Physical aspects of biophotons

Summary By comparing the theoretically expected results of photon emission from a chaotic (thermal) field and those of an ordered (fully coherent) field with the actual experimental data, one finds ample indications for the hypothesis that biophotons originate from a coherent field occurring within living tissues. A direct proof may be seen in the hyperbolic relaxation dynamics of spectral delayed luminescence under ergodic conditions.A possible mechanism has to be founded on Einstein's balance equation and, under stationary conditions, on energy conservation including a photochemical potential. It is shown that the considered equations deliver, besides the thermal equilibrium, a conditionally stable region far away from equilibrium, which can help to describe both biophoton emission and biological regulation.     

Proving the principle: Taking geodesic dynamics too seriously in Einstein's theory

In this paper I critically review attempts to formulate and derive the geodesic principle, which claims that free massive bodies follow geodesic paths in general relativity theory. I argue that if the principle is (canonically) interpreted as a law of motion describing the actual evolution of gravitating bodies, then it is impossible to generically apply the law to massive bodies in a way that is coherent with Einstein's field equations. Rejecting the canonical interpretation, I propose an alternative interpretation of the geodesic principle as a type of universality thesis analogous to the universality behavior exhibited in thermal systems during phase transitions.     

Luminescence research and its relation to ultraweak cell radiation

The fundamental laws of photochemistry and the essential results of experimental research on ultraweak cell radiation are presented. By comparing all the facts it can be concluded that the phenomena discussed may arise from a variety of possible reactions and sources. Recombination reactions of certain radicals actually do release sufficient energy to generate UV-photons of the intensity under consideration. On the other hand, stimulated emission cannot be excluded in view of the distinct deviation of the radiation field from thermal equilibrium. There exist, however, various other candidates, such as direct emitters like flavins, indoles, porphyrins, carbonyl derivatives and aromatic compounds, and molecular oxygen and its various species, as well as collective molecular interactions, e.g. dimole or exciplex transitions, triplet-triplet annihilation, collective hydrolysis, electric field effects in membranes, etc. Careful biochemical and biophysical experiments are still necessary to find answers to all the questions that remain; not only individual problems have to be solved, but it is important to keep in mind the interrelationships between certain reactions.     

Luminescence research and its relation to ultraweak cell radiation

Summary The fundamental laws of photochemistry and the essential results of experimental research on ultraweak cell radiation are presented. By comparing all the facts it can be concluded that the phenomena discussed may arise from a variety of possible reactions and sources. Recombination reactions of certain radicals actually do release sufficient energy to generate UV-photons of the intensity under consideration. On the other hand, stimulated emission cannot be excluded in view of the distinct deviation of the radiation field from thermal equilibrium. There exist, however, various other candidates, such as direct emitters like flavins, indoles, porphyrins, carbonyl derivatives and aromatic compounds, and molecular oxygen and its various species, as well as collective molecular interactions, e.g. dimole or exciplex transitions, triplet-triplet annihilation, collective hydrolysis, electric field effects in membranes, etc.Careful biochemical and biophysical experiments are still necessary to find answers to all the questions that remain; not only individual problems have to be solved, but it is important to keep in mind the interrelationships between certain reactions.     

Reconceptualising equilibrium in Boltzmannian statistical mechanics and characterising its existence

In Boltzmannian statistical mechanics macro-states supervene on micro-states. This leads to a partitioning of the state space of a system into regions of macroscopically indistinguishable micro-states. The largest of these regions is singled out as the equilibrium region of the system. What justifies this association? We review currently available answers to this question and find them wanting both for conceptual and for technical reasons. We propose a new conception of equilibrium and prove a mathematical theorem which establishes in full generality – i.e. without making any assumptions about the system׳s dynamics or the nature of the interactions between its components – that the equilibrium macro-region is the largest macro-region. We then turn to the question of the approach to equilibrium, of which there exists no satisfactory general answer so far. In our account, this question is replaced by the question when an equilibrium state exists. We prove another – again fully general – theorem providing necessary and sufficient conditions for the existence of an equilibrium state. This theorem changes the way in which the question of the approach to equilibrium should be discussed: rather than launching a search for a crucial factor (such as ergodicity or typicality), the focus should be on finding triplets of macro-variables, dynamical conditions, and effective state spaces that satisfy the conditions of the theorem.     

A probabilistic foundation of elementary particle statistics. Part I

The long history of ergodic and quasi-ergodic hypotheses provides the best example of the attempt to supply non-probabilistic justifications for the use of statistical mechanics in describing mechanical systems. In this paper we reverse the terms of the problem. We aim to show that accepting a probabilistic foundation of elementary particle statistics dispenses with the need to resort to ambiguous non-probabilistic notions like that of (in)distinguishability. In the quantum case, starting from suitable probability conditions, it is possible to deduce elementary particle statistics in a unified way. Following our approach Maxwell-Boltzmann statistics can also be deduced, and this deduction clarifies its status.Thus our primary aim in this paper is to give a mathematically rigorous deduction of the probability of a state with given energy for a perfect gas in statistical equilibrium; that is, a deduction of the equilibrium distribution for a perfect gas. A crucial step in this deduction is the statement of a unified statistical theory based on clearly formulated probability conditions from which the particle statistics follows. We believe that such a deduction represents an important improvement in elementary particle statistics, and a step towards a probabilistic foundation of statistical mechanics.In this Part I we first present some history: we recall some results of Boltzmann and Brillouin that go in the direction we will follow. Then we present a number of probability results we shall use in Part II. Finally, we state a notion of entropy referring to probability distributions, and give a natural solution to Gibbs' paradox.     

Local Fluctuations and Local Observers in Equilibrium Statistical Mechanics

The distribution function associated with a classical gas at equilibrium is considered. We prove that apart from a factorisable multiplier, the distribution function is fully determined by the correlations among local momenta fluctuations. Using this result we discuss the conditions which enable idealised local observers, who are immersed in the gas and form a part of it, to determine the distribution ‘from within’. This analysis sheds light on two views on thermodynamic equilibrium, the ‘ergodic’ and the ‘thermodynamic limit’ schools, and the relations between them. It also provides an outline for a new definition of equilibrium that is weaker than full ergodicity. Finally, we briefly discuss the possibility that the distribution can be determined by external observers.     

Effective Field Theories,Reductionism and Scientific Explanation

Effective field theories have been a very popular tool in quantum physics for almost two decades. And there are good reasons for this. I will argue that effective field theories share many of the advantages of both fundamental theories and phenomenological models, while avoiding their respective shortcomings. They are, for example, flexible enough to cover a wide range of phenomena, and concrete enough to provide a detailed story of the specific mechanisms at work at a given energy scale. So will all of physics eventually converge on effective field theories? This paper argues that good scientific research can be characterised by a fruitful interaction between fundamental theories, phenomenological models and effective field theories. All of them have their appropriate functions in the research process, and all of them are indispensable. They complement each other and hang together in a coherent way which I shall characterise in some detail. To illustrate all this I will present a case study from nuclear and particle physics. The resulting view about scientific theorising is inherently pluralistic, and has implications for the debates about reductionism and scientific explanation.     

Microbial energetics applied to waste repositories

Summary Through their catalytic abilities microbes can increase rates of chemical reactions which would take a very long time to reach equilibrium under abiotic conditions. Microbes also alter the concentration and composition of chemicals in the environment, thereby creating new conditions for further biological and chemical reactions. Rates of degradation and possible indirect consequences on leaching rates in waste repositories are a function of the presence or absence of microbes and of the conditions which allow them to become catalytically active.Microbially mediated reactions are no exception to the rule that all chemical processes are basically governed by thermodynamic laws. Naturally occurring processes proceed in the direction that leads to the minimal potential energy level attained when equilibrium is reached. A continuous supply of energy to an ecosystem in the form of biochemically unstable compounds maintains non-equilibrium conditions, a prerequisite for all chemotrophic life. Energy is released as a chemical reaction progresses towards equilibrium. Microbes scavenge that portion of the free energy of reaction (G_r) which can be converted into biochemically usable forms during the chemical oxidation processes. As electrontransfer catalysts, the microorganisms mediate reactions which are thermodynamically possible thereby stimulating reaction rates. Decomposition and mineralization in systems without a continuous supply of substrates and oxidants will lead to equilibria with minimal free energy levels at which point further microbial action would cease. The differences in the free energy levels of reactions (G_r), represent the maximal energy which is available to microorganisms for maintenance and growth. How much of the released free energy will be conserved in energy-rich bonds, compounds (e.g. ATP), and chemical potentials (e.g. emf) useful for biosynthesis and biological work is characteristic for the microbes involved and the processes and metabolic routes employed.Materials whose elements are not present in the most oxidized form attainable in the oxic environment of our planet are potentially reactive. Microbial activities are associated only with chemical reactions whose free energy changes are exergonic. This should be kept in mind for all investigations related to the role of microbes in repositories or in the layout of proper waste storage conditions. Rigorous application of thermodynamic concepts to environmental microbiology allows one to develop models and design experiments which are often difficult to conceive of in complex natural systems from physiological information alone. Thermodynamic considerations also aid in selecting proper deposition conditions and in carrying out thoughtful experiments in areas related to microbial ecology of waste repositories.     

Ergodic Theory, Interpretations of Probability and the Foundations of Statistical Mechanics

The traditional use of ergodic theory in the foundations of equilibrium statistical mechanics is that it provides a link between thermodynamic observables and microcanonical probabilities. First of all, the ergodic theorem demonstrates the equality of microcanonical phase averages and infinite time averages (albeit for a special class of systems, and up to a measure zero set of exceptions). Secondly, one argues that actual measurements of thermodynamic quantities yield time averaged quantities, since measurements take a long time. The combination of these two points is held to be an explanation why calculating microcanonical phase averages is a successful algorithm for predicting the values of thermodynamic observables. It is also well known that this account is problematic.This survey intends to show that ergodic theory nevertheless may have important roles to play, and it explores three other uses of ergodic theory. Particular attention is paid, firstly, to the relevance of specific interpretations of probability, and secondly, to the way in which the concern with systems in thermal equilibrium is translated into probabilistic language. With respect to the latter point, it is argued that equilibrium should not be represented as a stationary probability distribution as is standardly done; instead, a weaker definition is presented.     

A comment on the estimation of times required for the attainment of equilibrium by noncooperative,single site ligand-receptor systems

Summary A table presents the number of hours required for binding to reach 80% and 95% of the equilibrium value for a noncooperative, single site ligand binding system. A 2nd table provides the fraction of binding sites occupied and the fraction of the total ligand bound at equilibrium under the same conditions.     

大型商用厨房室内热舒适性的数值分析

大型商用厨房是一个复杂的高温高湿环境。在夏季若未采用有效的室外新风补给措施,则需要给厨房提供大量空调冷风以满足排烟需求,造成大量的能耗。本文提出一种大型中餐厨房布局,并基于分析软件FLUENT进行数值模拟,采用PMV-PPD预测模型对4种不同比例的送风情况进行热舒适性评价。结果表明,对于这种厨房布局,采用20%冷风比例的组合气幕通风方式,不仅能防止污染物逸出、降低厨房所需空调冷风风量,减少能耗,同时可获得满意的热舒适性环境。     

Quantum gravity: Meaning and measurement

A discussion of the meaning of a physical concept cannot be separated from discussion of the conditions for its ideal measurement. We assert that quantization is no more than the invocation of the quantum of action in the explanation of some process or phenomenon, and does not imply an assertion of the fundamental nature of such a process. This leads to an ecumenical approach to the problem of quantization of the gravitational field. There can be many valid approaches, each of which should be judged by the domain of its applicability to various phenomena. If two approaches have overlapping domains, the relation between them then itself becomes a subject of study. We advocate an approach to general relativity based on the unimodular group, which emphasizes the physical significance and measurability of the conformal and projective structures. A discussion of the method of matched asymptotic expansions, and of the weakness of terrestrial sources compared with astrophysical and cosmological sources, leads us to suggest theoretical studies of gravitational radiation based on retrodiction (observation) rather than prediction (experimentation).     

Heat balance modelling

The only way to describe the effects of the thermal environment on the human body completely is to do it by means of an energy balance equation. In such an equation all relevant meteorological parameters, behavioral characteristics (activity and clothing) and body measurements can be considered. Using Fanger's comfort equation and the models MEMI and IMEM as examples, the problems of energy balancing and ways of solving them are described. The value of energy balance models is documented by examples from the field of application.     

Biologie et thermodynamique des phénomènes irréversibles

Summary The thermodynamic study of systems in which stationary (non equilibrium) states were possible, led one of us (I. P.) to a number of general conclusions. In the present paper these conclusions are summarized and briefly discussed from a biological standpoint. It appears that the evolution of such systems is towards states with the least production of entropy (per mass unit) compatible with the conditions imposed. In the case of living matter this corresponds approximately to states of minimum metabolism. During this evolution the entropy contained in the system may decrease whilst the heterogenity increases. But this increase in heterogenity can only take place when there is a decrease in the entropy production, that is an evolution of the metabolism. We are thus led to suggest a physicochemical interpretation of Lamarchism. Finally we call attention to the fact that the moderation principle ofLe Chatelier-Braun is not limited to equilibrium states.     

Ten reasons why a thermalized system cannot be described by a many-particle wave function

It is widely believed that the underlying reality behind statistical mechanics is a deterministic and unitary time evolution of a many-particle wave function, even though this is in conflict with the irreversible, stochastic nature of statistical mechanics. The usual attempts to resolve this conflict for instance by appealing to decoherence or eigenstate thermalization are riddled with problems. This paper considers theoretical physics of thermalized systems as it is done in practice and shows that all approaches to thermalized systems presuppose in some form limits to linear superposition and deterministic time evolution. These considerations include, among others, the classical limit, extensivity, the concepts of entropy and equilibrium, and symmetry breaking in phase transitions and quantum measurement. As a conclusion, the paper suggests that the irreversibility and stochasticity of statistical mechanics should be taken as a real property of nature. It follows that a gas of a macroscopic number N of atoms in thermal equilibrium is best represented by a collection of N wave packets of a size of the order of the thermal de Broglie wave length, which behave quantum mechanically below this scale but classically sufficiently far beyond this scale. In particular, these wave packets must localize again after scattering events, which requires stochasticity and indicates a connection to the measurement process.     

The non-relativistic limits of the Maxwell and Dirac equations: the role of Galilean and gauge invariance

The aim of this paper is to illustrate four properties of the non-relativistic limits of relativistic theories: (a) that a massless relativistic field may have a meaningful non-relativistic limit, (b) that a relativistic field may have more than one non-relativistic limit, (c) that coupled relativistic systems may be “more relativistic” than their uncoupled counterparts, and (d) that the properties of the non-relativistic limit of a dynamical equation may differ from those obtained when the limiting equation is based directly on exact Galilean kinematics. These properties are demonstrated through an examination of the non-relativistic limit of the familiar equations of first-quantized QED, i.e., the Dirac and Maxwell equations. The conditions under which each set of equations admits non-relativistic limits are given, particular attention being given to a gauge-invariant formulation of the limiting process especially as it applies to the electromagnetic potentials. The difference between the properties of a limiting theory and an exactly Galilean covariant theory based on the same dynamical equation is demonstrated by examination of the Pauli equation.     

双块式无砟轨道温度场试验研究和数值分析

为较准确掌握无砟轨道温度场的分布规律,建立无砟轨道温度与环境温度的对应关系,为温度应力的计算和无砟轨道设计提供基础参数,本文测试了双块式无砟轨道不同部件、不同位置的温度和环境温度变化情况,建立有限元模型对无砟轨道温度场进行了数值模拟和对比.实测数据及数值模拟的结果均表明:道床板温度随外界气温呈以日为周期的周期性变化,秋季平均每天的升温时间约为8 h,降温约16 h;由于热交换条件的差异,距轨道表面越远,轨道温度受环境气温的影响越小,道床板角部的温度变化幅度大于中部,支撑层与基床表层的温度变化幅度很小;道床板内存在较大的温度梯度,随着距表面距离的增大,温度梯度逐渐减小,至支撑层时温度梯度可忽略不计;采用有限元模拟的方法获取无砟轨道温度随气温变化规律是可行的.     

Costs and benefits of mycorrhizas: Implications for functioning under natural conditions

Summary It is paradoxical that most plants under natural conditions are infected with vesicular-arbuscular mycorrhizal fungi, yet that it is often difficult to demonstrate that infected plants receive any benefit from the association. The costs and benefits of infection are analysed and a hypothesis formulated that infection only yields benefits at times during the life cycle when P demand by the plant exceeds the capacity of the root system. A simulation model is described that suggests that infection density should be more or less constant below a threshold value of root P uptake rate, but that above this value roots should be non-mycorrhizal. More extensive study of mycorrhizas under field conditions is needed to test such predictions.     

The microbiology programme for UK Nirex

Summary The Nirex Safety Assessment Research Programme (NSARP) considers the effect of microbial action on the repository near field. The upper limit of growth for natural soil organisms appears to be pH 12.25. Environmental conditions in the repository will probably allow slow growth particularly on damp wastes. Experiments using packed columns of waste and concrete have shown that an extremely high pH is not conducive to rapid microbial growth. However, viable populations can exist within regions adjacent to the concrete, e.g. where a surface film coats the concrete. Carbon dioxide and methane will be produced by microbial action within the repository but actual rates of production will be lower than that in a domestic landfill. The cellulosic fraction of waste is the main determinant of cell growth. It appears to be the sugar acids arising from alkaline degradation of cellulose which cause enhanced plutonium solubility. The potentially beneficial reduction of chemically derived polyhydroxy acids by the microorganisms is possible. A mathematical model has been constructed to describe the main features of biological action in the repository.