The poisoning and regeneration effect of alkali metals deposed over commercial V2O5-WO3/TiO2 catalysts on SCR of NO by NH3

In this study, commercial V2O5-WO3/TiO2 catalysts were deactivated by loading with alkali metals （K and Na）. These catalysts were then regenerated by washing with either deionized water or 0.5 mol/L H2SO4 （through the ultrasonic-assisted method）. The samples used in this research were characterized by NH3-temperature programmed desorption （TPD）, and X-ray photoelectron spectroscopy （XPS）. Results showed that Na2O and KaO doping can poison the V2O5-WO3/TiO2 catalyst and that the poisoning effect of Na2O was stronger than that of KaO. However, the Na2O-loaded sample was easier to regenerate than the KaO-loaded sample. The surfaces of catalysts can be sulfated by washing with dilute sulfuric acid because strong acid sites adhere to the catalyst surface. SO42- could also promote catalyst activity. As indicated by the NH3-TPD findings, the deposition of Na2Oand K2O could also reduce the amount of desorbed ammonia and destabilize the acid sites, especially strong chemisorption sites. XPS results revealed that catalysts were deactivated by the decrease in the concentration of chemisorbed oxy- gen [the Oα（Oα ＋ Oβ） ratio]. In the Na2O-doped catalyst, much chemisorbed oxygen was lost （from 28.8 % to 10.6 %）. However, the decrease in the Oα（Oα ＋ Oβ） ratio was less significant in the K20-doped catalyst （from 28.8 % to 23.5 %）. Nonetheless, the binding energies of Ols broadened with respect to both high and low energy. Inparticular, the binding energy of chemisorbed oxygen increased from 531.5 to 531.8 eV.     

Research on Mineral Processing of Low Quality Kalium-Natrium Feldspar

In light of characteristic of low quality feldspar ores in Wanzai County, Jiangxi Province, steel ball was taken as grinding medium, and selective grinding could make impurity separate from feldspar effectively. Through the flow of flotation-desliming-high gradient magnetic separation, the feldspar Concentration 1 was obtained with the yield of 70.19 % ,containing Fe2O3 0. 17 % and TiO2 0.07 %. The feldspar Concentrate 1 could meet the quality requirement of high-grade construction ceramic. And the slime that was deslimed in the flow was also separated and recovered; the feldspar Concentration 2 was obtained with the yield of 13.18 %, containing Fe2O3 0.31% and TiO2 0.17 %. The feldspar Concentrate 2 can be used for raw material of low-end ceramic. And gangue, with the yield of 16.63 %, was thrown away in this flow, the separating efficiency was high. Employing this flow could also bring high economy benefit and low influence of pollution to environment.     

4 K high frequency pulse tube cryocooler used for terahertz space application

Terahertz(THz) frequency region, defined from0.1 to 10 THz, is an important frequency band for radio astronomy and atmospheric science. As NbN Superconductor-Insulator-Superconductor(SIS) mixers used for terahertz detection, which are studied by the Purple Mountain Observatory(PMO), Chinese Academy of Sciences(CAS), work at 8–10 K, and require condition of micro vibrations, its astronomical observation in aerospace is limited by suitable refrigeration method. 4 K high frequency pulse tube cryocooler developed by Key Laboratory of Space Energy Conversion Technologies(SECT), Technical Institute of Physics and Chemistry(TIPC), CAS, offers an opportunity for the application of SIS mixers. This article introduces the progress of the two-stage high frequency pulse tube cryocooler researched by TIPC. The cryocooler has reached a no load temperature of 4.5 K which is the lowest temperature for this kind of cryocooler reported so far. The successful coupling between the THz component and the high frequency pulse tube cryocooler lays a solid foundation for space detection in the terahertz band.     

Vegetation and climate change during Marine Isotope Stage 3 in China

Fossil pollen records from 45 sites across China were evaluated and synthesized to document Vegetation and climate change during Marine Isotope Stage 3 （MIS 3） at 60-27 ka and to understand the large-scale controls. During MIS3, vegetation type was dominantly forest in eastern China, forest steppe/meadow in the north and Tibetan Plateau, and steppe desert in northwestern arid China. We developed a semi-quantitative vegetation index to reflect change in plant abundance （by inferring the general climate conditions）, with a vegetation score from 1 to 3 based on the different vegetation types inferred from pollen data at individual sites at intervals of 2,000 years.The reconstructed vegetation index shows higher values during MIS 3, especially during the period 53-40 ka, than at the Last Glacial Maximum. Our results also suggest that climate on the basis of vegetation change was cooler and drier during MIS 3 than during the Holocene optimum; however, MIS 3 vegetation was probably similar to modern vegetation. The close relationship between vegetation change, insolation and Asian summer monsoon strength suggests that climate variations, probably in both temper- ature and precipitation, are the primary drivers of regional vegetation change. Additional well-dated, high-resolution palaeoclimate records from many locations across China will be needed to understand the vegetation change and climate forcings on millennial and centennial scales within MIS 3.     

Research and design of the main equipments and structure of Xiangjiaba shiplift

The type of pinion and rack vertical shiplifts has been developed in recent a couple of years in the construction of dams. But the design methods and methodologies have rarely been discussed in literature. The Xiangjiaba shiplift is the second shiplift of this type following the Three Gorges shiplift. Being aimed at the technological rationality of the design in synthetically considering security, economy and applicability, this paper presents the research results of some vital issues relating the design of the Xiangjiaba shiplift, including the determination of design water depth of ship chamber based on fluid numeral computation and physical model test, the optimum design of general layout of main equipments and the civil structure of the Xiangjiaba shiplift, the finite element method （FEM） analysis of stress, vibration modes and the buckling of ship chamber, antiseismic research and the design of structures and mechanisms of the shiplift and the optimum design of driving mechanisms. This research provides the theoretical basis for the design of the Xiangjiaba shiplift. The design principles and research methods are valuable for the design of the same type of shiplifts.     

The influence of molar ratios of Ce/Zr on the selective catalytic reduction of NOx with NH3 over Fe2O3-WO3/CexZrl-xO2 （0 〈 x 〈 1） monolith catalyst

A series of CexZrl_xO2 （0 ≤ x ≤ 1） with dif- ferent molar ratios of Ce/Zr were syhthesized via coprecip- itation method, and Fe2O3-WO3/CexZrl-xO2 monolithic catalysts were prepared, for selective catalytic reduction of nitrogen oxides by ammonia （NH3-SCR）. The structural properties and redox behavior of the catalysts were com- prehensively characterized by N2 physisorption, X-ray diffraction （XRD）, X-ray photoelectron spectra （XPS）, H2-temperature programmed reduction （H2-TPR） and activity measurement for NH3-SCR. The results showed that the NH3-SCR activities of the catalysts were gradually enhanced by increasing the molar ratios of Ce/Zr, especially the low- temperature catalytic activity and the reaction temperature window. Fe2O3-WO3/Ceo.68Zro.3202 monolithic catalyst presented the best NH3-SCR activity among the investigated catalysts, more than 90 % NOx could be removed in the temperature range of 247-454 ℃ on the catalyst under the gas hourly space velocities of 30,000 h- 1. And it always held more than 99 % N2 selectivity and less than 20 ppm （1 ppm =10-6 L/L ） N20 generation concentration between 200 and 500 ℃, the catalyst also displayed its strong resistance of H20 and SO2. Good textural and structural properties, more surface Fe, Ce and active oxygen were together contributed to the excellent NH3-SCR performance of Fe2O3-WO3/ Ce0.68Zr0.32O2 catalyst.     

Minimization of influence by the drooping eyelid in extracting pupil center for eye tracking systems

Precise pupil center detection is an important factor for gaze tracking in video-oculography （VOG） systems. Existing methods perform well to extract the features when the area of pupil in eye image is clear, whereas, interferences, such as eyelashes, corneal reflection etc., will lead to a low success rate. One main reason is the closure of eyelids. In this paper, a systemic 3D transformation algorithm is proposed to accurately ascertain the pupil center, in spite of the complicating factors mentioned above. Experiments show the good performance of our method. And the pupil center could be extracted accurately, even though only 25% of the pupil is visible.     

Observations of thermospheric vector wind over Yellow River Station during auroral substorm events

Strong disturbances associated with auroral substorms originate from the ionosphere-magnetosphere owing to the effects of the solar wind, and the wind field in the ionosphere is related to such substorm activity. Here, we describe the analysis of four auroral substorm events, for which we employed an all-sky Fabry-Perot interferometer to observe the two-dimensional horizontal wind field and combined the results with data from an all-sky charge-coupled device imager, a fluxgate magnetometer installed at Yellow River Station, and the Super Dual Auroral Radar Network. The results demonstrate that, during auroral substorms, the vector wind field is related closely to variations in the ion drift and geomagnetic field. Moreover, we observed a changing wind field of approximately 300 rn/s in response to variations in the electric and magnetic fields （likely caused by ion drag） and a disturbance of about 200 m/s that we attribute to the interaction of Joule heating and ion drag.     

Anomalous top-quark coupling effects in rare B and K decays

The Large Hadron Collider at CERN is performing direct searches for top-quark anomalous flavor-changing neutral current （FCNC） processes. However, these processes may be correlated closely with the low-energy rare B and K meson decays. In this paper, we review the anomalous top-quark coupling effects in these low-energy flavor transitions, summarize the flavor constraints and discuss their implications for direct detection of top-FCNC processes at the Large Hadron Collider.     

Study of engaged performance regulation in controlled transfer clutch of 4WD car based on genetic sliding mode control

This paper investigates an approach to improve the engagement quality of controlled transfer clutch mode in 4 wheel drive （WD） car from three considerations of reducing friction, smoothening responsiveness and alleviating jerk. The method utilizes an improved sliding mode control with genetic algorithm instead of simplified mode to determine appropriate values of parameters in control close-loop, The simulation results show that the method is effective for improving the engagement quality of coupling satisfying different design needs for 4WD car, as well as robustness even if input torque is changed at a certain range.     

Evaluation on Gambiered Guangdong Silk＇s Ecological Properties

To evaluate gambiered Guangdong silk＇s ecology properties, the raw materials ecology, production ecology and use ecology are analyzed; and the safety to human is tested according to GB/T18885 - 2002. Gambiered Guangdong silk is a kind of natural product. All its raw materials are reproducible and degradable natural resources, and it can decompose completely when being discarded. R is comfortable to wear, and easy to clean and dry. It is mainly manufactured by dip-dyeing in dye yam solution, and insolating under the burning sun. The production energy is solar, a kind of clean and reproducible energy. The production process is clean and environmental friendly. There is neither the utilization of synthetic dyestuff and chemical auxiliary, nor the discharge of environment pollutant, and even the dreg of dye yam is used as fuel. The safety test results show that pH value of water extract, heavy metal content （except for Pb content）, color fastness and odor meet the requirements of GB/T18885 - 2002 and Okeo-tex standard 100.     

Effect of strain rate on the compressive deformation behaviors of lotus-type porous copper

Lotus-type porous copper was fabricated by unidirectional solidification, and compressive experiments were subsequently conducted in the strain rate range of 10-3–2400 s-1 with the compressive direction parallel to the pores. A GLEEBLE-1500 thermal-mechanical simulation system and a split Hopkinson pressure bar (SHPB) were used to investigate the effect of strain rate on the compressive deformation behaviors of lotus-type porous copper. The influence mechanism of strain rate was also analyzed by the strain-controlling method and by high-speed photography. The results indicated that the stress-strain curves of lotus-typed porous copper consist of a linear elastic stage, a plateau stage, and a densification stage at various strain rates. At low strain rate (< 1.0 s-1), the strain rate had little influence on the stress-strain curves; but when the strain rate exceeded 1.0 s-1, it was observed to strongly affect the plateau stage, showing obvious strain-rate-hardening characteristics. Strain rate also influenced the densification initial strain. The densification initial strain at high strain rate was less than that at low strain rate. No visible inhomogeneous deformation caused by shockwaves was observed in lotus-type porous copper during high-strain-rate deformation. However, at high strain rate, the bending deformation characteristics of the pore walls obviously differed from those at low strain rate, which was the main mechanism by which the plateau stress exhibited strain-rate sensitivity when the strain rate exceeded a certain value and exhibited less densification initial strain at high strain rate.     

Thermoelectric properties of Al substituted misfit cobaltite Ca3（Co1-xAlx）4O9 at low temperature

Thermoelectric properties of Al substituted compounds Ca3（Co1-xAlx）4O9 （x=0, 0.03, 0.05）, prepared by a sol-gel process, have been investigated in the temperature range 305-20 K. The results indicate that after Al substitution for Co in Ca3（Co1-xAlx）4O9, the direct current electrical resistivity and thermopower increase due to the reduction of carrier concentration. Experiments show that Al substitution results in decreased lattice thermal conductivity. The figure of merit of temperature behavior suggests that Ca3（Co0.97Al0.03）4O9 would be a promising candidate thermoelectric material for high-temperature thermoelectric application.     

Equilibrium between titanium ions and high-purity titanium electrorefining in a NaCl-KCl melt

TiCl_x (x = 2.17) was prepared by using titanium sponge to reduce the concentration of TiCl₄ in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiCl_x melt was employed as the electrolyte, and two parallel crude titanium plates and one high-purity titanium plate were used as the anode and cathode, respectively. A series of electrochemical tests were performed to investigate the influence of electrolytic parameters on the current efficiency and quality of cathodic products. The results indicated that the quality of cathodic products was related to the current efficiency, which is significantly dependent on the current density and the initial concentration of titanium ions. The significance of this study is the attainment of high-purity titanium with a low oxygen content of 30×10-6.     

A 14.5Gb/s word alignment circuit in 0.18μm CMOS technology for high-speed SerDes

This paper presents a word alignment circuit for high speed SerDes system.By using pipeline structure and circuit optimization techniques,the speed of the aligner is increased,and its performance is improved further through adopting the full custom design method.The proposed word aligner has fabricated in 0.18μm CMOS technology with total area of 1.075 ×0.775mm~2￣ including I/O pad.Measurement results show that this circuit achieves the maximum data rate of 14.5Gb/s,while consuming a total power of 34.9mW from a 1.8V supply.     

Research and Practice of Dynamic Network Security Architecture for IaaS Platforms

Network security requirements based on virtual network technologies in IaaS platforms and corresponding solutions were reviewed.A dynamic network security architecture was proposed,which was built on the technologies of software defined networking,Virtual Machine(VM)traffic redirection,network policy unified management,software defined isolation networks,vulnerability scanning,and software updates.The proposed architecture was able to obtain the capacity for detection and access control for VM traffic by redirecting it to configurable security appliances,and ensured the effectiveness of network policies in the total life cycle of the VM by configuring the policies to the right place at the appropriate time,according to the impacts of VM state transitions.The virtual isolation domains for tenants’VMs could be built flexibly based on VLAN policies or Netfilter/Iptables firewall appliances,and vulnerability scanning as a service and software update as a service were both provided as security supports.Through cooperation with IDS appliances and automatic alarm mechanisms,the proposed architecture could dynamically mitigate a wide range of network-based attacks.The experimental results demonstrate the effectiveness of the proposed architecture.     

Crystal structures,antibacterial activity and thermal decomposition kinetics of lanthanide complexes with 4-chloro-2-methoxybenzoic acid and 1,10-phenanthroline

A series of lanthanide complexes [Ln(4-Cl-2-MOBA)3phen]2(Ln=Sm(1), Nd(2), Ho(3), Eu(4), Dy(5), and Tb(6); 4-Cl-2-MOBA=4-chloro-2-methoxybenzoate, phen=1,10-phenanthroline) were synthesized and characterized. The single-crystal X-ray diffraction demonstrates that 1–3 are isomorphous, which present dimeric structures with four 4-Cl-2-MOBA anions function as bridging ligands. Complexes 1 and 4–6 display their characteristic luminescence emission bands of central Ln3?ions. The heat capacities, the thermodynamic functions and the thermogravimetry–Fourier transform infrared spectra of gaseous products of complexes 1–6 were investigated.Their non-isothermal kinetics of the second decomposition stage was studied by the integral isoconversional non-linear method and Stark method. Furthermore, 1–6 exhibited excellent antibacterial activity against Candida albicans,Escherichia coli and Staphylococcus aureu.     

Key technologies of precision demolition blasting of ultra-long urban viaduct in complicated surroundings

The key technologies of precision blasting were put forward based on the characteristics of urban via- duct blasting demolition in complicated surroundings. Initial bending instability mechanics model of reinforcing steel bar frame of blasting fragmented pier and sequenced collapsed dynamic model were established for quanti- tative blasting design. Technologies of water pressure blasting were applied in multi-cell box girder fragmenta- tion. The detonating network of non-electric duplication crossover was adopted for the safety and reliability of ultra-long delay. The rationality of blasting scheme and parameters were validated by physical model test. Harm- ful effects were forecasted and controlled by integrated protective technologies. Specialization, cooperation, pre- cision, execution （SCPE） project management method was put forward for precision management. The key tech- nologies of precision demolition blasting can provide reference for similar proiects.     

Impact of gamma radiation and salinity on growth and K^＋/Na^＋ balance in two populations of Medicago sativa （L.） cultivar Gabbs

The perennial Medicago sativa cv. Gabes is widely grown on saline soils in Tunisian oases. Morphological and physiological analyses of two populations （Mareth and Gannouch） were conducted in order to study the effect of salinity and gamma radiation （350 Gy） interaction on two populations of this species. It has been shown that the two irradiated populations of Medicago sativa are fairly tolerant to salt at growth phase compared to the non-irradiated. Exposure to gamma irradiation （350 Gy）, alone or in combination with salt stress, increased significantly （p 〈 0.001） shoot number, stem height and chlorophyll b pigment especially for the Gannouch population, while no change occurred for the Mareth population. The presence of salt to 9 g/1 affected significantly the root biomass and induced a reduction of shoot development of both control and irradiated alfalfa populations. For all treatments, plants of two populations remained able to produce and to allocate dry matter to the different organs. The survey of Na^＋/K^＋ ratio showed that the growth of the aerial organs of two non-irradiated populations was at least determined by a selectivity in favour of the K^＋ ions （r^2 = 0.97 and r^2 = 0.59 for Mareth and Gannouch non-irradiated populations, respectively）. However, the rather weak correlation detected for the irradiated populations, particularly for the irradiated Gannouch, seems to be the consequence of the effect of irradiation that improved potassium availability, essential element for growth and development. Results also showed that the two irradiated populations, especially the Mareth, accumulated Na^＋ ions in its photosynthetic organs. This accumulation was associated with an improvement of foliar water content at a level of salinity around 5 g/1. Such a mechanism reflects probably an inclusive behaviour of the plants and a good aptitude to use the dominant ions （Na^＋） for the osmotic adjustment. However, the non-irradiated populations are unable to adjust their internal os     

Adaptive Neural Control for a Class of Low-triangular-structured Nonlinear Systems with H-∞ Performance Analysis

In this paper, a neural-network-based variable structure control scheme is presented for a class of nonlinear systems with a general low triangular structure. The proposed variable structure controller is proved to be Cl, thus can be applied for backstepping design, which has extended the scope of previous nonlinear systems in the form of strict-feedback and pure-feedback. With the help of neural network approximator, H-∞ performance analysis of stability is given. The effectiveness of proposed control law is verified via simulation.