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Synthesis,thermal decomposition and crystal structure of copper (Ⅱ)α,β-unsaturated carboxylate with urea 总被引:1,自引:1,他引:0
A detailed synthesis is described for binuclear cage ternary complexes Cu2A4 [(NH2)2CO]2, where A = CH2 =CH-COO and CH2 =C(CH3)-COO- . Elemental analysis and thermal analysis have been investigated. The molecular structure of Cu2 (CH2 = CH-COO)4[(NH2)2CO]2 was determined by single crystal X-ray diffraction. The material forms blue crystal with tetragronal symmetry, space group P42/n, a = b = 1.239 35(6) nm, c = 1.398 05 (16) nm, Z = 4. There exists a magnetic exchange interaction between the two paramagnetic Cu atoms. The Cu-Cu bond length is 0.260 94 nm. 相似文献
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Lu Ping Liu Bin Zhang Zhe Wu Feng Deng Nan-sheng . College of Resource Environmental Science Wuhan University Wuhan Hubei China . School of Chemistry Environmental Engineering Jianghan University Wuhan Hubei China . Department of Environmental Chemical Engineering Huangshi Polytechnic College Huangshi Hubei China 《武汉大学学报:自然科学英文版》2003,(4)
0 IntroductionCyclodextrins (CD)arenon reducingcyclicmaltooligosaccharidesproducedfromstarchbycyclodextringlycosyltransferaseandarecom posedofahydrophilicoutersurfaceandahy drophobicinnercavity .β cyclodextrinsarecom posedofsevenD glucopyranoseunits.Theringshapedstructureandhydrophobicinnercavityal lowthemtohousevariousguestmoleculesandtoformhost/ guestinclusioncomplexes.Cyclodex trinswereusedtoforminclusioncomplexwithdrugstoincreasewatersolubilityandbioavailabili tyofpoorlywater solubledru… 相似文献
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ZHENG Xiaohui WANG Lijun ZHANG Lan HONG Yuankai HUANG Lixin SHA Yinlin 《科学通报(英文版)》2006,51(7):830-838
Alzheimer’s disease (AD) is one of the progressive neurodegenerative diseases associated with protein conformational transition, generally known as protein conformational disorders[1]. The general characteriza- tions of AD are the intracellular fibrillar… 相似文献
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The effect of thermo-mechanical treatment on the mechanical properties of a novel β-type Ti–36Nb–5Zr(wt%) alloy has been investigated.The solution treated alloy consists of β and α″ phases and exhibits a two-stage yielding with a low yield stress(around 100 MPa). After cold rolling at a reduction of 87.5% and subsequent annealing treatment at 698 K for 25 min, a fine microstructure with nanosized α precipitates distributed in small β grains as well as high density of dislocations was obtained to achieve a yield strength of 720 MPa and a ultimate tensile strength of 860 MPa. In spite of the formation of α precipitates, the β-stabilizers are not enriched in the parent β matrix due to the short duration and low temperature of the thermal treatment, resulting in a low chemical stability of β phase. The low stability of β phase and the small volume fraction of α precipitates produce a low Young’s modulus of 48 GPa. Such an excellent combination of low elastic modulus and high strength in mechanical properties indicates great potential for biomedical applications. 相似文献
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LIU Tao CHEN Long HOU Sen XUE Yonglai FENG Xizeng 《科学通报(英文版)》2006,51(5):530-535
GENE THERAPY IS A COMMON PROCESS TO DELIVER EXTRIN- SIC GENES INTO TARGET CELLS FOR FURTHER GENE EXPRESSION, FOR THE PURPOSE OF TREATING DISEASES. A WELL DESIGNED GENE DELIVERY CARRIER CAN EFFICIENTLY PACKAGE AND PRO- TECT NUCLEIC ACID FROM BEING DIGESTED BY A VARIETY OF ENZYMES IN VIVO AND SHOULD BE ABLE TO SPECIFICALLY LO- CATE EXTRINSIC GENES INTO THE TARGET ORGANISMS. S… 相似文献
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LENG Bin JIN XiaoGang LIN QiuXia CHEN Lei WANG Yan DU ZhiYan LIN KaiLi CHANG Jiang GU XiaoMing WANG ChangYong 《科学通报(英文版)》2013,58(24):3033-3042
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Yuanlong Zhao ;Jinliang Yuan ;Shanchi Peng ;Loren E. Babcock ;Jin Peng ;Qingjun Guo ;Jihpai Lin ;Tongshu Tai ;Ruidong Yang ;Yuxian Wang 《自然科学进展(英文版)》2008,18(12):1549-1556
A trilobite biostratigraphic study of a new section of the Kaili Formation at Jianshan, Chuandong Village, Jianhe County, Guizhou is reported. Additional occurrences of key species associated with the Ovatoryctocara granulata-Bathynotus holopygus Zone and the overlying Oryctocephalus indicus Zone that were originally defined from the trilobite assemblages at the WuliuZengjiayan section of the Kaili are reported from this new section. The first appearance datum (FAD) of Oryctocephalus indicus occurs at the 44.52 m above the base of the unit. Based on study of abundant specimens (n = 800) from the Kaili Formation, we argue that Oryctocephalus indicus is a widespread taxon with a global distribution. O. reticulatus (Lermontova, 1940) from the middle part of the Kounamkites Zone of the Amganian Stage in the Molodo River region of Siberia and O. americanus (Sundberg and McCollum, 2003) from Nevada, North America are similar to representatives of O. indicus which occur in the O. indicus Zone of the Kaili Formation. O. reticulatus and O. americanus are here synonymized with O. indicus (Reed, 1910). This study strengthens the Wuliu-Zengjiayan section of the Kaili Formation as a candidate section for a Global Stratotype for the base of the unnamed Cambrian Series 3. 相似文献