分光光度法测定钒酸钇晶体原料中的含钇量

在不同pH值下 ,通过液相法合成了钒酸钇晶体原料 .采用分光光度法测定了上述合成原料中的含钇量 .实验结果表明 ,pH =7.0时为原料合成的最佳酸碱度 ,原料中的含钇量可达 99.39% ,与理论值接近 .可作为优质YVO4 光学晶体的生长原料     

两种格兰型钒酸钇棱镜透射比的温度效应

为了研究温度对两种钒酸钇棱镜透射比的影响,采用理论计算与分析的方法,并通过实验验证,进行数据对比。结果表明:理论值与实验值符合,钒酸钇棱镜的温度稳定性好,温度对格兰.付科型钒酸钇棱镜的透射比比格兰.汤姆逊型钒酸钇棱镜透射比影响更小,这为钒酸钇棱镜在工程实验中的应用提供了重要的参考价值。     

Na3Sc2V3O12∶Fe3 ＋掺杂体系微观结构的理论研究

基于三角对称下3d5组态体系的完全能量矩阵,通过理论模拟实验的EPR参量,运用2个不同的参数值A4（这2个参数分别来自赤铁矿和钇铁石榴石的光谱）,研究了Na3Sc2V3O12石榴石晶体中的四面体三价铁中心的光谱和局域微观结构。计算结果与已有的实验值相吻合。     

用L—S藕合的蒙特—卡罗模型模拟复杂光谱

阐述了L—S耦合情况下的Monte—Carlo理论模型．在局域热动平衡条件下，用Monte—Carlo模型模拟Hf等离子体复杂光谱的部分光谱：类钇铪的光谱，其主要方法是：由统计方法计算出类钇铪等离子体的4d^3—d^26p束缚束缚跃迁的跃迁阵的谱线数目，从高斯分布中随机确定每条谱线的能量。再根据L—S耦合时能量与强度的关系来确定每条谱线的强度，从而模拟未分辨跃迁阵Hf^33 4d^3—d^26p的光谱线。     

利用可调偏振干涉滤波器监视DWDM系统光源波长变化

提出利用钒酸钇晶体偏振干涉滤波器对密集波分复用光通讯系统信道光源 (分布反馈激光器 )的波长漂移进行监视 .由于通过改变钒酸钇晶体的温度可以移动滤波器透射谱的峰值位置 ,因此该方法可以实现无盲区波长监视 .在实验中 ,保持滤波器的光强透过率不变 ,通过测量相应的滤波器温度改变 ,取得了 0 .0 2nm的波长监视精度 .     

H03+:Ba0.8Sr0.2Ti03纳米粉体的光谱性质研究

采用溶胶-凝胶法制备Ho3+:Ba0.8Sr0.2TiO3 (BST)纳米粉体.根据Judd-Ofelt理论对纳米粉体的吸收光谱进行拟合,得到晶体场强度参数Ω2、Ω4和Ω6分别为0.229×10-20、0.515×10-20和0.761×10-20cm2,并系统计算Ho3+各能级跃迁的振子强度、自发辐射跃迁几率、荧光分...     

钒酸钇原料制备

采用液相反应法合成钒酸钇原料 .为了寻求最佳合成点 ,测定了氧化钇 (Y2 O3)和偏钒酸铵 (NH4 VO3)在硝酸和氨水中的溶解度 -浓度曲线 ;分析了温度对溶解度的影响 .钒酸钇粉末在 10 0℃的条件下烘干 ,5 0 0℃条件下烧结4 8h.XRD粉末衍射表明 ,所得物质为四方相钒酸钇     

掺钕钒酸钇薄片激光器中弛豫振荡的偏振动力学研究

提出用密度矩阵理论描述ｃ轴切割掺钕钒酸钇晶体的４Ｆ３／２→４Ｉ１１／２四能级激光发射的光学非均匀特性，建立了正交偏振激光模式所遵循的动力学方程组．数值解结果定性地解释了实验上所观察的掺钕钒酸钇薄片的１．０６μｍ双偏振激光的弛豫振荡的竞争行为．     

Tm3+在氟氧化物玻璃中的光谱性质

通过测量Tm掺杂氟氧化物玻璃的光吸收谱,根据Judd-Ofelt理论,拟合得到了Tm3+离子的J-O强度参量Ω2=1.955×10-20 cm2,Ω4=2.629×10-20 cm2,Ω6=1.279×10-20 cm2.利用强度参量,给出氟氧化物玻璃中Tm3+离子各激发能级的自发辐射跃迁速率、辐射寿命、荧光分支比和积分发射截面等光谱参量的预计值,发现许多跃迁振子强度大于10-6且积分发射截面大于10-18cm,如(3F,3H)4→3H6(1707nm)跃迁的振子强度、积分发射截面分别为3.593×10-6,3.180×10-18cm,若上能级有足够高的量子效率,可能实现激光发射.而蓝光波段1G4→3H6(466nm)跃迁也有较大的振子强度(1.112×10-6)和积分发射截面值(0.984×10-18cm).     

光电子能谱在钒酸钇晶体生长中的应用

应用光电子能谱分析了钒酸钇（YVO4）多晶斜与单晶之间的关系，成功生长出低缺陷的YVO4晶体，并对晶体进行检测。由检测结果得出，YVO4晶体的小角晶界，散射中心等缺陷与多晶斜的Y,V质量比有密切的关系，晶体的外形变形、与晶体温度场关系较大。     

Markedness and its Interpretation in Language Use

Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.     

Features of Women's language

Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women＇s language from these perspectives： pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women＇s language, more attention should be paid to language use in social context. What＇s more, the linguistic phenomena in a speaking community can be understood more thoroughly.     

An Analysis of Catherine＇s Character——Wuthering Heights

Wuthering Heights, Emily Bronte＇s only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.     

Lower Paleozoic oil relationships within Williston Basin, Canada

The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.     

低渗透非均质砂岩油藏启动压力梯度研究

理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。     

On Tragic Consciousness In The Works By Ernest Hemingway

As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.     

Achieving Unusual States of Matter Under High Pressure

正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-     

Exchange-Correlation and Electronic Excitation Energies from Pairing Matrix Fluctuations

We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-     

Density Functional Theory for the Response of Periodic Systems to Electric Fields Based on the Vector Potential Approach

正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that     

On the Thermodynamic Limit for Responses to Static Electromagnetic Fields

For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the