共查询到20条相似文献,搜索用时 31 毫秒
1.
QIAN Shahua~ LUO Yan~ MO Shaobo~ WENG Yue~ . College of Resources Environmental Sciences Wuhan University Wuhan Hubei China . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China 《武汉大学学报:自然科学英文版》2006,11(2):437-440
0Introduction Vanadiumplaysanimportantroleinmodernindustry,es peciallyinsteelandchemicalindustry.Forinstance,itscompoundsarewidelyappliedintheproceduresofvitrioland petroleumchemicalmanufactureascatalyzers[14].Vanadium hasseveralvalences,butgenerallyitslowvalencesturnintohighoneseasilyinenvironment[5].BecauseV(Ⅴ)isthemost stableandpoisonousone,weoftenlayemphasisonitinenvi ronmentalpollutioncontrol.Vanadiumexistsinenvironmentalwaterwithextremelylowconcentration.Inseawateritscontentislessthan… 相似文献
2.
An electrochemical method for the simultaneous determination of lead(II) and Cadmium(II) with a calix[6]arene modified carbon
paste electrode (CPE) has been developed. Pb2+ and Cd2+ were accumulated at the surface of the modified electrode via formation of chemical complexes with calix[6]arene, and reduced
at 1.40 V. During the following anodic potential sweep, reduced lead and cadmium were oxidized, and two well-defined striping
peaks appeared at about −0.60 V and −0.84 V. Compared with a bare carbon paste electrode, the calix[6]arene modified CPE greatly
improves the sensitivity of determining lead and cadmium. The stripping peak currents change linearly with the concentration
of Pb2+ 3.0×10−8–8.0×10−6 mol·L−1 and with that of Cd2+ 6.0×10−8–1.0×10−5 mol ·L−1. The detection limits of Pb2+ and Cd2+ are found to be 8.0×10−9 mol·L−1 and 2.0×10−8 mol·L−1, respectively. The modified carbon paste electrode was applied to determine trace levels of lead and cadmium in water samples.
Comparing with that of atomic absorption spectrometry, the results suggests that the calix[6]arene modified CPE has great
potential for the practical sample analysis.
Foundation item: Supported by the National Natural Science Foundation of China (60171023)
Biography: JI Xiao-bo (1980-), male, Master, research direction: electroanalytical chemistry. 相似文献
3.
SHI Bo’an~ ZENG Danyun~ JI Xinghu~ XI Juan~ AI Xinping~ HE Zhike~ . College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China . Department of Chemistry Chemical Engineering Hubei Institute for Nationalities Enshi Hubei China 《武汉大学学报:自然科学英文版》2006,11(3):672-676
0 IntroductionThbiep ycroidmipnlee)xru ctahteinoinu mof(Ⅱ r)u t(he Rniuu(mbip,y m)3ai2n +ly) atrnids- t(r2is -,(21’ -,10-phenanthroline)ruthenium(Ⅱ) (Ru(phen)32 +) ,is a kindof sensitive analytical reagent for electrogenerated chemilumi-nescence(ECL) and chemiluminescence(CL) ,on which a par-ticular review has been presented[1]. The earliest publicationon the synthesis of Ru(bipy)32 +appeared in 1936[2], andduringthefollowing30 years ,theinvestigations relatedtothissubstance were only in… 相似文献
4.
Zhenrong Sun Shenyi Wang Yanping Huang Jiyun Lin Liangen Ding Zugeng Wang 《科学通报(英文版)》1998,43(5):399-402
The nonlinear refractive indexesn
2 for the ethanol solutions of 1, 10-phenanthroline (2.0 × 10−3 mol · L−1), [bis(l, 10-phenanthroline) lanthanum (III)] nitrate (1.0 × 10−3 mol · L−1), and [nitrato-fluoracil-bis (1, 10-phenanthroline) lanthanum (III) ] nitrate (1.0 × 10−3 mol · L−1) are first measured, the third-order nonlinear optical susceptibilities χ(3) and 〈γ〉 are calculated, and the mechanisms of the third-order optical nonlinearities enhanced by lanthanum (III) are discussed
preliminarily. 相似文献
5.
A carbon paste electrode modified with multi-walled carbon nanotubes (MWCNT) was prepared and the determination of ultra trace amount of zirconium based on the anodic adsorptive voltammetry of the zirconium-calcium-alizarin red S mix-polynuclear complex is described in this paper for the first time. The results showed that the sensitivity and the selectivity of the method are excellent. The second derivative linear scan voltammograms of the complex were recorded by polarographic analyzer from 200 to 1200 mV (vs. SCE) and it was found that the complex can be adsorbed on the surface of the electrode, yielding a peak at about 840 mV, corresponding to the oxidation of ARS in the complex. The peak current increases linearly with Zr (IV) concentration in the range of 6.0×10^-12--6.0×10^-11 mol. L^-1 (accumulation time 120 s), 6.0×10^-11--2.0×10^-9 mol. L-1 (accumulation time 90 s) and 2.0×10^-9--1.0×10^-7 mol. L^-1 (accumulation time 60 s) and the detection limit (S/N = 3) is 2.0×10^-12 mol. L^-1 (accumulation time 180 s). The procedure has been successfully applied to the determination of zirconium in the ore samples. 相似文献
6.
Wu Yun-hua Fei Jun-jie Dang Xue-ping Hu Sheng-shui College of Chemistry Molecular Sciences Wuhan University Wuhan Hubei China 《武汉大学学报:自然科学英文版》2004,9(3):366-370
0 IntroductionDetectionofammoniumionisveryimportantinmanyfields,suchashealthcare,agriculture ,cultivationandenviron mentalpollutioncontrol.Severalanalyticalmethodshavebeende velopedforammoniumdeterminationincludingionchromatography ,spectrophotometry,fluorimetryandchemiluminescence .MostofthemarebasedonspectrophotometryusingtheBerthelot reactionbetweenammonium ,phenol,andhypochloriteleadingtothefor mationofanindophenoldye[1 ] .Thereactiontimeisaboutanhour,andsomedissolvedorganicnitrogencompo… 相似文献
7.
Applications of crown ether cross-linked chitosan for the analysis of lead and cadmium in environmental water samples 总被引:2,自引:0,他引:2
A new type of crown ether cross-linked chitosan was synthesized by the reaction of chitosan with 4,4′-dibromodibenzo-18-crown-6
(Br-DBC). Its token structure was analyzed with FT-IR and NMR and the adsorption behaviors for lead and cadmium in environmental
water samples by FAAS were studied. In addition the best analysis conditions were discussed and the adsorption mechanism was
explained. As the enrichment factor is above 100, both recoveries are 94%–106%, the detection limits of lead and cadmium are
0.5μg·L−1 and 0.04 μg·L−1 and the relatively standard deviations of lead and cadmium are 3.1% and 2.8% respectively, this new method was successfully
applied to the determination of environmental water samples. This method is fast and simple and it greatly enhances the determination
ability of FAAS for lead and cadmium.
Foundation item: Supported by the State Education Committee Doctoral Foundation (No. 2000048615)
Biography: Tang Yu-rong(1943-), female, Associate professor, research direction: trace elements analysis. 相似文献
8.
The inclusion complex reaction condition and the mechanism of β-cyclodextrin with hymecromone have been studied by fluorescent
spectrum. The fluorescent intensity and the stability of the system can be qreatly increased in qiven condition, and the formation
constant of the inclusion complex reaction has been determined too. The system can be applied to the determination of trace
amounts of hymecromone, the maximum fluorescent intensity is obtained with excitation and emission wavelength at 362 nm and
452 nm, respectively. The linear range for hymecromone is 8.0×10−9 mol·L−1 to 1.0×10−5 mol·L−1. The detection limit is 1.8×10−9 mol·L−1. A simple, rapid and highly sensitive fluorimetric method is proposed for the determination of hymecromone. The results obtained
are in agreement with those given by an official method.
Foundation item: Supported by the National Natural Science Foundation of China (G1999046703)
Biography: Luo Zhao-fu(1947-), female, Associate professor. 相似文献
9.
A rapid and sensitive on-line preconcentration method for spectrophotometric determination of chromium (VI) in nature water
is described. Preconcentration and determination are based on (i) the quantitative and fast adsorption of chromium (VI) on
the high surface area nanometer-size TiO2 (anatase) powders, which prepared by a sol-gel method from hydrolysis of TiCl4 and (ii) the quantitative and reproducible elution of Cr (VI) by 2.0 mol·L−1 HCl. A mini-column system for preconcentration is developed, Cr(VI) on the mini-column is eluted and merged with a stream
water and DPCB (1,5-diphenylcarbazide) as the chromogenic reagent. The proposed system permits throughputs of 6 sample h−1 (0.001 μg·mL−1 Cr(VI)) or 20 sample h−1 (0.1 μg·mL−1 Cr(VI)). The preconcentration factor is 55. The detection limit is 0.8 ng · mL−1 Cr(VI). The reproducibility is satisfactory with a relative standard deviation of less than 3.35% (0.01 μg·mL−1 Cr(VI),n=5).
Supported by the National Natural Science Foundation of China
Ma Wanhong: born in 1961, Ph. D. Graduate student, Associate professor 相似文献
10.
The fluorescence intensity of the europium (III)-tetracycline (TC) complex can be greatly increased by TOPO, TBP, TTA and
surfactans, among which TOPO showed the greatest enhancement. The formation of ternary complex was proposed to be responsible
for the fluorescence enhancement. The Eu (III)-TOPO-TC system can be applied to the determination of trace amounts of tetracycline
in urinous sample; the maximum fluorescence intensity was obtained in the pH range of 8.2∼9.5 with excitation and emission
wave-lengths at 396 nm and 616 nm, respectively. The linear range for tetracycline is 6.0×10−9−5.0×10−7 mol·L−1. The detection limit is 2.0×10−9 mol·L−1(SNR=3). Experimental conditions and the mechanism of the enhancement effect are discussed.
Supported by National Natural Science Foundation of China
Huang Chunbao: born in 1958, Associate professor 相似文献
11.
Highly sensitive voltammetric method for the determination of estrogens, based on the enhancement effect of cetyltrimethylammonium
bromide (CTAB) has been described. In the presence of CTAB, the oxidation peak currents of estrogens (estradiol, estrone,
estriol, estradiol valerate and diethylstilbestrol) as the carbon paste electrode (CPE) increased significantly after open-circuit
accumulation. The peak current was proportional to the concentration of estradiol over the range from 5×10−9 to 2.5×10−6 mol·L−1. The detection limit was 8×10−10 mol·L−1 at 6 min of accumulation. The total amounts of estrogens in the blood serums were determined and the average recovery was
104.92%. Under the conditions used, the electrode process of estradiol was examined the mechanism for peak current enhancement
was also discussed.
Foundation item: Supported by the National Natural Science Foundation of China (60171023) and the Natural Science Foundation
of Hubei Province (99J060)
Biography: Wu Kang-bing(1977-), male, Ph.D. candidate. research direction: bioelectrochemistry. 相似文献
12.
CHEN Lihua~ ZHANG Yongkang~ YIN Hong~ LIU Liuzhan~ YANG Zhaoxia~ SHEN Hanxi~ . College of Chemistry Chemical Engineering Jishou University Jishou Hunan China . College of Chemistry Nankai University Tianjin China 《武汉大学学报:自然科学英文版》2006,11(3):704-708
0 IntroductionMaalnadria siusb atr ompajicosr .he aAltrthe pmrisoibnlienmi (n qtihneghtraoopsiucs,QHS,Fig.1) is a sesquiterpene endoperoxide isola-ted fromArtemisia annuaL., an ancient Chineseherbal medicine usedfor treatment of fever and ma-laria.Studies of the structure and activity relation-ship have shownthat endoperoxide groupis essentialfor anti malarial activity of QHS and absence of thismoiety lead to completely loss in activity of thedrug. Many techniques have been developed to de… 相似文献
13.
LI Huili LUE Bingnan WANG Dan LIU Xinyue 《武汉大学学报:自然科学英文版》2007,12(3):548-552
An expanded granular sludge bed (EGSB) reactor was adopted to study the influence factors and rule of enhancing granular sludge concentration and performance. The experiment was performed at 33 ℃, pH 6.0-8.0 with continuous flow by adding proper quantity of nutritional trace elements. The results show that SLR was the key of steady operation of EGSB reactor. The increment of the granular sludge was influenced by volume loading rate (VLR), liquid up-flow velocity and sludge loading rate (SLR). Concentration of granular sludge increased rapidly when liquid up-flow velocity was over 0.94 m · h^-1 with SLR being at 1.0-2.0 d ^-1. With the propriety parameters: liquid up-flow velocity 2.52 m · h^-1, SLR 1.0-2.2 d^-1 and VLR 8.2-13.1 kg · m ^3 · d^-1, 23 days' continuous operation resulted in an increment by over 80% of granular sludge concentration in the EGSB reactor, plus good granular sludge property. 相似文献
14.
DU JinFeng LI Ying ZHANG Qi YAO XiaoJun 《科学通报(英文版)》2007,52(2):200-204
The presence of several high affinity binding sites on human serum albumin (HSA) makes it a possible target for many drugs. This study is designed to examine the effect of aloe-emodin on HSA by fluo-rescence, CD spectroscopy and molecular modeling. The results of fluorescence measurements sug-gested that the hydrophobic interaction was the predominant intermolecular force stabilizing the AE-HSA complex, which was in good agreement with the result of molecular modeling study. And the enthalpy change ΔH0 and the entropy change ΔS0 were calculated to be -7.041 kJ·mol-1 and 76.619 J·mol-1·K-1 according to the Van't Hoff equation. The alterations of protein secondary structure in the presence of AE in aqueous solution were quantitatively calculated from CD spectra, and the content of α-helices obviously increased. 相似文献
15.
A new method for determination of trace sillicon in high purity lanthanum oxide by using electrothermal vaporization (ETV)-ICP-AES
with polytetrafluoroethylene (PTFE) slurry as a fluorinating reagent has been proposed. Under the optimized experimental conditions,
the fluorination reactions of analyte (Si) and matrix(La) with PTFE in the graphite furnace took place at high temperature,
and the fractional volatilily between Si and La was observed. Based on this principle the matrix interference could be eliminated.
The detection limit of Si was 4.0μg·L−1, and the RSD was 3.4%(C=0.2mg·L−1,n=10). The procedure proposed has been applied successfully to determine trace Si in La2O3 without any chemical pre-treatment.
Supported by the National Natural Science Foundation of China
Qin Yongchao: born in Dec. 1953, ph. D., Assciate Professor 相似文献
16.
QIAN Shahua LIN Han LI Xueqin XIAO Mei DENG Hongbing XIANG Luojing School of Resource Environmental Science Wuhan University Wuhan Hubei China 《武汉大学学报:自然科学英文版》2007,12(2):349-352
A new absorbent of nanometer-size TiO2 colloid for Cu(Ⅱ) was studied in this work. The adsorption rate could reach above 99% when the pH values were at the range of 5-6. The adsorption balance time, adsorption capacities, and the eluent were investigated. A novel method of trace Cu(Ⅱ) preconcentration and separation with nanometer-size titanium dioxide colloid and determination by flame atomic absorption spectrometry (FAAS) was advanced. The detection limit (3σ) of the method was 1.15 μg· L~(-1) , and the relative standard deviation (R.S.D) was 1.53% (n=6). Environmental sample experiments were also conducted to test the feasibility of the method, and it came out that the recovery rates were between 95.9% and 97.8%. 相似文献
17.
A novel material MnO2 nanosheet has been used as the support matrix for the immobilization of horseradish peroxidase (HRP). HRP entrapped in MnO2 nanosheet film exhibits facile direct electron transfer with the electron transfer rate constant of 6.86 s^-1. The HRP/MnO2 nanosheet film gives a reversible redox couple with the apparent formal peak potential (E^0') of -0.315 V (vs. Ag/AgCl) in pH 6.5 phosphate buffer solution (PBS). The formal potential E^0' of HRP shifts linearly with pH with a slope of -53.75 mV.pH^-1, denoting that an electron transfer accompanies single-proton transportation. The immobilized HRP shows an electrocatslytic activity to the reduction of H2O2. The response time of the biosensor for H2O2 is less than 3 s, and the detection limit is 0.21 μmol · L^-1 based on signal/noise = 3. 相似文献
18.
The contribution of root respiration to soil CO2 efflux in Puccinellia tenuiflora dominated community in a semi-arid meadow steppe 总被引:3,自引:1,他引:3
WANG Wei GUO Jixun 《科学通报(英文版)》2006,51(6):697-703
Rising atmospheric CO2 and temperature are altering ecosystem carbon cycling. Grasslands play an important role in regional climate change and global carbon cycle. Below-ground processes play a key role in the grassland carbon cycle because they regulate … 相似文献
19.
A new fluorescent reagent, 7-(8-hydroxy-3, 6-disulfonaphthylazo)-8-hydroxyquinoline-5-sulfonic acid (HDNHQ) for the determination
of magnesium has been developed. It reacted with magnesium to form a 1∶1 fluorescent complex withλ
ex/λ
em immediately at room temperature in ammonia-ammonium chloride buffer (pH 10.7). A linear relationship was obtained in the
magnesium concentration range of 0–160 ng·mL−1 with the detection limit of 0.04 ng·mL−1. The proposed method was simple, rapid and sensitive. It has been successfully applied to the determination of trace magnesium
in blood serum with recoveries of 103.75% and 98.16%, respectively.
Foundation item: Supported by the Zi-Qiang Foundation of Wuhan University
Biography: Zhang Xian (1975-), female, Ph. D candidant, research direction: organic reagent synthesis and analysis. 相似文献
20.
A new chemiluminescence (CL) method for the determination of tetracycline and oxytetracycline is developed, based on the CL
reaction of tetracycline and oxytetracycline with Ru (bipy)3
2+ and Ce (IV). In sulfuric acid medium, the CL emission is generated upon continuous oxidtion of Ru(bipy)3
2+ by cerium (IV). The emission intensity is greatly enhanced when tetracycline and oxytetracycline are introduced into the
reaction system after acid degradation. Under the optimum conditions, the calibration curves are linear over the range of
8.0×10−8∼4.0×10−6 mol/L for tetracycline and of 2.0×10−7∼4.0×10−5 mol/L for oxytetracycline, with the detection limits are 4.2×10−8 mol/L for tetracycline and 1.5×10−7 mol/L for oxytetracycline, respectively. The proposed method was used for the determination of tetracycline and oxytetracycline
in pharmaceutical formulations with good results.
Foundation item: Supported by the National Natural Science Foundation of China and the Natural Science Foundation of Hubei
Province.
Biography: HAH He-you (1962), male, Associate profeddor, Ph.D graduate candidate. Present address, Department of Chemistry,
Huainan Teacher's College, Huainan. 相似文献