Preparation of NiO nanoparticles from Ni（OH）2-NiCO3-4H2O precursor by mechanical activation

A mechanical activation process was introduced as a facile method for producing nickel oxide nanopowders. The precursor compound Ni（OH）2-NiCO3-4H2O was synthesized by chemical precipitation. The precursor was milled with NaCl diluent. A high-energy ball milling process led to decomposition of the precursor and subsequent dispersal in NaCl media. Nickel oxide nanocrystalline powders were produced by subsequent heat treatment and water washing. Milling rotation speed, milling time, ball-to-powder ratio （BPR）, and nickel chlo-ride-to-precursor ratio were introduced as influential parameters on the wavelength of maximum absorption （λmax）. The effects of these pa-rameters were investigated by the Taguchi method. The optimum conditions for this study were a milling rotation speed of 150 r/min, a mill-ing time of 20 h, a BPR of 15/1, and a NaCl-to-powder weight ratio （NPR） of 6/1. In these conditions,λmax was predicted to be 292 nm. The structural properties of the samples were determined by field emission scanning electron microscopy, X-ray diffraction, and energy dispersive spectrometry.     

带材板形自适应控制

通过对轧机液压弯辊系统特性深入细致的分析,提出了采用具有极点配置广义自校正算法的控制策略。在此基础上,设计了一个自校正控制器,它兼顾了系统的动态特性和稳态特性,并用它对本液压弯辊系统进行控制,仿真结果表明该控制系统的性能良好。     

Na_2CO_3调控醇热法制备规则形貌Ag纳米晶

以乙二醇为溶剂、Na2S为成核剂、聚乙烯吡喏烷酮(PVP)和Na2CO3为修饰剂,采用醇热法制备不同形貌的Ag纳米晶。通过调节反应时间、Na2CO3浓度、滴加速率以及起始滴加时间等来调控Ag纳米晶的微结构。利用场发射扫描电子显微镜(FESEM)和紫外-可见光(UV-vis)吸收光谱对Ag纳米晶的形貌和尺寸以及局域表面等离子特性(LSPR)进行表征。结果表明:浓度为50μmol/L的Na2CO3,在AgNO3滴加完毕后5.5 min时以2 mL/min的速率滴加到体系中反应3 h,能够得到平均颗粒尺寸为60 nm、尺寸分布均匀的截角立方Ag纳米晶。     

略谈磁性指向器的形制

司南是最早的磁性指向器.北宋时期,磁化技术的突破,导致磁性指向器的形制有了新的演变,其中,用针指向是磁性指向器形制最重要的改进.指南针的出现,极大提高了磁性指向器的指向精度,加快了磁偏现象的发现.之后,指南针的形制仍不断被改进,指南鱼发展成水罗盘,用以指向的木刻鱼被穿上小木条的磁针取代,"指南鱼"的形制消失;指南龟发展成枢轴支承式,成了旱罗盘.本文对磁性指向器的发明和演进过程稍作梳理,希望对帮助广大读者了解这一问题能够有所裨益.     

冷轧机的板形控制目标模型

建立了薄带冷轧机的板形自动控制目标设定模型，它以轧后带钢的在线屈曲和后屈曲理论为板形生成的力学判据，以实测带钢温度横向分布为补偿，分别在２０３０ＣＶＣ冷连轧机和１２５０ＨＣ冷轧机上运行成功，生产实绩证明其控制效果优于原用的引进模型，板形质量显著提高。     

一类C~2连续保形插值三次参数样条曲线的构造

本文给出插值三次参数曲线段在插值节点P_i(i=0,1,…,n)处切线和切矢量的选取方法,采用逐段构造,从而得到了通过平面上插值点列P_i(i=0,1…,n)的一类c~2连续保形插值三次参数样条曲线。     

钢管拱肋吊装线形控制与测量技术

通过工程实例，介绍了钢管拱桥缆索吊机悬臂吊装施工方法以及拱段的线形控制与测量等技术要点，阐述了拱段的安装、坐标参数的计算以及扣索索力计算等问题。     

热轧带钢板形板厚耦合特性变化机理与参数求解

通过对建立的耦合关系模型的分析,指出Mp,Mw,Q,Kp和Kw是决定工业轧机板形板厚综合控制系统耦合特性的参数。它们随实际轧制生产条件的变化而改变。采用有限元模型,结合工业轧机系统实测数据,给出1700mm热连轧机耦合特性参数的求解方法,该方法为板形板厚解耦设计的工业应用提供了切实可行的途径。     

Detection and response mechanism of CN− using Ag2S coated piezoelectric crystal sensor

A new method of determination of trace CN⁻ in water was proposed. A thin film of Ag₂S was electrochemically deposited on both sides of a silver coated piezoelectric crystal. The Ag₂S−Ag films can react with CN⁻ selectively, which causes the frequency shifts of the plezoelectric crystal. The frequency shifts are proportional to the concentration of CN⁻ in the range of 10⁻⁶≈10⁻³ g/L. XPS experiments indicated the sensing film was Ag₂S−Ag. A coordination complex Ag−CN⁻ was formed when Ag₂S−Ag film contacted with solution containing CN⁻ ion. A response mechanism was proposed based on the XPS data. Supported by National Natural Science Foundation of China Hu Jiming: born in Sept, 1952, Professor     

Scalable synthesis of A2S3 （A=Sb, Bi） submicro/nanowires using their powders via solvothermal proceeding

One-dimensional (1D) nanostructural materials of semiconductors are being widely studied due to their unusual opto-electronic properties and potential im-plementation as nanodevices[1―6]. The nanowires of A2S3 (A=Sb, Bi) are one of the most interesting 1…     

智能结构静态形状控制中压电执行元件最优位置选择

讨论智能结构静态形状控制中压电执行元件最优位置选择问题．确定出压电执行元件对智能结构静态形状控制效果的度量,并以此做为选择压电执行元件最优位置的定量指标．给出选择方法及数值示例．