CuZrAlNb非晶复合材料的摩擦磨损性能

为探讨元素Nb对CuZrAl体系磨损性能的影响,制备了CuZrAlNb非晶复合材料.通过扫描电镜、X射线衍射仪和摩擦磨损试验机分别对Cu44.6Zr48 Al4 Nb3.4和Cu45Zr48Al4Nb3合金的显微组织、相组成及摩擦磨损性能进行研究.结果表明：Nb元素微量添加能够改变合金的显微结构及磨损性能.Cu45Zr48 Al4 Nb3为非晶复合材料,摩擦系数相对较大、耐磨系数最大,磨损机制为黏着磨损并伴随磨粒磨损,耐磨性能好;Cu44.6Zr48Al4Nb3.4为非晶合金,其摩擦系数、耐磨系数小于Cu45Zr48Al4Nb3非晶复合材料,磨损机制为黏着磨损.该研究为实际生产CuZrAlNb非晶复合材料提供了基础数据.     

Formation and mechanical properties of Zr-based bulk metallic glass composites with high oxygen levels

Zr-based bulk metallic glass(BMG) composites with in situ formed Y 2 O 3 particle reinforcements were synthesized by proper additions of Y to ultrahigh-oxygen-containing glass-forming alloy precursors.Microstructures,thermal stabilities,and mechanical properties of the composites were investigated.Glass formation was greatly enhanced by Y additions in the alloys and the resultant particles were homogenously distributed in the glassy matrix,allowing for the fabrication of oxide dispersion strengthened BMG composites.The compressive strength and hardness increased by 10% and 20%,respectively,with the introduction of Y 2 O 3 particles.These results are significant for the design and production of Zr-based BMGs and BMG composites with improved properties using commercial high-oxygen content raw materials under industrial conditions.     

Effects of density difference of constituent elements on glass formation in TiCu-based bulk metallic glasses

Glass formation is generally favored by a large atomic size mismatch among constituent elements,which usually leads to large density differences among them as well.During melting,elemental segregation occurs due to Stokes’ law and then inevitably affects glass formation.In this paper,such effects on glass-forming ability in a TiCu-based alloy system have been demonstrated.In the bulk glassforming composition Ti43Cu42Hf14Si1,macroscopic segregation of Si was observed in the as-melted ingots and silicon was completely depleted in the as-cast rods.In another Ti33Cu47Ni8Zr11Si1 alloy,nevertheless,the effects of density differences among the constituent elements were less severe.It was also confrmed that using proper pre-alloys could be an effective way in alleviating the side effects of the elemental segregation.     

ZrCuAlMo大块非晶的制备及热稳定性研究

通过铜模吸铸法制备（Zr47Cu44Al9）100-xMox（x=0,1,2,3）大块非晶合金.利用X射线衍射、差热分析等,研究分析添加Mo对Zr47Cu44Al9合金非晶形成能力及热稳定性的影响.结果表明,Mo的添加量为2%时,合金具有最大的非晶形成能力,纯非晶试样的临界尺寸从4mm增大到6mm以上,8mm的样品只有微弱的衍射峰.Mo提高非晶形成能力的原因主要是抑制引起异质形核的CuZr相的析出与长大.利用Kissinger方法计算得到的其玻璃转变激活能Eg为278.57kJmol-1、晶化激活能Ex为392.46kJmol-1、晶化峰值的激活能Ep为376.97kJmol-1.与原合金相比,晶化激活能与晶化峰值激活能的数据都增大,说明Mo的添加不仅提高了原合金的非晶形成能力,同时也增强了合金的热稳定性.     

Relationship between composite structures and compressive properties in CuZr-based bulk metallic glass system

Bulk metallic glass (BMG) composites with the austenite B2 phase as reinforcement macroscopically showed strain hardening behavior due to the plasticity induced by martensitic transformation during deformation. Relationship between characteristics of the B2-CuZr reinforcing phase and uniaxial compressive properties of CuZr-based BMG composites was studied. Mechanical properties of these BMG composites were found to depend on not only the reinforced phases but also the amorphous matrix,and the yield and fracture strength can be roughly estimated by the rule of mixture principle. Distribution of the reinforced B2-CuZr phase has an important impact on the compressive plasticity even for the composites with a similar volume fraction of the crystalline phase.     

Effect of TRT process on GFA, mechanical properties and microstructure of Zr-based bulk metallic glass

The effect of yttrium addition on the glass-forming ability(GFA) and mechanical properties of the Zr-based (Zr_(0.525)Al_(0.1)Ti_(0.05)Cu_(0.179)Ni_(0.146))_(100-x)Y_x and(Zr_(0.55)Al_(0.15)Ni_(0.1)Cu_(0.2))_(100-x)Y_x(x=0,0.2,0.4 0.6,1,2) alloys was studied.Micro-alloying of 0.6%yttrium enhances the room temperature ductility as well as the GFA of the Zr-based alloys.The mechanism of enhancing the GFA and room temperature ductility was analyzed.It is indicated that proper yttrium addition stabilizes the...     

块体Pd82Si18非晶合金的制备及晶化行为研究

采用玻璃包覆 水淬技术制备了块体Pd82Si18非晶合金．实验结果表明，净化对该熔体的非晶形成能力有很大的影响．通过对深过冷Pd82Si18合金的凝固行为研究发现，当过冷度大于190K时，过冷熔体会出现液相分离现象，热力学分析表明这将降低该过冷熔体的非晶形成能力．该非晶的晶化实验结果显示，与旋铸法制备的Pd82Si18非晶条带不同，块体非晶的晶化过程中出现两个放热峰，同时玻璃转变温度、晶化温度、过冷液相区都有相应的变化．通过分析可知Pd82Si18非晶合金的晶化过程与制备过程中的冷却速率有很重要的联系．     

Investigation of the microcrack evolution in a Ti-based bulk metallic glass matrix composite

The initiation and evolution behavior of the shear-bands and microcracks in a Ti-based metallic-glass–matrix composite(MGMC) were investigated by using an in-situ tensile test under transmission electron microscopy(TEM). It was found that the plastic deformation of the Ti-based MGMC related with the generation of the plastic deformation zone in crystalline and shear deformation zone in glass phase near the crack tip. The dendrites can suppress the propagation of the shear band effectively. Before the rapid propagation of cracks, the extending of plastic deformation zone and shear deformation zone ahead of crack tip is the main pattern in the composite.     

Zr_(55)Al_(10)Ni_5Cu_(30)大块金属玻璃的晶化行为研究

分别在603 K、653 K、683 K、723 K、753 K、793 K和0.5 h、1 h、2 h、3 h、5 h的保温时间下对Zr55Al10Ni5Cu30大块金属玻璃进行了退火热处理.采用x射线衍射(XRD)法分析了退火后Zr55Al10Ni5Cu30大块金属玻璃的弛豫和晶化相析出的过程,计算了不同温度下结晶度和纳米晶粒尺寸的大小.通过差示扫描量热(DSC)法分析了Zr55Al10Ni5Cu30大块金属玻璃的热稳定性.Kjssinger曲线分析表明,Zr55Al10Ni5Cu30大块金属玻璃弛豫后晶化激活能高于其淬态的晶化激活能,退火温度对大块金属玻璃热稳定性有显著影响.     

玻璃纤维和石墨增强PTFE复合材料的力学性能

通过机械混合、冷压和烧结成型制备了不同质量分数(5%～30%)的玻纤和石墨填充聚四氟乙烯(PTFE)复合材料.测试了不同样品的拉伸、冲击和硬度等力学性能,利用扫描电镜对冲击断面形貌进行观察.结果表明:加入玻纤后,拉伸强度、断裂伸长率和冲击强度迅速下降,弹性模量增加,材料呈脆性;材料硬度随玻纤加入量增加而增加,随软质石墨的加入量增加而减小;玻纤改性处理,会提高复合材料硬度;石墨对材料冲击韧性影响较小,少量加入时对拉伸强度影响也较小;质量分数10%的石墨和20%的玻纤填充增强PTFE复合材料的综合力学性能较好.     

Microstructure and mechanical properties of a novel Zr-based bulk metallic glass composite

Zr48.5Cu46.5Al5 bulk metallic glass （BMG） composites with diameters of 3 and 4 mm were prepared through suction casting in an arc melting furnace by modulating the alloy composition around the monothetic BMG composition of the high glass forming ability. Microstructural characterization reveals that the composites contain micron-sized CuZr phase with martensite structure, as well as nano-sized Zr2Cu crystalline particles and Cu10Zr7 plate-like phase embedded in an amorphous matrix. Room temperature compression tests showed that the composites exhibited significant strain hardening and obvious plastic strain of 7.7% for 3 mm and 6.4% for 4 mm diameter samples, respectively.     

Macro-micro dynamic behaviors and fracture modes of roll bonded 7A52/ 7A01/7B52 aluminum laminates in high velocity deformation

Damage tolerance improvement in the lamination of aluminum alloy plates and composites has been reported in many studies. In the present study the macro-micro dynamic deformation behavior and related mechanisms of 7A52/7A01/7B52 laminated plates processed by hot roll bonding of 7A52, 7A01 and 7B52 plate at high strain rates and quasi-static compression has been investigated. The microstructure of the laminated plates was examined with backscatter diffraction (EBSD) techniques, scanning and transmission electron microscopies. The results showed that with increased strain rate, obvious strain rate hardening was observed in the single layer specimens. The peak flow stress of the multilayer samples was slightly higher than that of the 7A52 monolayer samples and much lower than that of the 7B52 monolayer samples at the same strain rate. Beyond the peak stress state, the strain hardening was replaced by thermal softening in the 7A52 layer, leading to low resistance of deformation and high tendency to facilitate deformation-induced adiabatic shear bands (ASBs) that consist of dynamic recrystallized grains. ASBs in laminated samples were deflected and bifurcated at the interface of 7A52 layer. In addition, bifurcated ASBs converged at the interface between the 7A52 and 7A01 layers. The high deformation resistance observed in the laminate under dynamic loading was a consequence of the high capacity for strain hardening in the 7A01 layer. This hardening effectively overcame the influences of thermal softening and dynamic recovery during dynamic loading. This study provides an understanding of the laminate's microstructure evolution during dynamic deformation and its relevance to the fracture modes of a multilayer structure under dynamic loading.     

悬浮熔炼-铜模吸铸法制备Cu50Zr42Al8块状金属玻璃

采用悬浮熔炼-铜模吸铸法制备了Cu基块状金属玻璃,对直径5.0 mm的Cu50Zr42Al8三元合金圆棒利用X射线衍射(XRD)和差示扫描量热法(DSC)对合金的结构和热稳定性进行了测定.实验结果表明,该合金圆棒的组织为明显的非晶相,玻璃转变温度Tg、晶化温度Tx的值分别为730 K与778 K,过冷液相区宽度ΔT值为48 K,临界冷却速度Rc为25.5 K/s,表明该合金具有较强的玻璃形成能力,悬浮熔炼-铜模吸铸法是一种适合于制备块状金属玻璃的方法.     

Nb元素对Cu48Zr48Al4合金组织与性能的影响

以高纯铜锆金属母材为原料,采用铜模滴注的方法制备Cu Zr基非晶合金及其复合材料,并进行拉伸实验。利用扫描电镜、X射线衍射仪和扫描量热分析仪对Cu48Zr48Al4和Cu44.8Zr48Al4Nb3.2合金进行结构表征和拉伸性能分析。结果表明:Nb元素微量添加能够改变Cu48Zr48Al4合金的组织形貌。Cu48Zr48Al4合金为非晶复合材料,抗拉强度较小、塑性微弱,断口呈现树枝脉络;Cu44.8Zr48Al4Nb3.2为非晶合金,具有较大的抗拉强度,没有塑性,断口为单一的塑坑形貌;两种合金断口表面均存在熔化现象,样品侧表面形成较少的剪切带。该研究为实际生产Cu Zr Al Nb非晶复合材料提供了基础数据。     

Effect of Sn addition on the glass-forming ability and mechanical properties of Ni-Nb-Zr bulk metallic glasses

The effect of tin (Sn) addition on the glass forming ability (GFA) and mechanical properties of the Ni-Nb-Zr ternary alloy system has been studied. The addition of Sn improves the GFA; Ni61Nb35.5-xZr3.5Snx (in at.%) alloys with x=1 can be cast into amorphous samples at least 3 mm in diameter using a copper mold injection-casting method. The critical size for glass formation decreases to 2 mm when x=5 because Ni2SnZr phase precipitates readily. The addition of Sn is also effective in enhancing the stability ...     

Martensitic transfor mation involved mechanical behaviors and wide hysteresis of NiTiNb shape memory alloys

On the basis of thermoelastic martensitic transformation involved,the mechanical behaviors of NiTiNb shape memory alloys were experimentally studied and their wide hysteresis effect was theoretically d...     

深冷处理对Cu40Zr44Ag8Al8非晶复合材料组织和力学性能的影响

研究了深冷处理对Cu40Zr44Ag8Al8非晶复合材料组织演变和力学性能的影响.运用光学金相、X射线衍射分析（XRD）、差示扫描量热分析（DSC）和显微硬度等实验手段,对Cu40Zr44Ag8Al8非晶复合材料深冷处理前后的非晶结构和晶化相进行测试分析.结果表明：深冷处理2h,Cu40Zr44Ag8Al8非晶复合材料的第二相体积份数增多.随着深冷处理时间增加到24h,第二相的体积份数和尺寸进一步增多,同时非晶复合材料的显微硬度也有一定的提高.XRD分析表明Cu40Zr44Ag8Al8非晶复合材料中形成了Cu10Zr7相和AgZr相.非晶复合材料非晶基体的玻璃转变温度Tg随着深冷处理时间的增加而提高,晶化潜热则随着深冷时间的增加而降低.Cu40Zr44Ag8Al8非晶复合材料组织结构的演变与深冷处理过程产生的内应力有关.     

球形波冲击压缩后Zr41Ti14Cu12.5Ni10Be22.5大块金属玻璃的损伤与断裂特性研究

研究了Zr41Ti14Cu12.5Ni10Be22．5大块金属玻璃在不同速度的球形弹丸高速撞击下的损伤与断裂特性。通过表面形貌、X射线衍射谱的变化情况，可以看出．随着弹丸速度的增加，弹坑变成球形，弹坑深度逐渐增大，剪切带／裂纹有轻微增大，弧形损伤带是球面波高速撞击后的独特损伤行为。球形弹丸高速撞击作用下大块金属玻璃的晶化和常温退火与静高压下非晶态合金的晶化有着不同的机制。     

Cu_(60)Zr_(29)Ti_(11)大块非晶合金的黏度特征和强液体行为

采用铜模铸造法制备了Cu60Zr29Ti11大块非晶合金,用X射线衍射仪、三点压弯式黏度仪对该非晶合金的动力学性质进行了研究.测定了大块非晶合金Cu60Zr29Ti11在过冷液相区的黏度,得到了它的动力学脆性系数m=31,以及流变激活能E=63.4kJ/mol.表明大块非晶合金Cu60Zr29Ti11是一种强液体,有较强的非晶形成能力,形成非晶比较稳定.分析了合金在过冷态的流变激活能变化规律,发现流变激活能的变化并不符合Kivelson的Super-Arrhenius公式.     

Mechanical and thermal properties of AA7075/TiO2/Fly ash hybrid composites obtained by hot forging

In the present paper, multiple reinforcements TiO2 and fly ash were utilized for the fabrication of AA7075 matrix based hybrid composites using stir casting technique followed by hot forging. In hybrid composites, the fly ash content was fixed to 3 wt% while that of TiO2 was varied from 2.5 to 10 wt%. Scanning electron microscopy images revealed homogenous dispersion of both the reinforcements in AA7075 matrix.Compression test was conducted to study the mechanical behaviour of hybrid composites. The hybrid composites showed increase in compressive strength with the incorporation of multiple reinforcements and further increased with the increase in the weight fractions of TiO2 particles. The coefficient of thermal expansion was measured between 50 and 250 ℃ with a high precision thermal mechanical analyser. The thermal coefficient of hybrid composites decreased with the addition of TiO2 and fly ash. However a slight decrease in thermal conductivity of hybrid composites was observed when compared to that of AA7075 alloy.