSC). As a luminescence medium, Gd2O3:Eu3+ improved light harvesting via conversion luminescence and increased the photocurrent of the DSSC. As a p-type dopant insulating rare earth oxides form an energy barrier, and the Gd2O3:Eu3+ elevated the energy level of the oxide film and increased the photovoltage. The photoelectric conversion efficiency for a DSSC with Gd2O3:Eu3+ doping (6:100) reached 7.01%, which was 17.4% higher than the photoelectrical conversion efficiency of a DSSC without Gd2O3:Eu3+ doping.  相似文献   

13.
We apply antilocalization measurements to experimentally study the interactions and exchange between InAs surface accumulation electrons and local magnetic moments of the rare earth ions Sm3?,Gd3?,Ho3?,and Dy3?,of the transition metal ions Ni2?,Co2?,and Fe3?,and of Fe3O4nanoparticles and Fe3?-phthalocyanine deposited on the surface.The influence of the deposited species on the surface electrons is observed through the changes in the spin–orbit scattering and magnetic spin-flip scattering rates,which carry information about magnetic interactions.Experiments indicate a temperature-dependent magnetic spin-flip scattering for Ho3?,Dy3?,Ni2?,and Co2?.Concerning the spin–orbit scattering rate,we observe an increase,except for the cases of Ni2?,Fe3?,Fe3O4nanoparticles and Fe3?-phthalocyanine.We also observe an increase in SO scattering in another system where we study the interactions of Au nanoparticles and ferromagnetic Co0.6Fe0.4nanopillars and an In0.53Ga0.47As quantum well.Experimental results are analyzed and compared to theoretical models.Our method provides a controlled way to probe the quantum properties of two-dimensional electron systems,either on the surface of InAs or in a quantum well.  相似文献   

14.
Magnetic Co1-xNixFe2O4 nanoparticles (NPs) were successfully synthesized via a solvothermal method using ethylene glycol as solvent.The samples were characterized by X-ray diffraction (XRD),field emiss...  相似文献   

15.
We have prepared a series of(ZnO)1-x(Fe2O3)x≤0.10bulk samples with various concentrations of Fe dopant by ball milling and investigated their structural, compositional, optical and magnetic properties by means of X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS),Raman spectrometer and vibrating sample magnetometer(VSM), respectively. Information about different impurity phases was obtained through Rietveld refinements of XRD data analysis. XPS results showed different valence states(Fe2+ tand Fe3+) supported by shaking satellite peaks in samples. With increasing Fe doping percentage, the crystal quality deteriorated and a shift of E2 low band(characteristic of ZnO) has been observed in Raman spectra. Energy band gap estimated from reflectance UV–vis spectroscopy showed shift for all bulk samples. The magnetic behavior was examined using a vibrating sample magnetometer(VSM), indicating ferromagnetic behavior at room temperature(300 K). The effective magnetic moment per Fe atom decreases with increase in doping percentage which indicates that ferromagnetic behavior arises from the substitution of Fe ions in the ZnO lattice.  相似文献   

16.
Typical O??-sialon-based ceramics, with a formula of Si2?x Al x O1+x N2?x , where x was set as 0.25, were fabricated by in-situ synthesis. Si3N4, Al2O3, and SiO2 powders were used as raw materials, and MgO and Y2O3 were added as sintering additives. All the samples were sintered at different temperatures under a nitrogen pressure of 0.25?C0.30 MPa, and their microstructure, phase content, and thermal conductivity were evaluated. The effects of O??-sialon and ??-Si3N4 on the thermal conductivity were analyzed by numerical calculation in detail. In the case of the similar porosity, the thermal conductivity of O??-sialon-based ceramics decreased with the ratio of O??-sialon/??-Si3N4 increasing. When the ratio was 12, the thermal conductivity of O??-sialon ceramics sintered at 1360°C was 1.197 W·m?1·K?1.  相似文献   

17.
A new series of solid solutions Lu2W3−x Mo x O12 (0.5≤x≤2.5) were successfully synthesized by the solid-state method. Their crystal structure and negative thermal expansion properties were studied using high-temperature X-ray powder diffraction and the Rietveld method. All samples of rare-earth tungstates and molybdates are found to crystallize in the same orthorhombic structure with space group Pnca and show the negative thermal expansion phenomena related to transverse vibration of bridging oxygen atoms in the structure. Thermal expansion coefficients (TEC) of Lu2W3−x Mo x O12 are determined as −20.0×10−6 K−1 for x=0.5 and −16.1×10−6 K−1 for x=2.5 but -18.6×10−6 and −16.9×10−6 K−1 for unsubstituted Lu2W3O12 and Lu2Mo3O12 in the identical temperature range of 200 to 800°C. High-temperature X-ray diffraction (XRD) data and bond length analysis suggest that the difference between W-O and Mo-O bond is responsible for the change of TECs after the element substitution in this series of solid solutions.  相似文献   

18.
Powders of spinel LiLaxMn2—xO4 were successfully synthesized by the ultrasonic-assisted sol-gel (UASG) method. The structure and properties of LiLaxMn2—xO4 were examined by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electronic microscopy (SEM), galvanostatic charge-discharge test, and cyclic voltammetry (CV). XRD results show that the La3+ can partially replace Mn3+ in the spinel and the doped materials with La3+ have a larger lattice constant compared with pristine LiMn2O4. FT-IR indicates that the absorption peak of Mn3+−O and Mn4+− O bonds has a red and blue shift with the increase of doping lanthanum in LiLaxMn2—xO4, respectively. The charge-discharge test exhibits that the initial discharge capacity of LiLaxMn2—xO4 drops off, and the capacity retention increases gradually at C/5 discharge rate with the increase of doping lanthanum, and LiLa0.01Mn1.99O4 has a higher discharge capacity and a better cycling performance at 1C discharge rate. CV reveals that the doping La3+ is beneficial to the reversible extraction and intercalation of Li+ ions.  相似文献   

19.
The major drawbacks of Nd-Fe-B magnets are relatively low Curie temperature and poor thermal stability. Ribbons with the near stoichiometric 2:14:1 composition of Nd10.8Dy0.75Tb0.75Fe79.7-xCoxZr0.8Nb0.8Cu0.4B6.0 (x=0, 3, 6, 9, 12, 15) were prepared by rapid quenching and subsequent heat treatment. The effect of Co element on the magnetic properties, thermal stability, and microstructure of the ribbons was systematically studied by vibrating sample magnetometer (VSM), thermal magnetic analysis, atomic force microscopy (AFM), and transmission electron microscopy (TEM). It was found that Co substitution was significantly effective in improving the magnetic properties and the thermal stability of nanocrystalline ribbons. Although the intrinsic coercivity decreased from 1308.7 kA/m for x=0 to 817.4 kA/m for x=15, the remanence polarization and maximum energy product increased from 0.839 T and 116.5 kJ/m3 for the Co-free samples to 1.041 T and 155.1 kJ/m3 for the 12at% Co-substituted samples, respectively. About 10 K increase in Curie temperature was observed for the 2:14:1 phase with 1at% Co substitution. The absolute values of temperature coefficients of induction and coercivity were significantly decreased with Co substitution, which may be attractive for high operational temperature applications. The microstructure of nanocrystalline ribbons was slightly refined with Co substitution.  相似文献   

20.
CaO-Al2O3-SiO2 (CAS) glass-ceramics were prepared via a melting method using naturally cooled yellow phosphorus furnace slag as the main raw material. The effects of the addition of Fe2O3 on the crystallization behavior and properties of the prepared glass-ceramics were studied by differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The crystallization activation energy was calculated using the modified Johnson-Mehl-Avrami equation. The results show that the intrinsic nucleating agent in the yellow phosphorus furnace slag could effectively promote the crystallization of CAS. The crystallization activation energy first increased and then decreased with increasing amount of added Fe2O3. At 4wt% of added Fe2O3, the crystallization activation energy reached a maximum of 676.374 kJ·mol-1. The type of the main crystalline phase did not change with the amount of added Fe2O3. The primary and secondary crystalline phases were identified as wollastonite (CaSiO3) and hedenbergite (CaFe(Si2O6)), respectively.  相似文献   

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