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1.
研究了Na2SO4-NaCl-NaHCO3-(NH4)2SO4-NH4Cl-NH4HCO3-H2O体系在拽定温度下的溶解度关系。结果表明该五元交互体系的相图是由7个结晶区组成。在A4,B4,C4,D4四个五元零变量点中,A4和D4为相应体系的干涸点。 相似文献
2.
合成了新型蓝色光致发光材料Ca8Mg(SiO4)4Cl2:Ce(3+),并对其进行了光谱测试.分析了Ce(3+)在Ca8Mg(SiO4)4Cl2晶体中应占据的晶体学格位.测试结果表明,在紫外光激发下,Ca8Mg(SiO4)4Cl2:Ce(3+)的发射光谱为一峰位在410nm~425nm之间的宽谱带,经分析确认作为发光中心的Ce(3+)占据Ca8Mg(SiO4)4Cl2晶体中多面体八配位的Ca(Ⅱ)格位. 相似文献
3.
以3,3-二甲基-(1H-1,2,4-三唑)-2-丁酮为配体(L)和不同铜盐反应,合成了六个Cu(Ⅱ)配合物CuL2Cl2、CuL2BT2、CuL3(BF4)2、CuL4(ClO4)2和CuL4SO4·4H2O),通过元素分析、摩尔电导、红外,研究了配合物的组成、结构和性质,并测定了CuL4(ClO4)2的晶体结构。 相似文献
4.
C4k∪C4k∪Cm的优美性 总被引:2,自引:0,他引:2
董俊超 《烟台大学学报(自然科学与工程版)》1999,12(4):238-241
C4k∪C4k的优美性已被证明,本文研究C4k∪Ck∪Cm的优美性。给出了其为优美图的必要条件,同时给出了C4k∪Ck∪Ck-1,C4(3t+1)∪C(t+1)∪C4(2t+1)以及C4(3t+1)∪C(3t-1)∪Ct-1的优美标号。 相似文献
5.
宫宝安 《烟台大学学报(自然科学与工程版)》1994,(1):36-42
对典型的多面体碳烷系列体系C_4H_4、C_6H_6、C_8H_8、C_(10)H_(10)、C_(20)H_(20)、C_4(CH_3)4、C_8(CH_3)8、C_(10)(CH_3)_(10)和四面体碳烷系列体系C_4H_4、C_4Li_4、C_4Na4、C_4Cl_4、C4F_4、C_4(CH_3)、C_4(pH_3)_4、C_4(PCl_3)_4、C_4(PF_3)_4,本文用量子化学中的CNDO/2计算方法,进行了相对的电子结构研究和比较。结果表明,具有“给体行为和”受体行为的配体,有助于级解四面体碳骨架特有的紧凑张力,从而提高相应的四面体碳烷分子的稳定性。 相似文献
6.
本文合成了4,4′-联吡啶为桥联配体的多核Cu(Ⅱ)配合物(Cu(phen)(μ-4,4′-bpy)(ClO4)2)n.H2O(phen=1,10菲咯啉,4,4′bpy=4,4′联吡啶),于定温下测定了该配合物的晶体结构,Cu(Ⅱ)的配位环境是一个畸变八面体,Cu(Ⅱ)通过4,4′联吡啶连接成锯齿状的链。 相似文献
7.
用气体电量计法分解极化曲线研究了温度对PbO2,Pt电极上Ce^4+阳极形成过程的影响,得到了两电极上Ce^4+和O2的表现活化能,在Pt电极上Ce^4+的活化能在于O2的活化能;温度升高时使Ce^4+的电流效率升高,但PbO2电极上Ce^4+的活化能小于O2的活化能,温度升高时Ce^4+的是流效率降低,研究了不同Ce^3+浓度对Ti/Pt基MnO2电极上Ce^4+阳极形成过程的影响,得到出该反应 相似文献
8.
中原油田储层结垢预测 总被引:6,自引:0,他引:6
详细分析研究了中原油田地层产出水,注入水和各种处理水遥离子组成及特点,并采用结垢指数法,饱和系数法和饱和指数法对储层结垢进行了预测。结果表明,中原油田文一污,文二污,濮一污前注入水和各种处理水等在油藏条件下都有结垢趋势存在,结后物质主要为CaCO3、CaSO4、BaSO4、SrSO4,其中CaCO3的结垢趋势最大,CaSO4、BaSO4、SrSO4的结垢趋势相对较小;随着储层温度增加,CaCO3、 相似文献
9.
偶氮,亚胺,酯类液晶的合成及中心桥键对介晶性的影响研究 总被引:1,自引:1,他引:0
报道了偶氮化合物p-H21C10O-C6H4-N→‖N-C6H4-COOCh,亚胺化合物p-H21C10O-C6H4-CH→‖N-C6H4-COOCh,酯类化合物p-H21C10O-C6H4-COOCh,(Ch as the abbreviation of cholesteryl group)的合成,结构鉴定,以及DSC和偏光显微镜对其介晶性研究的结果,并对中心桥键对介晶性的影响进行了讨论。 相似文献
10.
四甲基环戊二烯与五羰湛铁在二甲苯中加热回流6h,即生成标题化合物1,1与碘在氯仿中反应生成Fe-Fe键断裂在铁碘化物(C5HMe4)Fe(CO)2I,2,1与氯化汞反应生成Fe-Fe键断裂的铁氯汞化物(C5HMe4)Fe(CO)2HgCl3和铁氯化物(C5HMe4)Fe(CO)2Cl4.1与氯化亚锡反应仅分离到铁氯化物4.以元素分析,IR和HNMR谱表征化合物1~4的结构。 相似文献
11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness. 相似文献
12.
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly. 相似文献
13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。 相似文献
14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death. 相似文献
15.
Miao Maosheng 《华南师范大学学报(自然科学版)》2014,(6)
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula- 相似文献
16.
Yang Weitao 《华南师范大学学报(自然科学版)》2014,46(6):137-138
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re- 相似文献
17.
Bernard Kirtman 《华南师范大学学报(自然科学版)》2014,(6)
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that 相似文献
18.
《上海师范大学学报(自然科学版)》2014,(5):550
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with 相似文献
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《吉林大学学报(理学版)》2014,(5):1105
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has 相似文献