共查询到20条相似文献,搜索用时 62 毫秒
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紫毛香茶菜中7,20-环氧-对映-贝壳杉烯型二萜王艳红1)陈耀祖2)孙汉董3)林中文3)(1)中山大学化学与化学工程学院,广州510275;2)浙江大学化学系;3)中国科学院昆明植物研究所)关键词唇形科,香茶菜属,紫毛香茶菜,对映-贝壳杉烯,二萜分类... 相似文献
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狭基香茶菜干燥后经水提取、醇沉淀再经SephadexG-150柱色谱纯化,分离得到4种狭基香茶菜水溶性多糖ARP、ARP-2、ARP-3和ARP-4;采用SephadesxG-200柱层析,琼脂糖凝胶电泳等方法证明为均一性多糖组分,用凝胶谱法测得相对平均分子质量分别是42000、9400、34000和8700;红外光谱,高效液相色谱等表明,ARP-1由L-鼠李糖、D-1葡萄糖组成,糖残基以α1,2 相似文献
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从唇形和尾叶香茶菜叶子的甲醇提取物中,分离提取了4个对映-贝壳杉烯型二萜,并利用核磁共振氢谱和碳谱,以及质谱、红外光谱和紫外光谱等方法,对以上各化合物进行了结构鉴定。化合物1在该植物的文献中未见报道。 相似文献
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新香茶菜素是从中草药显脉叶香茶菜中提取出来的一种天然有机二萜化合物,由X射线衍射测定结果可知,其晶体属单斜晶系,空间群为P21,α=0.6776(2),b=1.4640(8),c=1.1412(5)nm,β=95.71°(3),Z=2,晶体结果表明,分子中含有一个α-亚甲基环戊基乙酸酯和一个四氢γ-吡喃酮结构,这两种结果中与环直接链连的双键部分具有一定的内应力,是反应活性区。 相似文献
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从尾叶香茶菜(Rabdosia excisa)的地上部分分离到11种化合物,其中5种经过测定其熔点、比旋度、紫外光谱、红外光谱、核磁共振和质谱等结果,分别鉴定为isokamebakaurin,oridonin, 齐墩果酸, 熊果酸,β-谷甾醇.其中isokamebakaurin是首次从尾叶香茶菜中分离到的.对于醇提水溶部位,进行了药理作用研究,证明其具有一定的免疫调节、抗菌作用及显著的抗氧化作用.本研究结果为进一步从尾叶香茶菜中提取药物提供了指导性依据. 相似文献
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从唇形科尾叶香茶菜叶子的甲醇提取物中,分离提取了4个对映-贝壳杉烯型二萜,并利用核磁共振氢谱和碳谱,以及质谱、红外光谱和紫外光谱等方法,对以上各化合物进行了结构鉴定.化合物1在该植物的文献中未见报道. 相似文献
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王艳红 《中山大学学报(自然科学版)》1998,37(2):49-51
从紫毛香茶菜干叶的乙醇提取物中分离得到2个二萜化合物,利用红外、紫外、质谱以及核磁共振波谱等光谱方法,对这2个化合物的结构进行了鉴定.紫毛香茶菜的化学成分尚未见文献报道. 相似文献
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RP-HPLC法测定不同生长期尾叶香茶菜中二萜类成分的含量 总被引:1,自引:0,他引:1
采用反相高效液相色谱法测定了不同生长期尾叶香茶菜叶的4种主要二萜类成分kamebakaurin(Ⅰ), excisanin A(Ⅱ), rabdokunmin C(Ⅲ)和kamebanin(Ⅳ)的含量. 结果表明, 不同生长期尾叶香茶菜叶中二萜类成分含量发生变化. 化合物Ⅰ和Ⅱ在7月上旬含量最高; 化合物Ⅲ在6月初到8月中旬含量变化不大, 但8月上旬含量开始下降;化合物Ⅳ在6月中旬含量最高, 7月上旬含量开始下降. 7月上旬尾叶香茶菜中总二萜类成分含量最高. 相似文献
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腺花香茶菜二萜成分研究 总被引:2,自引:2,他引:0
王艳红 《中山大学学报(自然科学版)》1998,37(1):122-124
由腺花香茶菜全草的丙酮提取物中分离得到2个对映-贝壳杉烯型二萜,利用红外、紫外、质谱和核磁共振等光谱方法,对这2个化合物的结构进行了鉴定.其中的1个化合物灰岩香茶菜甲素首次从该植物中分离得到 相似文献
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Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness. 相似文献
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Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly. 相似文献
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理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。 相似文献
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As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death. 相似文献
15.
Miao Maosheng 《华南师范大学学报(自然科学版)》2014,(6)
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula- 相似文献
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Yang Weitao 《华南师范大学学报(自然科学版)》2014,46(6):137-138
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re- 相似文献
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Bernard Kirtman 《华南师范大学学报(自然科学版)》2014,(6)
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that 相似文献
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《上海师范大学学报(自然科学版)》2014,(5):550
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with 相似文献
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《吉林大学学报(理学版)》2014,(5):1105
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has 相似文献