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1.
铜基甲醇合成催化剂的EPR表征   总被引:1,自引:0,他引:1  
用EPR谱法对铜基甲醇合成催化剂作表征。结果表明:在少量Al ̄(3+)掺杂的ZnO-Al_2O_3体系可检测到g=1.9606±0.0002,△Hpp=2.8G的顺磁信号,其强度随Al_2O_3掺杂量增加而增强,当Al/Zn~2/100(原子比)时趋于峰值;而在三组份Cu-ZnO-Al_2O_3和四组份Cu-ZnO-Al_2O_3-Sc_2O_3催化剂体系中,此顺磁信号基本消失。以上结果为三价金属离子(Al ̄(3+)、Sc ̄(3+))在ZnO晶格掺杂诱生正一价缺位从而有利于Cu以+1价态存在的观点,提供了新证据。  相似文献   

2.
甲醇脱氢制备甲酸甲酯的催化性能研究   总被引:3,自引:0,他引:3  
将浸渍法制备的Cu/SiO2、Cu-ZnO/SiO2、Cu-ZnO-ZrO2/SiO2,以及Cu/γ-Al2O3、Cu-ZnO/γ-Al2O3、Cu-ZnO-ZrO2/γ-A六种催化剂应用于甲醇脱氢制甲酸甲酯反应。实验结果表明,以Al2O3为载体的催化选择性较差且易积炭失活;加有ZnO助催化剂的Cu-ZnO/SiO2性能优于末加助催化剂的Cu/SiO2;加有权助催化剂的Cu-Zn-ZrO2/Si  相似文献   

3.
CO2加H2合成甲醇反应中CuO/ZnAl2O4催化剂性能的研究   总被引:4,自引:0,他引:4  
研究了制备条件对CO2加H2合成CH3OH反应中CuO/ZnAl2O4催化剂的性能及ZnAl2O4尖晶石形成的影响。采用XRD、BET、TPD和FT-IR等测试技术,对催化剂晶相结构和表面物种进行了深入分析。结果表明,沉淀方法对催化活性具有重要影响;NaCO3沉淀剂最有利于ZnAl2O4尖晶石的形成;Zn/Al摩尔配比为0.23/0.38时,尖晶石形成最为完整,活性最好。经TPD和FT-IR测试,  相似文献   

4.
由共沉淀法合成了Zn/Al摩尔比为1、2、3和6的Zn-Al水滑石.热重-差热结果显示其分解经两个过程,分别对应180和220℃的吸热峰.经400℃焙烧,生成Zn-Al复合氧化物,XRD测定仅显示ZnO物相(除Zn/Al比为6的样品),表明组成成分均一.微量吸附量热结果表明Zn-Al复合氧化物的表面酸碱性介于γ-Al2O3和ZnO之间,碱性(酸性)随着Zn(Al)含量的增加而增强.  相似文献   

5.
Al_2O_3 弥散 Ti(C,N)基金属陶瓷刀具   总被引:1,自引:0,他引:1  
在Ti(C,N)基金属陶瓷中,通过加入Al2O3弥散颗粒,使材料的硬度和高温性能都得到提高,从而获得更好的切削耐磨性。研究结果表明:Al2O3的引入使Ti(C,N)基金属陶瓷的常温强度和韧性有所下降而硬度和高温力学性能得到了改善。切削试验表明:Ti(C,N)-Al2O3系金属陶瓷比硬质合金、Al2O3-TiC复合陶瓷刀具有更好的切削性能。SEM观察表明:在Ti(C,N)-Al2O3金属陶瓷中,Al2O3与Ti(C,N)有相互抑制晶粒生长的作用,使Ti(C,N)基金属陶瓷的晶粒更细化  相似文献   

6.
由共沉淀法合成了Zn/Al摩经为1,2,3,和6的Zn-Al水滑石。热重-差热结果显示其分解两个过程,分别对应180和220℃的吸热峰,经400℃焙烧,生成Zn-Al复合氧化物,XRD测定仅显示ZnO物相,表明组成成分均一。微量吸附量热结果表明Zn-Al复合经物的表面酸碱性介于γ-Al2O3和ZnO之间,碱性随着Zn含量的增加而增强。  相似文献   

7.
水滑石及柱撑水滑石的制备和表征   总被引:18,自引:1,他引:18  
制备了水滑石Mg6Al2(OH)16CO3.4H2O和类水滑石Mg4Al2(OH)12(NO3)2.4H2O,Zn6Al2(OH)16CO3.4H2O它们的晶体结构基本相似,热稳定性都不很高,200℃时将失去全部结晶水,200~450℃时将失去全部层间阴离子,以及大部分OH^-。用离子交换法和共沉淀法制轩了1,5-二萘磺酸柱撑水滑石Mg4Al2(OH)12(C10H6(SO3)2).4H2O,其层  相似文献   

8.
利用流态化化学气相淀积(CVD)制备Al2O3-SnO2复合粒子。探讨了SnO2在Al2O3超细颗粒上的包敷状态,考察了反应温度,反应物进料逍度比,反应时间等对反应结果的影响。结果表明,SnO2在复合粒子团聚体体相中呈均匀分布,形成Al2O3-SnO2复合粒子,SnO2均匀淀积在Al2O3超细颗粒原生粒子表面,流态化CVD包敷效果优于非流化过程,随反应时间的延长,产物中SnO2含量线性递增;而当反  相似文献   

9.
采用快速燃烧方法制备了超细Cu/ZnO/Al2O3催化剂,考察了制备参数对催化剂的结构和性质的影响,在脲与NO3^-摩尔比为0.26、预置反应温度为500℃,制得了分散度较好、颗粒较细的Cu/ZnO/Al2O3催化剂,其粒径和比表面分别为16nm和93.5m^2·g^-1,制备参数对CO2与H2合成甲醇反应中催化剂的催化性能有显著的影响,对制备过程和机理亦进行了较为详细的讨论。  相似文献   

10.
借助IR,DTA,XRD及OM分析手段,研究了ZnO,Na2O对CaO-Al2O3-SiO2系统玻璃析晶性能的影响。结果表明,随(Na2O+ZnO)/(Al2O3+SiO2)的量比增大,玻璃结构由致密转向疏松,且不均匀性增加,析晶活化能下降  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

13.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

14.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

15.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

16.
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that  相似文献   

17.
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the  相似文献   

18.
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of  相似文献   

19.
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with  相似文献   

20.
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