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1.
《矿物冶金与材料学报》2021,28(12):2001-2007
Graphene oxide (GO) wrapped Fe3O4 nanoparticles (NPs) were prepared by coating the Fe3O4 NPs with a SiO2 layer, and then modifying by amino groups, which interact with the GO nanosheets to form covalent bonding. The SiO2 coating layer plays a key role in integrating the magnetic nanoparticles with the GO nanosheets. The effect of the amount of SiO2 on the morphology, structure, adsorption, and regenerability of the composites was studied in detail. An appropriate SiO2 layer can effectively induce the GO nanosheets to completely wrap the Fe3O4 NPs, forming a core-shell Fe3O4@SiO2@GO composite where Fe3O4@SiO2 NPs are firmly encapsulated by GO nanosheets. The optimized Fe3O4@SiO2@GO sample exhibits a high saturated adsorption capacity of 253 mg·g?1 Pb(II) cations from wastewater, and the adsorption process is well fitted by Langmuir adsorption model. Notably, the composite displays excellent regeneration, maintaining a ~90% adsorption capacity for five cycles, while other samples decrease their adsorption capacity rapidly. This work provides a theoretical guidance to improve the regeneration of the GO-based adsorbents.  相似文献   

2.
《矿物冶金与材料学报》2021,28(12):1908-1916
The effect of CaCO3, Na2CO3, and CaF2 on the reduction roasting and magnetic separation of high-phosphorus iron ore containing phosphorus in the form of Fe3PO7 and apatite was investigated. The results revealed that Na2CO3 had the most significant effect on iron recovery and dephosphorization, followed by CaCO3, the effect of CaF2 was negligible. The mechanisms of CaCO3, Na2CO3, and CaF2 were investigated using X-ray diffraction (XRD), scanning electron microscopy and energy dispersive spectrometry (SEM–EDS). Without additives, Fe3PO7 was reduced to elemental phosphorus and formed an iron–phosphorus alloy with metallic iron. The addition of CaCO3 reacted with Fe3PO7 to generate an enormous amount of Ca3(PO4)2 and promoted the reduction of iron oxides. However, the growth of iron particles was inhibited. With the addition of Na2CO3, the phosphorus in Fe3PO7 migrated to nepheline and Na2CO3 improved the reduction of iron oxides and growth of iron particles. Therefore, the recovery of iron and the separation of iron and phosphorus were the best. In contrast, CaF2 reacted with Fe3PO7 to form fine Ca3(PO4)2 particles scattered around the iron particles, making the separation of iron and phosphorus difficult.  相似文献   

3.
4.
Carbonated decomposition of hydrogarnet is one of the vital reactions of the calcification–carbonation method, which is designed to dispose of low-grade bauxite and Bayer red mud and is a novel eco-friendly method. In this study, the effect of the silica saturation coefficient (x) on the carbonation of hydrogarnet was investigated from the kinetic perspective. The results indicated that the carbonation of hydrogarnets with different x values (x = 0.27, 0.36, 0.70, and 0.73) underwent two stages with significantly different rates, and the kinetic mechanisms of the two stages can be described by the kinetic functions R3 and D3. The apparent activation energies at Stages 1 and 2 were 41.96–81.64 and 14.80–34.84 kJ/mol, respectively. Moreover, the corresponding limiting steps of the two stages were interfacial chemical reaction and diffusion.  相似文献   

5.
《矿物冶金与材料学报》2020,27(10):1347-1352
A new method of high-gravity combustion synthesis (HGCS) followed by post-treatment (PT) is reported for preparing high-performance high-entropy alloys (HEAs), Cr0.9FeNi2.5V0.2Al0.5 alloy, whereby cheap thermite powder is used as the raw material. In this process, the HEA melt and the ceramic melt are rapidly formed by a strong exothermic combustion synthesis reaction and completely separated under a high-gravity field. Then, the master alloy is obtained after cooling. Subsequently, the master alloy is sequentially subjected to conventional vacuum arc melting (VAM), homogenization treatment, cold rolling, and annealing treatment to realize a tensile strength, yield strength, and elongation of 1250 MPa, 1075 MPa, and 2.9%, respectively. The present method is increasingly attractive due to its low cost of raw materials and the intermediate product obtained without high-temperature heating. Based on the calculation of phase separation kinetics in the high-temperature melt, it is expected that the final alloys with high performance can be prepared directly across master alloys with higher high-gravity coefficients.  相似文献   

6.
We report the picosecond laser ablation of aluminum targets immersed in a polar organic liquid (chloroform, CHCl3) with ~2 ps laser pulses at an input energy of ~350 μJ. The synthesized aluminum nanoparticles exhibited a surface plasmon resonance peak at ~340 nm. Scanning electron microscopy images of Al nanoparticles demonstrated the spherical morphology with an average size of (27 ± 3.6) nm. The formation of smaller spherical Al nanoparticles and the diminished growth could be from the formation of electric double layers on the Al nanoparticles. In addition to spherical aluminum nanoparticles, triangular/pentagonal/hexagonal nanoparticles were also observed in the colloidal solution. Field emission scanning electron microscopy images of ablated Al targets demonstrated laser induced periodic surface structures (LIPSSs), which were the high spatial frequency LIPSSs (HSF-LIPSSs) since their grating period was ~280 nm. Additionally, coarse structures with a period of ~700 nm were observed.  相似文献   

7.
Computational simulations and high-temperature measurements of velocities near the surface of a mold were carried out by using the rod deflection method to study the effects of various operating parameters on the flow field in slab continuous casting (CC) molds with narrow widths for the production of automobile exposed panels. Reasonable agreement between the calculated results and measured subsurface velocities of liquid steel was obtained under different operating parameters of the CC process. The simulation results reveal that the flow field in the horizontal plane located 50 mm from the meniscus can be used as the characteristic flow field to optimize the flow field of molten steel in the mold. Increases in casting speed can increase the subsurface velocity of molten steel and shift the position of the vortex core downward in the downward circulation zone. The flow field of liquid steel in a 1040 mm-wide slab CC mold can be improved by an Ar gas flow rate of 7 L·min?1 and casting speed of 1.7 m·min?1. Under the present experimental conditions, the double-roll flow pattern is generally stable at a submerged entry nozzle immersion depth of 170 mm.  相似文献   

8.
Electroslag remelting (ESR) gives a combination of liquid metal refining and solidification structure control. One of the typical aspects of liquid metal refining during ESR for the advanced steel and alloy production is desulfurization. It involves two patterns, i.e., slag–metal reaction and gas–slag reaction (gasifying desulfurization). In this paper, the advances in desulfurization practices of ESR are reviewed. The effects of processing parameters, including the initial sulfur level of consumable electrode, remelting atmosphere, deoxidation schemes of ESR, slag composition, melting rate, and electrical parameters on the desulfurization in ESR are assessed. The interrelation between desulfurization and sulfide inclusion evolution during ESR is discussed, and advancements in the production of sulfur-bearing steel at a high-sulfur level during ESR are described. The remaining challenges for future work are also proposed.  相似文献   

9.
The mineral transition and formation mechanism of calcium aluminate compounds in CaO?Al2O3?Na2O system during the high-temperature sintering process were systematically investigated using DSC?TG, XRD, SEM?EDS, FTIR, and Raman spectra, and the crystal structure of Na4Ca3(AlO2)10 was also simulated by Material Studio software. The results indicated that the minerals formed during the sintering process included Na4Ca3(AlO2)10, CaO·Al2O3, and 12CaO·7Al2O3, and the content of Na4Ca3(AlO2)10 could reach 92wt% when sintered at 1200°C for 30 min. The main formation stage of Na4Ca3(AlO2)10 occurred at temperatures from 970 to 1100°C, and the content could reach 82wt% when the reaction temperature increased to 1100°C. The crystal system of Na4Ca3(AlO2)10 was tetragonal, and the cells preferred to grow along crystal planes (110) and (210). The formation of Na4Ca3(AlO2)10 was an exothermic reaction that followed a secondary reaction model, and its activation energy was 223.97 kJ/mol.  相似文献   

10.
Ore particles, especially fine interlayers, commonly segregate in heap stacking, leading to undesirable flow paths and changeable flow velocity fields of packed beds. Computed tomography (CT), COMSOL Multiphysics, and MATLAB were utilized to quantify pore structures and visualize flow behavior inside packed beds with segregated fine interlayers. The formation of fine interlayers was accompanied with the segregation of particles in packed beds. Fine particles reached the upper position of the packed beds during stacking. CT revealed that the average porosity of fine interlayers (24.21%) was significantly lower than that of the heap packed by coarse ores (37.42%), which directly affected the formation of flow paths. Specifically, the potential flow paths in the internal regions of fine interlayers were undeveloped. Fluid flowed and bypassed the fine interlayers and along the sides of the packed beds. Flow velocity also indicated that the flow paths easily gathered in the pore throat where flow velocity (1.8 × 10?5 m/s) suddenly increased. Fluid stagnant regions with a flow velocity lower than 0.2 × 10?5 m/s appeared in flow paths with a large diameter.  相似文献   

11.
文章在分析宁武县产业结构现状的基础上,提出其产业结构调整与生态旅游特色县建设的重点与对策。  相似文献   

12.
建设龙头企业特色县,是我省加快发展县域经济和乡镇企业的可持续发展战略。本文对如何使县域经济和乡镇企业快速发展,科技工作如何为其发展提供强有力的服务进行了论述,提出了龙头企业特色县建设中急需解决的问题及对策。  相似文献   

13.
甘肃天祝县夏玛林区的蝶类   总被引:19,自引:1,他引:18  
记述天祝县夏玛林区的蝶类36种,隶属于6科21属,其中4科5种为甘肃省新记录。  相似文献   

14.
金寨县地处皖西和大别山区,莲花山位于金寨县境的中部偏东。莲花山过去由于交通不便,信息闭塞,经济文化发展相对滞后,客观上较好地保留了当地独特的风俗习惯和方言特色。莲花山方言特别令人感兴趣的是其方俗词语中留存了一定数量的古代汉语词汇,这些方俗词语作为活的方言材料,具有多方面的语料价值和研究价值。本文选取其中的26条词语,进行考察和例释。  相似文献   

15.
16.
西安户县非公有制经济发展简论   总被引:1,自引:0,他引:1  
非公有制经济是我国社会主义市场经济的重要组成部分,我们应坚持公有制为入体,多种所有制经济共同发展的社会主义基本经济体制。  相似文献   

17.
介绍江西省井冈山市砻市镇方言的声韵调、音韵特点和同音字汇。  相似文献   

18.
桂平市城镇体系中心局面单一,未能形成不同层次的体系,城镇数量多、密度大,各镇职能类似,基础设施薄弱,工业化进程缓慢;城镇积聚能力差,水平低,。桂平市城镇化发展应强调,优行发展城区,以城区为核心,次一级中心城镇为纽带,一般城镇为基础,逐步建立规模适度、布局合理、整体功能完备的城镇体系。  相似文献   

19.
刘爱荣 《太原科技》2011,(1):102-103,106
山西省代县峪口西曲网沟铁矿为一小型铁矿床,具有埋藏浅,易采、易选,矿石品位为中等稳定品位,水文地质条件简单,开采技术条件可行等特点。对峪口西曲网沟铁矿的地质特征、成矿条件进行了分析研究,为该区矿山开采具有重要的指导意义。  相似文献   

20.
李蕃一生命运多舛。他幼失母爱,壮年流离,老年获任山东黄县知县,却遭人构陷落职,最后归乡养老。李蕃的遭遇既有时代转承带来的变故,也有家庭变故带来的不幸,还有的则是他的性格与当下官场生态冲突的必然结果。难能可贵的是,在经历各种曲折后,他仍能坚持自己的人生理想与价值追求,即以自己之力为百姓谋利。  相似文献   

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