The effect of water on the electrical conductivity of olivine

It is well known that water (as a source of hydrogen) affects the physical and chemical properties of minerals--for example, plastic deformation and melting temperature--and accordingly plays an important role in the dynamics and geochemical evolution of the Earth. Estimating the water content of the Earth's mantle by direct sampling provides only a limited data set from shallow regions (<200 km depth). Geophysical observations such as electrical conductivity are considered to be sensitive to water content, but there has been no experimental study to determine the effect of water on the electrical conductivity of olivine, the most abundant mineral in the Earth's mantle. Here we report a laboratory study of the dependence of the electrical conductivity of olivine aggregates on water content at high temperature and pressure. The electrical conductivity of synthetic polycrystalline olivine was determined from a.c. impedance measurements at a pressure of 4 GPa for a temperature range of 873-1,273 K for water contents of 0.01-0.08 wt%. The results show that the electrical conductivity is strongly dependent on water content but depends only modestly on temperature. The water content dependence of conductivity is best explained by a model in which electrical conduction is due to the motion of free protons. A comparison of the laboratory data with geophysical observations suggests that the typical oceanic asthenosphere contains approximately 10(-2) wt% water, whereas the water content in the continental upper mantle is less than approximately 10(-3) wt%.     

Sound velocities of majorite garnet and the composition of the mantle transition region

The composition of the mantle transition region, characterized by anomalous seismic-wave velocity and density changes at depths of approximately 400 to 700 km, has remained controversial. Some have proposed that the mantle transition region has an olivine-rich 'pyrolite' composition, whereas others have inferred that it is characterized by pyroxene- and garnet-rich compositions ('piclogite'), because the sound velocities in pyrolite estimated from laboratory data are substantially higher than those seismologically observed. Although the velocities of the olivine polymorphs at these pressures (wadsleyite and ringwoodite) have been well documented, those of majorite (another significant high-pressure phase in the mantle transition region) with realistic mantle compositions have never been measured. Here we use combined in situ X-ray and ultrasonic measurements under the pressure and temperature conditions of the mantle transition region to show that majorite in a pyrolite composition has sound velocities substantially lower than those of earlier estimates, owing to strong nonlinear decreases at high temperature, particularly for shear-wave velocity. We found that pyrolite yields seismic velocities more consistent with typical seismological models than those of piclogite in the upper to middle parts of the region, except for the potentially larger velocity jumps in pyrolite relative to those observed at a depth of 410 km. In contrast, both of these compositions lead to significantly low shear-wave velocities in the lower part of the region, suggesting possible subadiabatic temperatures or the existence of a layer of harzburgite-rich material supplied by the subducted slabs stagnant at these depths.     

The post-spinel transformation in Mg2SiO4 and its relation to the 660-km seismic discontinuity

The 660-km seismic discontinuity in the Earth's mantle has long been identified with the transformation of (Mg,Fe)2SiO4 from gamma-spinel (ringwoodite) to (Mg,Fe)SiO3-perovskite and (Mg,Fe)O-magnesiowüstite. This has been based on experimental studies of materials quenched from high pressure and temperature, which have shown that the transformation is consistent with the seismically observed sharpness and the depth of the discontinuity at expected mantle temperatures. But the first in situ examination of this phase transformation in Mg2SiO4 using a multi-anvil press indicated that the transformation occurs at a pressure about 2 GPa lower than previously thought (equivalent to approximately 600 km depth) and hence that it may not be associated with the 660-km discontinuity. Here we report the results of an in situ study of Mg2SiO4 at pressures of 20-36 GPa using a combination of double-sided laser-heating and synchrotron X-ray diffraction in a diamond-anvil cell. The phase transformation from gamma-Mg2SiO4 to MgSiO3-perovskite and MgO (periclase) is readily observed in both the forward and reverse directions. In contrast to the in situ multi-anvil-press study, we find that the pressure and temperature of the post-spinel transformation in Mg2SiO4 is consistent with seismic observations for the 660-km discontinuity.     

Carbon solubility in olivine and the mode of carbon storage in the Earth's mantle

The total amount of carbon in the atmosphere, oceans and other near-surface reservoirs is thought to be negligible compared to that stored in the Earth's mantle. Although the mode of carbon storage in the mantle is largely unknown, observations of microbubbles on dislocations in minerals from mantle xenoliths has led to the suggestion that carbon may be soluble in silicates at high pressure. Here we report measurements of carbon solubility in olivine, the major constituent of the upper mantle, at pressures up to 3.5 GPa. We have found that, contrary to previous expectations, carbon solubility in olivine is exceedingly low--of the order of 0.1 to 1 parts per million by weight. Together with similar data for pyroxenes, garnet and spinel, we interpret this to imply that most carbon must be present as a separate phase in the deeper parts of the upper mantle, probably as a carbonate phase. Large-scale volcanic eruptions tapping such a carbonate-bearing mantle reservoir might therefore rapidly transfer large amounts of carbon dioxide into the atmosphere, consistent with models that link global mass extinctions to flood basalt eruptions via a sudden increase in atmospheric carbon dioxide levels.     

Natural examples of olivine lattice preferred orientation patterns with a flow-normal a-axis maximum

Tectonic plate motion is thought to cause solid-state plastic flow within the underlying upper mantle and accordingly lead to the development of a lattice preferred orientation of the constituent olivine crystals. The mechanical anisotropy that results from such preferred orientation typically produces a direction of maximum seismic wave velocity parallel to the plate motion direction. This has been explained by the existence of an olivine preferred orientation with an 'a-axis' maximum parallel to the induced mantle flow direction. In subduction zones, however, the olivine a axes have been inferred to be arranged roughly perpendicular to plate motion, which has usually been ascribed to localized complex mantle flow patterns. Recent experimental work suggests an alternative explanation: under conditions of high water activity, a 'B-type' olivine preferred orientation may form, with the a-axis maximum perpendicular to the flow direction. Natural examples of such B-type preferred orientation are, however, almost entirely unknown. Here we document widespread B-type olivine preferred orientation patterns from a subduction-type metamorphic belt in southwest Japan and show that these patterns developed in the presence of water. Our discovery implies that mantle flow above subduction zones may be much simpler than has generally been thought.     

Pressure sensitivity of olivine slip systems and seismic anisotropy of Earth's upper mantle

The mineral olivine dominates the composition of the Earth's upper mantle and hence controls its mechanical behaviour and seismic anisotropy. Experiments at high temperature and moderate pressure, and extensive data on naturally deformed mantle rocks, have led to the conclusion that olivine at upper-mantle conditions deforms essentially by dislocation creep with dominant [100] slip. The resulting crystal preferred orientation has been used extensively to explain the strong seismic anisotropy observed down to 250 km depth. The rapid decrease of anisotropy below this depth has been interpreted as marking the transition from dislocation to diffusion creep in the upper mantle. But new high-pressure experiments suggest that dislocation creep also dominates in the lower part of the upper mantle, but with a different slip direction. Here we show that this high-pressure dislocation creep produces crystal preferred orientations resulting in extremely low seismic anisotropy, consistent with seismological observations below 250 km depth. These results raise new questions about the mechanical state of the lower part of the upper mantle and its coupling with layers both above and below.     

Seismic evidence of negligible water carried below 400-km depth in subducting lithosphere

Strong evidence exists that water is carried from the surface into the upper mantle by hydrous minerals in the uppermost 10-12?km of subducting lithosphere, and more water may be added as the lithosphere bends and goes downwards. Significant amounts of that water are released as the lithosphere heats up, triggering earthquakes and fluxing arc volcanism. In addition, there is experimental evidence for high solubility of water in olivine, the most abundant mineral in the upper mantle, for even higher solubility in olivine's high-pressure polymorphs, wadsleyite and ringwoodite, and for the existence of dense hydrous magnesium silicates that potentially could carry water well into the lower mantle (deeper than 1,000?km). Here we compare experimental and seismic evidence to test whether patterns of seismicity and the stabilities of these potentially relevant hydrous phases are consistent with a wet lithosphere. We show that there is nearly a one-to-one correlation between dehydration of minerals and seismicity at depths less than about 250?km, and conclude that the dehydration of minerals is the trigger of instability that leads to seismicity. At greater depths, however, we find no correlation between occurrences of earthquakes and depths where breakdown of hydrous phases is expected. Lastly, we note that there is compelling evidence for the existence of metastable olivine (which, if present, can explain the distribution of deep-focus earthquakes) west of and within the subducting Tonga slab and also in three other subduction zones, despite metastable olivine being incompatible with even extremely small amounts of water (of the order of 100?p.p.m. by weight). We conclude that subducting slabs are essentially dry at depths below 400?km and thus do not provide a pathway for significant amounts of water to enter the mantle transition zone or the lower mantle.     

Anisotropy of thermal diffusivity in the upper mantle.

Heat transfer in the mantle is a key process controlling the Earth's dynamics. Upper-mantle mineral phases, especially olivine, have been shown to display highly anisotropic thermal diffusivity at ambient conditions, and seismic anisotropy data show that preferred orientations of olivine induced by deformation are coherent at large scales (>50 km) in the upper mantle. Thus heat transport in the upper mantle should be anisotropic. But the thermal anisotropy of mantle minerals at high temperature and its relationship with deformation have not been well constrained. Here we present petrophysical modelling and laboratory measurements of thermal diffusivity in deformed mantle rocks between temperatures of 290 and 1,250 K that demonstrate that deformation may induce a significant anisotropy of thermal diffusivity in the uppermost mantle. We found that heat transport parallel to the flow direction is up to 30 per cent faster than that normal to the flow plane. Such a strain-induced thermal anisotropy implies that the upper-mantle temperature distribution, rheology and, consequently, its dynamics, will depend on deformation history. In oceans, resistive drag flow would result in lower vertical diffusivities in both the lithosphere and asthenosphere and hence in less effective heat transfer from the convective mantle. In continents, olivine orientations frozen in the lithosphere may induce anisotropic heating above mantle plumes, favouring the reactivation of pre-existing structures.     

Resistance to mantle flow inferred from the electromagnetic strike of the Australian upper mantle

Seismic anisotropy is thought to result from the strain-induced lattice-preferred orientation of mantle minerals, especially olivine, owing to shear waves propagating faster along the a-axis of olivine crystals than along the other axes. This anisotropy results in birefringence, or 'shear-wave splitting', which has been investigated in numerous studies. Although olivine is also anisotropic with respect to electrical conductivity (with the a-axis being most conductive), few studies of the electrical anisotropy of the upper mantle have been undertaken, and these have been limited to relatively shallow depths in the lithospheric upper mantle. Theoretical models of mantle flow have been used to infer that, for progressive simple shear imparted by the motion of an overriding tectonic plate, the a-axes of olivine crystals should align themselves parallel to the direction of plate motion. Here, however, we show that a significant discrepancy exists between the electromagnetic strike of the mantle below Australia and the direction of present-day absolute plate motion. We infer from this discrepancy that the a-axes of olivine crystals are not aligned with the direction of the present-day plate motion of Australia, indicating resistance to deformation of the mantle by plate motion.     

Evidence for mantle metasomatism by hydrous silicic melts derived from subducted oceanic crust

The low concentrations of niobium, tantalum and titanium observed in island-arc basalts are thought to result from modification of the sub-arc mantle by a metasomatic agent, deficient in these elements, that originates from within the subducted oceanic crust. Whether this agent is an hydrous fluid or a silica-rich melt has been discussed using mainly a trace-element approach and related to variable thermal regimes of subduction zones. Melting of basalt in the absence of fluid both requires high temperatures and yields melt compositions unlike those found in most modern or Mesozoic island arcs. Thus, metasomatism by fluids has been thought to be the most common situation. Here, however, we show that the melting of basalt under both H2O-added and low-temperature conditions can yield extremely alkali-rich silicic liquids, the alkali content of which increases with pressure. These liquids are deficient in titanium and in the elements niobium and tantalum and are virtually identical to glasses preserved in mantle xenoliths found in subduction zones and to veins found in exhumed metamorphic terranes of fossil convergent zones. We also found that the interaction between such liquids and mantle olivine produces modal mineralogies that are identical to those observed in metasomatized Alpine-type peridotites. We therefore suggest that mantle metasomatism by slab-derived melt is a more common process than previously thought.     

An experimental study of phase transformations in olivine under pressure and temperature conditions corresponding to the mantle transition zone

High-pressure polymorphs of olivine (wadsleyite and ringwoodite) are major minerals in the mantle transition zone (MTZ).Phase transformations in olivine are important for a series of geodynamic problems such as the mineralogical and evolutionary history of the mantle,mantle convection patterns,and deep focus earthquakes in subduction zones.In this study,we examine phase transformations in olivine with two compositions,namely Mg 2 SiO 4 (Fo 100) and (Mg 0.9 Fe 0.1) 2 SiO 4 (Fo 90),at pressures between 14.1 and 20 GPa and a constant temperature of 1400°C,using the newly installed multi-anvil system at the Laboratory for Studies of the Earth’s Deep Interior (SEDI),China University of Geosciences (Wuhan).At 14.1 GPa,Fo 90 transformed completely into the wadsleyite structure (β),while Fo 100 remained as olivine (α).Between 14.8 and 15.6 GPa,both Fo 100 and Fo 90 transformed into the wadsleyite structure.Wadsleyite crystals were identified by two characteristic Raman peaks between 722 and 723 and 917 and 919 cm 1.They exhibit a bimodal grain size distribution:large-crystals with average grain sizes greater than 100 μm and microcrystals less than 10 μm.The population of microcrystals increased with pressure,apparently due to the increase in over-pressure (the difference between the experimental pressure condition and the equilibrium transformation pressure at 1400°C),which promotes nucleation and retards grain growth.All run charges contained large numbers of wadsleyite microcrystals,because of the low activation energy of the nucleation process.The experimentally observed microstructure may shed light on the morphology of wadsleyite observed in shocked meteorites.At 19.5 GPa,wadsleyite coexisted with ringwoodite (γ) in Fo 100,but was absent in Fo 90.At 20 GPa,both samples transformed completely into ringwoodite,which was characterized by the 798 and 840 cm 1 Raman lines.Ringwoodite crystals are euhedral grains (average grain size 10-20 μm),with well-developed triple junctions.The complex upper mantle structure in eastern China determined from seismological studies cannot be explained by the simple transformation sequence of the olivine system alone.Phase transformations in other pyroxene-normative components (including pyroxenes and garnets) and the interaction of these components with olivine may be responsible for the complex structure.High-pressure and high-temperature experimental studies on complex systems (e.g.olivine-pyroxene),combined with data from geophysical exploration,may help in establishing a more realistic geological-petrological model for eastern China and further our understanding of the possible physical mechanisms that are responsible for the complex structure.Such studies will have profound implications for understanding the dynamic processes in the deep Earth interior.     

The strength of Mg(0.9)Fe(0.1)SiO3 perovskite at high pressure and temperature

The Earth's lower mantle consists mainly of (Mg,Fe)SiO3 perovskite and (Mg,Fe)O magnesiowüstite, with the perovskite taking up at least 70 per cent of the total volume. Although the rheology of olivine, the dominant upper-mantle mineral, has been extensively studied, knowledge about the rheological behaviour of perovskite is limited. Seismological studies indicate that slabs of subducting oceanic lithosphere are often deflected horizontally at the perovskite-forming depth, and changes in the Earth's shape and gravity field during glacial rebound indicate that viscosity increases in the lower part of the mantle. The rheological properties of the perovskite may be important in governing these phenomena. But (Mg,Fe)SiO3 perovskite is not stable at high temperatures under ambient pressure, and therefore mechanical tests on (Mg,Fe)SiO3 perovskite are difficult. Most rheological studies of perovskite have been performed on analogous materials, and the experimental data on (Mg,Fe)SiO3 perovskite are limited to strength measurements at room temperature in a diamond-anvil cell and microhardness tests at ambient conditions. Here we report results of strength and stress relaxation measurements of (Mg(0.9)Fe(0.1))SiO3 perovskite at high pressure and temperature. Compared with the transition-zone mineral ringwoodite at the same pressure and temperature, we found that perovskite is weaker at room temperature, which is consistent with a previous diamond-anvil-cell experiment, but that perovskite is stronger than ringwoodite at high temperature.     

High 3He/4He ratios in picritic basalts from Baffin Island and the role of a mixed reservoir in mantle plumes

The high 3He/4He ratio of volcanic rocks thought to be derived from mantle plumes is taken as evidence for the existence of a mantle reservoir that has remained largely undegassed since the Earth's accretion. The helium isotope composition of this reservoir places constraints on the origin of volatiles within the Earth and on the evolution and structure of the Earth's mantle. Here we show that olivine phenocrysts in picritic basalts presumably derived from the proto-Iceland plume at Baffin Island, Canada, have the highest magmatic 3He/4He ratios yet recorded. A strong correlation between 3He/4He and 87Sr/86Sr, 143Nd/144Nd and trace element ratios demonstrate that the 3He-rich end-member is present in basalts that are derived from large-volume melts of depleted upper-mantle rocks. This reservoir is consistent with the recharging of depleted upper-mantle rocks by small volumes of primordial volatile-rich lower-mantle material at a thermal boundary layer between convectively isolated reservoirs. The highest 3He/4He basalts from Hawaii and Iceland plot on the observed mixing trend. This indicates that a 3He-recharged depleted mantle (HRDM) reservoir may be the principal source of high 3He/4He in mantle plumes, and may explain why the helium concentration of the 'plume' component in ocean island basalts is lower than that predicted for a two-layer, steady-state model of mantle structure.     

Stable methane hydrate above 2 GPa and the source of Titan's atmospheric methane

Methane hydrate is thought to have been the dominant methane-containing phase in the nebula from which Saturn, Uranus, Neptune and their major moons formed. It accordingly plays an important role in formation models of Titan, Saturn's largest moon. Current understanding assumes that methane hydrate dissociates into ice and free methane in the pressure range 1-2 GPa (10-20 kbar), consistent with some theoretical and experimental studies. But such pressure-induced dissociation would have led to the early loss of methane from Titan's interior to its atmosphere, where it would rapidly have been destroyed by photochemical processes. This is difficult to reconcile with the observed presence of significant amounts of methane in Titan's present atmosphere. Here we report neutron and synchrotron X-ray diffraction studies that determine the thermodynamic behaviour of methane hydrate at pressures up to 10 GPa. We find structural transitions at about 1 and 2 GPa to new hydrate phases which remain stable to at least 10 GPa. This implies that the methane in the primordial core of Titan remained in stable hydrate phases throughout differentiation, eventually forming a layer of methane clathrate approximately 100 km thick within the ice mantle. This layer is a plausible source for the continuing replenishment of Titan's atmospheric methane.     

Magma mixing in upper mantle: Evidence from high Mg<Superscript>#</Superscript> olivine hosted melt inclusions in MORBs near East Pacific Rise 13°N

Early formed high-Mg^# olivine phenocrysts during evolution of MORB magmas usually host melt inclusions, which record im-portant information about the early-stage evolution of magma. Five MORB samples from near East Pacific Rise (EPR) 13°N vary little in K/Ti (0.07–0.12), Tb/Lu (1.72–1.84) and Sm/Nd (0.310–0.332) and have similar REEs patterns, indicating that depleted upper mantle has similar mineral composition. Sixty-five initial melt inclusions derived by correcting olivine fractionation and “FeO-Loss” show averagely higher MgO contents than their host rocks. Melt inclusions have higher CaO/Al₂O₃ ratios than their host rocks, and these CaO/Al₂O₃ ratios are positively and negatively correlated with MgO and Na₂O respectively, suggesting that these magmas have experienced high pressure crystallization of clinopyroxene. Average crystallization pressure, which is calculated based on the pressure dependence of clinopyroxene crystallization, is 0.83–0.25 GPa, and implys that these melt inclusions are averagely trapped in mantle depth of ~24 km. These melt inclusions show negative correlations of Ca₈/Al₈ and Na₈ with Fe₈, and wider ranges of Ca₈/Al₈, Na₈, Fe₈ and K/Ti than their host rocks, suggesting that these melt inclusions formed by mixing magmas of different melting degrees and depths. According to the average value and ranges of Ca₈/Al₈, Na₈, Fe₈ and K/Ti, these magmas would necessitate other mixing ends in shallow crust except in upper mantle. The compositional diversity of melt inclusions in MORBs phenocrysts cannot always be used to indicate magma mixing and crystallization in shallow crust, and melt inclusions in high Mg^# olivine formed under mantle pressure must be excluded in study of the magma process at crustal level. This study shows that, in EPR, MORBs have experienced mixing of magmas formed by different melting degrees and depths in the mantle.     

An olivine-free mantle source of Hawaiian shield basalts

More than 50 per cent of the Earth's upper mantle consists of olivine and it is generally thought that mantle-derived melts are generated in equilibrium with this mineral. Here, however, we show that the unusually high nickel and silicon contents of most parental Hawaiian magmas are inconsistent with a deep olivine-bearing source, because this mineral together with pyroxene buffers both nickel and silicon at lower levels. This can be resolved if the olivine of the mantle peridotite is consumed by reaction with melts derived from recycled oceanic crust, to form a secondary pyroxenitic source. Our modelling shows that more than half of Hawaiian magmas formed during the past 1 Myr came from this source. In addition, we estimate that the proportion of recycled (oceanic) crust varies from 30 per cent near the plume centre to insignificant levels at the plume edge. These results are also consistent with volcano volumes, magma volume flux and seismological observations.     

Hydrous olivine unable to account for conductivity anomaly at the top of the asthenosphere

The oceanic asthenosphere is observed to have high electrical conductivity, which is highly anisotropic in some locations. In the directions parallel and normal to the plate motion, the conductivity is of the order of 10(-1) and 10(-2) S m(-1), respectively, which cannot be explained by the conductivity of anhydrous olivine. But because hydrogen can be incorporated in olivine at mantle pressures, this observation has been attributed to olivine hydration, which might cause anisotropically high conductivity by proton migration. To examine this hypothesis, here we report the effect of water on electrical conductivity and its anisotropy for hydrogen-doped and undoped olivine at 500-1,500 K and 3 GPa. The hydrous olivine has much higher conductivity and lower activation energy than anhydrous olivine in the investigated temperature range. Nevertheless, extrapolation of the experimental results suggests that conductivity of hydrous olivine at the top of the asthenosphere should be nearly isotropic and only of the order of 10(-2) S m(-1). Our data indicate that the hydration of olivine cannot account for the geophysical observations, which instead may be explained by the presence of partial melt elongated in the direction of plate motion.     

Survival times of anomalous melt inclusions from element diffusion in olivine and chromite

The chemical composition of basaltic magma erupted at the Earth's surface is the end product of a complex series of processes, beginning with partial melting and melt extraction from a mantle source and ending with fractional crystallization and crustal assimilation at lower pressures. It has been proposed that studying inclusions of melt trapped in early crystallizing phenocrysts such as Mg-rich olivine and chromite may help petrologists to see beyond the later-stage processes and back to the origin of the partial melts in the mantle. Melt inclusion suites often span a much greater compositional range than associated erupted lavas, and a significant minority of inclusions carry distinct compositions that have been claimed to sample melts from earlier stages of melt production, preserving separate contributions from mantle heterogeneities. This hypothesis is underpinned by the assumption that melt inclusions, once trapped, remain chemically isolated from the external magma for all elements except those that are compatible in the host minerals. Here we show that the fluxes of rare-earth elements through olivine and chromite by lattice diffusion are sufficiently rapid at magmatic temperatures to re-equilibrate completely the rare-earth-element patterns of trapped melt inclusions in times that are short compared to those estimated for the production and ascent of mantle-derived magma or for magma residence in the crust. Phenocryst-hosted melt inclusions with anomalous trace-element signatures must therefore form shortly before magma eruption and cooling. We conclude that the assumption of chemical isolation of incompatible elements in olivine- and chromite-hosted melt inclusions is not valid, and we call for re-evaluation of the popular interpretation that anomalous melt inclusions represent preserved samples of unmodified mantle melts.     

Stable structure of Zr_(49)Cu_(44)Al_7 metallic glass matrix composite with CuZr phase under high pressure up to 40.8 GPa

Ternary Zr49Cu44Al7 metallic glass matrix composite rods with CuZr nano-phase,exhibiting an elastic strain of 1.6% and a high strength of 1.78 GPa,have been manufactured. The structural evaluation of the ternary metallic glass matrix composite under high pressure has been investigated using angle dispersive X-ray diffraction with a synchrotron radiation source. The investigation shows that the amorphous matrix structure is stable under pressures up to 40.8 GPa at room temperature. No pressure induced CuZr n...     

Synthesis of boron-doped diamond with laser heated diamond anvil cell

Boron-doped diamond has been synthesized from graphite mixed with different ratio of B₄C at high pressure high temperature (HPHT) using laser heated diamond anvil cell. The starting composition was transformed to diamond compound at pressure ∼9 GPa, 2300–2400 K as indicated by the in-situ X-ray diffraction pattern with synchrotron radiation source. Raman spectrum of the recovered specimen from HPHT state confirmed that boron has been doped into diamond lattice.