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1.
细粒焦对废水中酚的吸附研究   总被引:1,自引:0,他引:1  
用焦化厂细粒焦对废水中苯酚进行吸附,并研究了各种主要因素对苯酚吸附率的影响。实验结果表明:在25℃时,细粒焦的用量为2.5%,细粒焦粒径为0.0760.097mm,pH=2.0,反应时间为120min,在浓度为40mg/L的苯酚溶液中,苯酚的去除率可达98%以上。同时探讨了细粒焦对焦化厂含酚废水处理的可行性。  相似文献   

2.
目的探讨用差值吸收光谱法测定废水中微量苯酚的有效方法。方法基于在λ=280nm波长处,苯酚的碱性溶液和中性溶液的差值吸光度与苯酚的浓度呈线性的关系,采用分光光度法对废水中的苯酚进行定量分析。结果分光光度法对废水中的苯酚进行定量分析方法的线性范围为0~3.6×10-3g/L,回收率为98.6%~103.3%,检出限为0.9μg/L,5次重复测定其相对标准偏差不足1.5%。结论分光光度法用于废水中微量苯酚的测定不仅具有快速、灵敏,实验结果稳定、可靠之特点,而且有效地消除了紫外-可见分光光度法中有机杂质的干扰。  相似文献   

3.
以磷酸三丁酯(TBP)为萃取剂,分别用正辛醇、氯仿、四氯化碳、石油醚和环己烷作为稀释剂萃取邻甲苯酚(o-cresol)稀溶液.系统研究了络合萃取剂对邻甲苯酚溶液的相平衡分配比;试验了萃取剂浓度、稀释剂种类、盐效应以及溶液pH值对萃取平衡分配比的影响;利用红外光谱测定了负载有机相中萃合物的结构,定性分析了络合萃取过程.  相似文献   

4.
以钛钌电极为阳极、钢板为阴极,对含对硝基苯酚(PNP)的模拟废水进行了电化学处理.试验研究了外加电压、极板间距、电解质质量分数、溶液pH值、电解时间等因素对PNP处理效果的影响,结果表明:外加电压7V,pH=10~11,极板间距2cm。支持电解质Na2S04质量分数0.5%的条件下,电解5h,PNP的去除率可达89.3%.  相似文献   

5.
采用一锅超声回流法制备一种新型的二氧化钛-氧化石墨烯(TiO2-GO)复合材料, 通过X射线衍射(XRD)、红外光谱(IR)和 Raman光谱对其结构进行表征, 并研究溶液的pH值、 吸附温度、 吸附时间、 溶液的初始质量浓度对该材料作为吸附剂对苯酚废水去除效果的影响. 实验结果表明: 400 mg/L的苯酚溶液, 室温下, pH=5时,该材料对苯酚的吸附量为80 mg/g;吸附过程符合Langmuir模型,动力学实验数据符合准二级动力学曲线; TiO2-GO可在30 min内有效净化苯酚废水,具有一定的应用前景.  相似文献   

6.
研究了超声波降解苯酚废水的效果和超声波对降解效果的影响因素,实验结果说明溶液初始浓度,温度,pH等因素对苯酚降解效果有明显影响.结果表明:溶液的初始浓度为135.15mg/L,超声辐射时间为4小时,温度为30°C,pH=3.0时,超声波降解苯酚的效果较好,为5.64%.曝气可以促进苯酚的降解,加入H2O2可使降解率提高到61.60%.  相似文献   

7.
研究了超声波降解苯酚废水的效果和超声波对降解效果的影响因素,实验结果说明溶液初始浓度,温度,pH等因素对苯酚降解效果有明显影响.结果表明:溶液的初始浓度为135.15mg/L,超声辐射时间为4小时,温度为30℃,pH=3.0时,超声波降解苯酚的效果较好,为5.64%.曝气可以促进苯酚的降解,加入H2O2可使降解率提高到61.60%.  相似文献   

8.
固定化酪氨酸酶去除水中酚及胺类物质的研究   总被引:4,自引:0,他引:4  
探讨了一种以酶处理含酚废水的方法。将酪氯酸酶固定化到疏水基团修饰的琼脂珠上,蛋白吸附率和酶活力回收分别达到了90%和80%。经过固定化酪氨酸酶的处理,水溶液中的酚类物质被 氧化,最终生成棕色或黑色沉淀,因而很容易支除。并且,溶液中的胺类化合物和酚的氧化产物聚合生成棕色沉淀而被除去。酚类化合物的去除速度为:邻苯二酚〉对甲苯酚〉对氯苯酚〉苯酚〉对甲氧基苯酚。  相似文献   

9.
从邻甲代烯丙氧基苯酚反应合成呋喃酚的反应历程出发,建立了邻甲代烯丙氧基苯酚合成呋喃酚的动力学模型.在数值模拟,仿真优化以及实验室工作的基础上,对环合反应的工艺操作条件进行了优化,即反应温度152 ℃,邻甲代烯丙氧基苯酚的初始质量分数为32%,催化剂质量分数为邻甲代烯丙氧基苯酚质量的3.0%,反应时间10 h.在此工艺条件下,反应的转化率可以达到96%以上,收率大于75%.同时环合动力学模型的建立也为呋喃酚的工业生产装置的放大与设计提供了理论基础.  相似文献   

10.
探讨了以邻频丁基苯酚为原料,四氧化碳为溶剂,硝酸为硝化剂硝化合成DNBP(邻频丁基-4,6二硝基苯酚)的新工艺,用正交实验确定了反应条件对DNBP收率的影响,确定了合成DNBP的最佳工艺条件,在此反应条件下DNBP的收率约为85%。对含酸废水进行了进一步处理,实验证明,含酸废水可循环利用。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

18.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

19.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

20.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

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