The isotope effect: Prediction,discussion, and discovery

The precise position of a spectral line emitted by an atomic system depends on the mass of the atomic nucleus and is therefore different for isotopes belonging to the same element. The possible presence of an isotope effect followed from Bohr's atomic theory of 1913, but it took several years before it was confirmed experimentally. Its early history involves the childhood not only of the quantum atom, but also of the concept of isotopy. Bohr's prediction of the isotope effect was apparently at odds with early attempts to distinguish between isotopes by means of their optical spectra. However, in 1920 the effect was discovered in HCl molecules, which gave rise to a fruitful development in molecular spectroscopy. The first detection of an atomic isotope effect was no less important, as it was by this means that the heavy hydrogen isotope deuterium was discovered in 1932. The early development of isotope spectroscopy led to successes as well as problems. At the end of the paper I briefly comment on the relationship between theory, experiment and prediction in this area of spectral physics.     

‘Let the stars shine in peace!’ Niels Bohr and stellar energy, 1929–1934

Faced with various anomalies related to nuclear physics in particular, in 1929 Niels Bohr suggested that energy might not be conserved in the atomic nucleus and the processes involving it. By this radical proposal he hoped not only to get rid of the anomalies but also saw a possibility to explain a puzzle in astrophysics, namely the energy generated by stars. Bohr repeated his suggestion of stellar energy arising ex nihilo on several occasions but without ever going into detail. In fact, it is not very clear what he meant or how seriously he took the stellar energy hypothesis. This paper relates Bohr's comments to the period's attempts to find a mechanism for stellar energy and also to the role played by astrophysics at the Copenhagen institute. Moreover, it looks at how Bohr's hypothesis was received not only by physicists but also by astronomers. In this regard the disciplinary status of astrophysics and its contemporary relation to the new quantum mechanics is of relevance. It turns out that, with very few exceptions, the hypothesis was met with silence by astronomers and astrophysicists concerned with the problem of stellar energy production. And yet, for a brief period of time it did have an impact on how physicists thought about the interior of the stars.     

On the “negative utility” of Ernst Cassirer׳s philosophy of physics: An application to the EPR argument

This paper tries to reconstruct Ernst Cassirer's potential reception of the EPR argument, as exposed by Einstein in his letter to Cassirer of March 1937. It is shown that, in conformity with his transcendental epistemology taking the conditions of accessibility as constitutive of the quantum object, Cassirer would probably have rejected the argument. Indeed, Cassirer would probably not have subscribed to its separability/local causality presupposition (which goes against his interpretation of the quantum formalism as a self-sufficient condition constitutive of the quantum object, without any reliance on spatial intuition), nor to its completeness requirement (as his partial endorsement of Bohr's complementarity, and his rejection of the Kantian "idea of complete determination", illustrate). By rejecting both of its premises, Cassirer's philosophy of physics thus enables to escape the EPR dilemma, and exhibits what, in Kantian terms, might be called a "negative utility" with respect to physical science. A further investigation of the anti-reductionist utility of Cassirer's systematic philosophy with respect to physics and other "symbolic forms" is finally suggested.     

Pluralism and anarchism in quantum physics: Paul Feyerabend's writings on quantum physics in relation to his general philosophy of science

This paper aims to show that the development of Feyerabend's philosophical ideas in the 1950s and 1960s largely took place in the context of debates on quantum mechanics.In particular, he developed his influential arguments for pluralism in science in discussions with the quantum physicist David Bohm, who had developed an alternative approach to quantum physics which (in Feyerabend's perception) was met with a dogmatic dismissal by some of the leading quantum physicists. I argue that Feyerabend's arguments for theoretical pluralism and for challenging established theories were connected to his objections to the dogmatism and conservatism he observed in quantum physics.However, as Feyerabend gained insight into the physical details and historical complexities which led to the development of quantum mechanics, he gradually became more modest in his criticisms. His writings on quantum mechanics especially engaged with Niels Bohr; initially, he was critical of Bohr's work in quantum mechanics, but in the late 1960s, he completely withdrew his criticism and even praised Bohr as a model scientist. He became convinced that however puzzling quantum mechanics seemed, it was methodologically unobjectionable – and this was crucial for his move towards ‘anarchism’ in philosophy of science.     

A history of entanglement: Decoherence and the interpretation problem

This paper examines the interweaving of the history of quantum decoherence and the interpretation problem in quantum mechanics through the work of two physicists—H. Dieter Zeh and Wojciech Zurek. In the early 1970s Zeh anticipated many of the important concepts of decoherence, framing it within an Everett-type interpretation. Zeh has since remained committed to this view; however, Zurek, whose papers in the 1980s were crucial in the treatment of the preferred basis problem and the subsequent development of density matrix formalism, has argued that decoherence leads to what he terms the ‘existential interpretation’, compatible with certain aspects of both Everett's relative-state formulation and the Bohr's ‘Copenhagen interpretation’. I argue that these different interpretations can be traced back to the different early approaches to the study of environment-induced decoherence in quantum systems, evident in the early work of Zeh and Zurek. I also show how Zurek's work has contributed to the tendency to see decoherence as contributing to a ‘new orthodoxy’ or a reconstruction of the original Copenhagen interpretation.     

Holography and emergence

In this paper, I discuss one form of the idea that spacetime and gravity might ‘emerge’ from quantum theory, i.e. via a holographic duality, and in particular via AdS/CFT duality. I begin by giving a survey of the general notion of duality, as well as its connection to emergence. I then review the AdS/CFT duality and proceed to discuss emergence in this context. We will see that it is difficult to find compelling arguments for the emergence of full quantum gravity from gauge theory via AdS/CFT, i.e. for the boundary theory's being metaphysically more fundamental than the bulk theory.     

Explaining Atomic Spectra within Classical Physics: 1897-1913

In this paper we analyse the approach to interpreting atomic spectra in the framework of classical physics from the discovery of the electron in 1897 to Bohr's atomic model of 1913. Taken as a whole, efforts in this direction are part of a remarkable intellectual endeavour in which the classical theoretical framework seems to have been exploited to its full potential. By demonstrating the limits and weaknesses of classical physics in solving the problem of spectral emissions, these attempts opened the way to a complete break from traditional thought and the introduction of the new quantum ideas.     

The roots of the silver tree: Boyle,alchemy, and teleology

Though Robert Boyle called final causes one of the most important subjects for a natural philosopher to study, his own treatise on the subject, the Disquisition about Final Causes, has received comparatively little scholarly attention. In this paper, I explicate Boyle's complex argument against the use of teleological explanations for inanimate bodies, such as metals. The central object of this argument is a mysterious allusion to a silver plant. I claim that the silver plant is best understood as a reference to alchemical product: the Arbor Dianae, an offshoot of George Starkey's recipe for the Philosophers' Stone. Then, I show how the context of alchemy not only clarifies Boyle's argument but also places it within a wider dialectic about matter and teleology. I then contrast the parallel arguments of Boyle and John Ray on the question of whether metals have divine purposes and show that the difference is explained by Boyle's belief in the transmutation of metals.     

Quantum jumps,superpositions, and the continuous evolution of quantum states

The apparent dichotomy between quantum jumps on the one hand, and continuous time evolution according to wave equations on the other hand, provided a challenge to Bohr's proposal of quantum jumps in atoms. Furthermore, Schrödinger's time-dependent equation also seemed to require a modification of the explanation for the origin of line spectra due to the apparent possibility of superpositions of energy eigenstates for different energy levels. Indeed, Schrödinger himself proposed a quantum beat mechanism for the generation of discrete line spectra from superpositions of eigenstates with different energies.However, these issues between old quantum theory and Schrödinger's wave mechanics were correctly resolved only after the development and full implementation of photon quantization. The second quantized scattering matrix formalism reconciles quantum jumps with continuous time evolution through the identification of quantum jumps with transitions between different sectors of Fock space. The continuous evolution of quantum states is then recognized as a sum over continually evolving jump amplitudes between different sectors in Fock space.In today's terminology, this suggests that linear combinations of scattering matrix elements are epistemic sums over ontic states. Insights from the resolution of the dichotomy between quantum jumps and continuous time evolution therefore hold important lessons for modern research both on interpretations of quantum mechanics and on the foundations of quantum computing. They demonstrate that discussions of interpretations of quantum theory necessarily need to take into account field quantization. They also demonstrate the limitations of the role of wave equations in quantum theory, and caution us that superpositions of quantum states for the formation of qubits may be more limited than usually expected.     

Collaborative explanation,explanatory roles,and scientific explaining in practice

Scientific explanation is a perennial topic in philosophy of science, but the literature has fragmented into specialized discussions in different scientific disciplines. An increasing attention to scientific practice by philosophers is (in part) responsible for this fragmentation and has put pressure on criteria of adequacy for philosophical accounts of explanation, usually demanding some form of pluralism. This commentary examines the arguments offered by Fagan and Woody with respect to explanation and understanding in scientific practice. I begin by scrutinizing Fagan's concept of collaborative explanation, highlighting its distinctive advantages and expressing concern about several of its assumptions. Then I analyze Woody's attempt to reorient discussions of scientific explanation around functional considerations, elaborating on the wider implications of this methodological recommendation. I conclude with reflections on synergies and tensions that emerge when the two papers are juxtaposed and how these draw attention to critical issues that confront ongoing philosophical analyses of scientific explanation.     

On black hole complementarity

Black hole complementarity has been proposed as a way to reconcile the result of Hawking, that black holes evaporate, with fundamental unitary quantum theories of gravity, such as string theory. Hawking's semi-classical analysis suggests that the evaporation of black holes is a non-unitary process, yet black hole complementarity gives a perspective on the semi-classical black hole which retains unitarity. We outline this proposal and address a number of methodological criticisms that have been made with regard to this proposal.     

Chance,determinism and the classical theory of probability

This paper situates the metaphysical antinomy between chance and determinism in the historical context of some of the earliest developments in the mathematical theory of probability. Since Hacking's seminal work on the subject, it has been a widely held view that the classical theorists of probability were guilty of an unwitting equivocation between a subjective, or epistemic, interpretation of probability, on the one hand, and an objective, or statistical, interpretation, on the other. While there is some truth to this account, I argue that the tension at the heart of the classical theory of probability is not best understood in terms of the duality between subjective and objective interpretations of probability. Rather, the apparent paradox of chance and determinism, when viewed through the lens of the classical theory of probability, manifests itself in a much deeper ambivalence on the part of the classical probabilists as to the rational commensurability of causal and probabilistic reasoning.     

‘Working in a new world’: Kuhn,constructivism, and mind-dependence

In The Structure of Scientific Revolutions, Kuhn famously advanced the claim that scientists work in a different world after a scientific revolution. Kuhn's view has been at the center of a philosophical literature that has tried to make sense of his bold claim, by listing Kuhn's view in good company with other seemingly constructivist proposals. The purpose of this paper is to take some steps towards clarifying what sort of constructivism (if any) is in fact at stake in Kuhn's view. To this end, I distinguish between two main (albeit not exclusive) notions of mind-dependence: a semantic notion and an ontological one. I point out that Kuhn's view should be understood as subscribing to a form of semantic mind-dependence, and conclude that semantic mind-dependence does not land us into any worrisome ontological mind-dependence, pace any constructivist reading of Kuhn.     

Fresnel's laws,ceteris paribus

This article is about structural realism, historical continuity, laws of nature, and ceteris paribus clauses. Fresnel's Laws of optics support Structural Realism because they are a scientific structure that has survived theory change. However, the history of Fresnel's Laws which has been depicted in debates over realism since the 1980s is badly distorted. Specifically, claims that J. C. Maxwell or his followers believed in an ontologically-subsistent electromagnetic field, and gave up the aether, before Einstein's annus mirabilis in 1905 are indefensible. Related claims that Maxwell himself did not believe in a luminiferous aether are also indefensible. This paper corrects the record. In order to trace Fresnel's Laws across significant ontological changes, they must be followed past Einstein into modern physics and nonlinear optics. I develop the philosophical implications of a more accurate history, and analyze Fresnel's Laws' historical trajectory in terms of dynamic ceteris paribus clauses. Structuralists have not embraced ceteris paribus laws, but they continue to point to Fresnel's Laws to resist anti-realist arguments from theory change. Fresnel's Laws fit the standard definition of a ceteris paribus law as a law applicable only in particular circumstances. Realists who appeal to the historical continuity of Fresnel's Laws to combat anti-realists must incorporate ceteris paribus laws into their metaphysics.     

From secondary causes to artificial instruments: Pierre-Sylvain Régis's rethinking of scholastic accounts of causation

Although several of Descartes's disciples established occasionalism as the natural outcome of Cartesianism, Pierre-Sylvain Régis forcefully resisted this conclusion by developing an account of secondary causes in which God does not immediately intervene in the natural world. In order to understand this view, it has been argued that Régis melds Aquinas's concurrentism with the new, mechanist natural philosophy defended in Cartesian physics. In this paper, I contend that such a reading of Régis's position is misleading for our understanding of both his account of secondary causality and the relationship between medieval debates and seventeenth century natural philosophy. I show that Régis's account of secondary causality denies two fundamental features at the core of the account proposed by Aquinas, namely that God acts immediately in nature and that secondary causes are per se causes. I contend that Régis's view more closely resembles a specific account of artificial instrumental causality developed by Duns Scotus. The comparison with Scotus shows that Régis is still dealing with conceptual tools that can be traced back to the scholastic tradition. Yet, Régis implements these tools to establish an account of causation that is fundamentally irreconcilable with scholastic natural philosophy.     

Putting a spin on circulating reference,or how to rediscover the scientific subject

Bruno Latour claims to have shown that a Kantian model of knowledge, which he describes as seeking to unite a disembodied transcendental subject with an inaccessible thing-in-itself, is dramatically falsified by empirical studies of science in action. Instead, Latour puts central emphasis on scientific practice, and replaces this Kantian model with a model of “circulating reference.” Unfortunately, Latour's alternative schematic leaves out the scientific subject. I repair this oversight through a simple mechanical procedure. By putting a slight spin on Latour's diagrammatic representation of his theory, I discover a new space for a post-Kantian scientific subject, a subject brilliantly described by Ludwik Fleck. The neglected subjectivities and ceaseless practices of science are thus re-united.     

Realism on the rocks: Novel success and James Hutton's theory of the earth

In this paper, I introduce a new historical case study into the scientific realism debate. During the late-eighteenth century, the Scottish natural philosopher James Hutton made two important successful novel predictions. The first concerned granitic veins intruding from granite masses into strata. The second concerned what geologists now term “angular unconformities”: older sections of strata overlain by younger sections, the two resting at different angles, the former typically more inclined than the latter. These predictions, I argue, are potentially problematic for selective scientific realism in that constituents of Hutton's theory that would not be considered even approximately true today played various roles in generating them. The aim here is not to provide a full philosophical analysis but to introduce the case into the debate by detailing the history and showing why, at least prima facie, it presents a problem for selective realism. First, I explicate Hutton's theory. I then give an account of Hutton's predictions and their confirmations. Next, I explain why these predictions are relevant to the realism debate. Finally, I consider which constituents of Hutton's theory are, according to current beliefs, true (or approximately true), which are not (even approximately) true, and which were responsible for these successes.     

Dark matter,the Equivalence Principle and modified gravity

Dark matter (DM) is an essential ingredient of the present Standard Cosmological Model, according to which only 5% of the mass/energy content of our universe is made of ordinary matter. In recent times, it has been argued that certain cases of gravitational lensing represent a new type of evidence for the existence of DM. In a recent paper, Peter Kosso attempts to substantiate that claim. His argument is that, although in such cases DM is only detected by its gravitational effects, gravitational lensing is a direct consequence of Einstein's Equivalence Principle (EEP) and therefore the complete gravitational theory is not needed in order to derive such lensing effects. In this paper I critically examine Kosso's argument: I confront the notion of empirical evidence involved in the discussion and argue that EEP does not have enough power by itself to sustain the claim that gravitational lensing in the Bullet Cluster constitutes evidence for the DM Hypothesis. As a consequence of this, it is necessary to examine the details of alternative theories of gravity to decide whether certain empirical situations are indeed evidence for the existence of DM. It may well be correct that gravitational lensing does constitute evidence for the DM Hypothesis—at present it is controversial whether the proposed modifications of gravitation all need DM to account for the phenomenon of gravitational lensing and if so, of which kind—but this will not be a direct consequence of EEP.