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1.
研究了树脂吸附法处理1,2-重氮氧基萘-4-磺酸生产酸析母液废水,考察了树脂吸附脱附性能的影响因素,并确定了最佳工艺参数。结果表明,NDA-409树脂对1,2,4-酸氧体生产酸析母液废水的吸附脱附效果良好。原废水呈深黑色,其中1,2,4-酸氧体浓度为8000-9000mg/L,CODcr浓度为10000-11000mg/L左右,处理后的出水无色透明,1,2,4-酸氧体浓度约为85mg/L,氧体去除率达99%,CODcr浓度小于100mg/L,CODcr去除率达99%;采用组合脱附剂对树脂进行洗脱再生,1,2,4-酸氧体的脱附率能稳定在99%以上。经过12批次小试稳定性实验和四批次放大实验证明,NDA-409树脂对1,2,4-酸氧体的吸附-脱附性能稳定。该工艺简单,操作方便,技术先进,不仅能有效地处理废水,使其实现达标排放,而且能回收废水中宝贵的化工原料,实现环境效益、社会效益和经济效益的统一,是一项具有推广价值的废水治理技术。  相似文献   

2.
针对石油工业含油废水排放量大、对环境污染严重的问题,以渤海某钻井平台的钻井盐屑含油废水为研究对象,采用A–MBR、Fenton氧化与活性炭吸附组合工艺对其进行处理.实验表明:当进水COD为3,930.1~5,119.0,mg/L、NH3–N和油的质量浓度分别为203.2~232.1,mg/L和903.4~936.9,mg/L时,组合工艺对废水COD、NH3–N和油的平均去除率分别为98.8%、97.7%和99.6%,处理效果好,出水水质稳定,水质达到天津市《污水综合排放标准》(DB 12/356—2008)的二级排放要求,可为同类废水处理提供参考.  相似文献   

3.
为研究恢复启动全程自养脱氮(CANON)工艺的方法,在原CANON工艺反应器上流式生物滤池中进行小试试验未对反应器内污泥进行任何处理的条件下,以自配的含NH4+.N和N02--N的培养基质为入水,采取经由厌氧氨氧化(ANAMMOX)反应的方式,对停止运行约1年的原CANON工艺进行恢复启动.调整水力停留时间(HRT)和培养基质中NH4+N、N02--N质量浓度,启动ANAMMOX反应;然后,调整培养基质中N02--N质量浓度和溶解氧(DO),成功启动了CANON反应器,整个过程共耗时67d.CANON工艺恢复启动完成后,当HRT为4.25h时去除效果较好,此时NH4+-N的容积负荷为160mg/(L·d),NH4+-N的去除率为90%左右,总氮(TN)去除率约为70%,TN去除量与N03--N生成量的比值介于1:0.13与1:0.32之间.  相似文献   

4.
报道影响水凝胶性质的因素及生色过程。研究表明,BSA-SDS-Ag聚合物水凝胶的吸光度A和电导率δ均随体系pH.Ag(NH3)2^ 浓度,反应温度和时间而变化。A除随温度升高而急剧增加之外,其它因素无前一平台;但δ的变化确较复杂。显色过程表明随Ag(NH3)2^ 浓度增加而加深,亦随反应时间的增加而加深,说明该体系为化学键合的凝胶体系,微粒的粒径亦随之变大。  相似文献   

5.
水解酸化—好氧生物处理焦化废水的试验研究   总被引:2,自引:0,他引:2  
对处理焦化废水的两种工艺的试验研究表明,采用水解酸化-好氧生物处理较单一好氧生物处理可取得良好的效果。水解酸化作为焦化废水的预处理比较适宜。当实际焦化废水进水CODcr浓度为2214mg/L,水解酸化停留时间12h,好氧曝气时间18h,间歇动态试验出水CODcr浓度为172mg/L时,CODcr的去除率达92.23%,满足污水综合排放标准(GB8978-95)的排放要求。  相似文献   

6.
降解氰化物微生物的筛选   总被引:9,自引:1,他引:8  
氰化物是一种毒性极大的物质,CN-浓度高将影响废水生化处理效果。对此,我们从太原煤气化公司生化站曝气池活性污泥中分离,筛选出高效降解CN-的细菌,共分离出23个菌株。通过降CN-实验比较、筛选出6h内降解率达80%以上的菌株8个。最适作用条件为:温度28℃,pH为7.2~8.5。其中9704006号菌株的降解率可高达90%以上。该菌株8h内可使浓度在30mg/L的含CN-废水降致0.5mg/L以下,达到国家废水排放一级标准。  相似文献   

7.
N-(2-甲氧基-5-甲酰基苄基)亚胺基二乙酸的合成及表征   总被引:4,自引:0,他引:4  
以4-甲氧基苯甲醛为原料,在无水氯化锌催化下,用浓盐酸和40%甲醛溶液进行氯甲基化反应制得取代氯苄,再以新制的无水碳酸钾为质子吸收剂、干燥的乙腈为溶剂,与亚氨基二乙酸二乙酯进行N-烷基化反就,然后用Ba(OH)2-水悬浮液进行了水解得到N-(2-甲氧基-5-甲酰基苄基)亚胺基二乙酸的钡盐沉淀,最后用烯硫酸处理得到N-(2-甲氧基-5-甲酰基苄基)亚胺基二乙酸,该方法产率高,工艺简单,通过^1H NMR、IR和元素分析对所得化合物的结构进行了表征。  相似文献   

8.
针对高浓度含氮废水亚硝化SBR工艺,进行了动力学模型研究,建立了NH4 -N浓度变化模型、NO2--N浓度变化模型和NO3--N浓度变化模型.通过试验对动力学模型进行了预测与评价,结果表明:以动力学方程式(尤其是NH4 -N浓度变化的模型、NO2--N浓度变化的模型)计算的理论值与实测值结果基本吻合,对高浓度氨氮废水亚硝化SBR工艺的设计和运行具有一定的指导意义.  相似文献   

9.
厌氧消化对养猪场废水的净化效果   总被引:1,自引:0,他引:1  
考察了不同水力停留时间下厌氧消化对养猪场废水水质(COD、NH4^+-N、TP和pH)的影响及装置产气量的变化.结果表明,厌氧消化对废水COD的去除效果较好,实验期内废水COD浓度持续下降,最终去除率为78.1%.但对NH4^+-N的去除效果不理想,最终去除率仅为1.8%,对废水TP的最终去除率为68.4%.  相似文献   

10.
采用有机碱在非水条件下将纯碱工业副产的NH4Cl分解为NH3和HCl,研究了在异丙醇溶剂中三辛胺(TOA)分解NH4Cl释放NH3的工艺,考察了反应温度、N2流量、TOA与NH4Cl摩尔比、异丙醇与TOA摩尔比、反应时间等对NH4Cl分解反应的影响。结果表明:NH4Cl处理量为0.1 mol时的最佳分解工艺条件为反应温度353 K、N2流量120 mL/min、TOA与NH4Cl摩尔比为1.4∶1、异丙醇与TOA摩尔比为7.1∶1、反应时间8.25 h。在最优条件下,NH3收率达到97%以上,且无废水排放。进一步探讨了极性溶剂下有机碱分解NH4Cl的反应机制,发现溶剂异丙醇中羟基与TOA中N原子上的孤对电子形成氢键,使TOA的碱性增强,与NH4Cl反应更容易释放出NH3。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

15.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

16.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

17.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

18.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

19.
20.
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has  相似文献   

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