Atomic packing and short-to-medium range order evolution of Zr-Pd metallic glass

A larger-scale Zr₇₀Pd₃₀ alloy system has been simulated using molecular dynamics (MD) to investigate structure evolution in Zr₇₀Pd₃₀ metallic glass. The simulated pair distribution function of Zr₇₀Pd₃₀ metallic glass agrees well with the experimental results. Voronoi polyhedron analysis indicates that the icosahedra are not randomly distributed in space, but form characteristic intercrossed icosahedral clusters with medium-range order. Intercrossed icosahedral clusters are the dominant local configurations in Zr₇₀Pd₃₀ metallic glass and probably cause the quasicrystalline phase discovered in Zr₇₀Pd₃₀ metallic glass.     

Atomic packing and short-to-medium range order evolution of Zr-Pd metallic glass

A larger-scale Zr70Pd30 alloy system has been simulated using molecular dynamics (MD) to investigate structure evolution in Zr70Pd30 metallic glass. The simulated pair distribution function of Zr70Pd30 metallic glass agrees well with the experimental results. Voronoi polyhedron analysis indicates that the icosahedra are not randomly distributed in space,but form characteristic intercrossed icosahedral clusters with medium-range order. Intercrossed icosahedral clusters are the dominant local configurations i...     

Ni-Hf非晶合金及其团簇式成分解析

Ni-Hf是一类重要的二元非晶形成体系,但其非晶形成能力较弱,最佳非晶成分尚不明确.本文利用团簇加连接原子模型,首先解析了二元深共晶点Ni65Hf35对应共晶相Ni7Hf3和Ni10Hf7的团簇结构,获得了可代表各自结构特征的主团簇;随后依据非晶合金的通用团簇式[团簇]（连接原子）1或3,设计出若干可能具有高非晶形成能力的合金成分.实验结果表明,急冷甩带后只有Ni71.43Hf28.57和Ni68.75Hf31.25两个成分点形成完全非晶,其中后者成分由团簇成分式[Ni-Ni7Hf5]Ni3描述,并具有最高的热稳定性（877K）和最低的液相线温度Tl（1482K）,被认为是Ni-Hf系中高非晶形成能力的成分点,其位于Ni65Hf35共晶点的富Ni侧,靠近共晶相Ni7Hf3.     

Zr基与Ti基非晶合金的不同划痕变形行为

采用痕法研究了Zr47.9Ti0.3Ni3.1Cu39.3Al9.4与Ti40Zr25Be30Cr5两种非晶合金的塑性变特征,考查了载荷与痕速度对塑性变特征的影响.结果表明两种铸态非晶合金样品的剪切带表现出同的特征：Ti非晶合金在痕两侧剪切带现分枝特征,随着载荷和痕速度的增加,出现多重分枝和混乱分特征;而Zr非晶合金的剪切带特征以一次剪切带为主,随载荷和痕速度增加,剪切带特征向单一、平滑趋势转变.进一研究了弛豫对Zr非晶合金痕变特征的影响,发现弛豫使Zr非晶合金剪切带向分枝特征转变.从自由体积观点探讨了两种合金中同剪切带特征的和演制.     

Formation and biocorrosion behavior of Zr-Al-Co-Nb bulk metallic glasses

Ni-and Cu-free Zr-Al-Co-Nb glassy alloys with different Nb and Co contents were synthesized by melt spinning and copper mold casting.The effects of Nb addition to partially replace Co in the Zr55Al20Co25 glassy alloy on the glass-forming ability,thermal properties,in-vitro biocorrosion behavior and surface wettability of the metallic glasses were investigated.Although addition of Nb up to 5 at.% slightly decreased the supercooled liquid region and the glass-forming ability(GFA),the alloys could be casted in a bulk glassy rod form with diameters up to 3mm.The Zr-Al-Co-Nb glassy alloys were spontaneously passivated with low passive current densities in phosphate buffered saline and Hanks’ solution.Substitution of "toxic" Co by Nb is effective in improved the corrosion resistance of the Zr-Al-Co glassy alloy.Water contact angle measurements showed that Nb addition increased the hydrophilicity of the glassy alloys,which may enhance cell adhesion of the alloys in biomedical applications.     

Deformation behavior during nanoindentation in Ce-based bulk metallic glasses

Recently, bulk metallic glasses (BMGs) have at- tracted a great deal of attention due to their extremely high strength, improved wear resistance and excellent corrosion resistance[1-7]. However, it is known that their structural applications are currently…     

Effect of Ni addition on the glass-forming ability and soft-magnetic properties of FeNiBPNb metallic glasses

The effect of Ni addition on the glass-forming ability (GFA) and soft-magnetic properties of an (Fe1-xNix)75.5B14.5P7Nb3 (x=0-0.6) alloy system were investigated. We found that the addition of Ni was effective in allowing the alloy to approach a eutectic point as well as increasing the thermal stability of the supercooled liquid. By increasing the amount of Ni,the supercooled liquid region (ΔTx),the reduced glass transition temperature Trg (Tg/Tl) and the Y parameter [Tx/(Tg+Tl)] increased from 49 to 75 K,0...     

Zr63.36Cu14.52Ni10.12Al12非晶合金的大塑性与尺寸效应

用铜模吸铸法制备了直径为3,4和6mm的Zr63.36Cu14.52Ni10.12Al12阶梯形圆棒试样,研究了试样尺寸大小对室温塑性和强度的影响.结果表明：φ3mm试样的压缩屈服强度σs为1740.6MPa,极限强度σmax为2030.7MPa,断裂强度σcf为1510.5MPa,塑性应变εp为20.6%,表现出比较大的塑性,存在明显的加工硬化现象;φ4mm试样塑性应变εp为2.6%,屈服强度σs为1748.5MPa,断裂强度σcf为1856.6MPa;φ6mm试样塑性应变φp为0.2%,断裂强度σcf为1221.3MPa.该合金的压缩塑性应变随着块体非晶合金直径的增大而减小,存在明显的尺寸效应,尺寸效应与非晶合金的自由体积有关,冷却速率决定非晶合金中自由体积分数,试样尺寸越小,冷却速率就越大,凝固过程形成的自由体积分数越大,大的自由体积分数促进压缩过程多重剪切带的形成从而有利于塑性的提高.     

Effect of Sn addition on the glass-forming ability and mechanical properties of Ni-Nb-Zr bulk metallic glasses

The effect of tin (Sn) addition on the glass forming ability (GFA) and mechanical properties of the Ni-Nb-Zr ternary alloy system has been studied. The addition of Sn improves the GFA; Ni61Nb35.5-xZr3.5Snx (in at.%) alloys with x=1 can be cast into amorphous samples at least 3 mm in diameter using a copper mold injection-casting method. The critical size for glass formation decreases to 2 mm when x=5 because Ni2SnZr phase precipitates readily. The addition of Sn is also effective in enhancing the stability ...     

Correlation of mechanical properties in bulk metallic glasses with ~（27）Al NMR characteristics

We report 27Al NMR and magnetic susceptibility measurements of Zr and ZrHf-based bulk metallic glasses (BMGs). 27Al NMR Knight shift shows that there exists a clear correlation between the local electronic properties at Al sites and mechanical properties. In addition,magnetic susceptibility measurements also provide clues on the influence of the electronic states,especially the strong influence of d-orbital characteristics on the mechanical properties of toughness and hardness.     

微波消解-火焰原子吸收法测定傣药铁刀木叶中5种金属元素

采用微波密闭消解系统对傣药铁刀木(Cassia siamea)叶进行消解,在最佳工作条件下使用火焰原子吸收分光光度计,并用标准曲线法测定铁刀木叶中钙、铜、锰、钠、镁5种金属元素的含量.实验表明,5种金属元素的含量有所不同,钙的含量最高,铜的含量最低.方法检出限均小于0.003 5μg/mL,加标回收率在96.28%～102.8%之间,相对偏差RSD≤2.13%,结果表明实验准确度和精密度符合实验要求,也为傣药铁刀木叶的有效成分研究提供一定的科学依据.     

非晶合金短程序研究与回火条件的选取

用核磁共振和穆斯堡尔效应配合研究了Ｆｅ８４Ｂ１０Ｃ６非晶合金的短程序。探讨了用回火非晶合金来研究短程序时的最佳热处理条件。结果表明，在淬态非晶合金中存在体心四方的Ｆｅ３Ｂ和正交型的Ｆｅ３Ｂ两种短程序。当用晶化方法来研究非晶合金的短程序时，推荐采用较低的回火温度（略高於非晶合金的晶化开始温度）和短的回火时间。     

磺酸盐驱油体系在多孔隙砂岩中的滞留与吸附损耗

采用两相滴定法分别考察磺酸盐驱油剂在砂岩表面的吸附损失及在多孔隙砂岩中的驱动损耗。结果表明:磺酸盐类驱油剂在砂岩表面的吸附损失主要与砂岩的表面积正相关;在驱动过程中,多孔隙介质的孔隙体积及孔喉结构是造成驱油剂滞留损失的主要原因;在砂岩表面的吸附及在多孔隙介质中的滞留都会使驱油剂在溶液中的有效质量浓度急剧减小;通过组分间的增溶作用,增加磺酸盐驱油剂在水相中的溶解性能,减少溶液中游离分子的数量,能够降低磺酸盐驱油剂的损失。     

中日手语手指语、词汇构成和句式表达的比较

通过对中日手语的界定,分析了两国手语在手指语、词汇构成、句式表达等方面的异同点,便于学习者理解和掌握中日手语的基本知识,对中日两国聋人之间的沟通和交流起到促进作用。     

浅谈大地选煤厂分选粒级及选煤方法的确定

根据霍州煤电集团大地煤业有限公司矿井选煤厂的煤源及煤质,确定其选煤厂的分选粒级及选煤方法为：200mm～50mm原煤采用重介浅槽分选机分选,50mm～1mm原煤采用重介旋流器分选,1mm～0.25mm原煤采用TBS粗煤泥分选机分选,-0.25mm煤泥采用加压过滤机脱水回收。     

论社会转型视野下壮族政治伦理研究之困境

中国的社会转型期可以划分为短时段、中时段和长时段。不同时间段的社会转型都给壮族政治伦理的研究带来了一定的困境。这种困境主要表现为三方面：不同语境下不同问题与逻辑如何对接;外来理论方法如何与壮族思维方式契合;如何以现代概念诠释壮族政治伦理。     

西湖凹陷平湖构造带地层压力特征及与油气分布的关系

东海陆架盆地西湖凹陷平湖构造带古近纪平湖组普遍发育异常压力,探讨地层高压发育的特征及其与油气分布的关系,旨在为油气勘探提供地质依据。以声波时差资料为基础,结合测井、地质、地化及油气测试资料,利用Bowers法计算单井地层压力,恢复平湖构造带单井压力剖面,以实测地层压力结果为约束,分析地层压力的分布特征。认为该构造带异常高压主要分布在埋藏较深的平湖组,随深度增加,高压幅度呈阶梯状增大;平湖构造带不同构造单元高压顶界面的深度具有明显差异,从平中区向平北区高压异常顶界面有变深的趋势,其中平中区为3.3km,平北区为3.7km。压力场的纵向叠置决定了油气的分布,高压发育与油气层分布的耦合关系分为4种类型:双封闭高压型、双封闭压力过渡型、单封闭压力过渡型、单封闭常压型,其中以双封闭压力过渡型和单封闭常压型为主。单封闭常压带、双封闭压力过渡带和双封闭高压带的顶部为油气的有利聚集区。     

川中地区香四段气水分布特征及成因机理

川中地区上三叠统香溪群第四段(香四段)为具低孔、低渗的致密碎屑岩储层.香四段气水层集中发育于中下部,气水分布态势严格受岩性控制,构造起伏对气水分布起辅助作用,非常规岩性-构造气藏与岩性气藏并存.气水分布关系因所处区域位置或构造带不同而有明显差异,相对稳定的斜坡区有利于岩性圈闭聚气成藏,而局部构造高部位有利于岩性-构造圈闭聚气成藏.     

佛山市区大气降水pH值的时空分布及酸雨成因研究

通过分析佛山市区5个测点2000～2002年大气降水的监测数据，并结合历史资料。对大气降水pH值的时空分布及酸雨成因进行了研究。在此基础之上，提出了防治酸雨污染的对策建议。     

塔南凹陷南屯组近岸水下扇沉积特征及有利含油相带分析

综合利用地震、测井、岩心等资料,对塔南凹陷南屯组近岸水下扇的沉积特征、展布、演化及有利含油相带进行研究。结果表明:本区近岸水下扇可识别出3种亚相、4种微相,不同相带间沉积特征差异显著;近岸水下扇集中发育于凹陷东部控盆断裂的下降盘,在多期扇体叠置连片下,形成了东南、东北两套扇裙,其展布、演化具有南北各自连片,扇裙先盛后衰的特点,但受控盆断裂幕式活动和东南、东北物源供给差异的影响,东南扇群的发展和消亡均略早于东北扇群;中扇辫状沟道储层物性及含油气性最好,主要发育中低孔储层,但不同位置及埋深储层渗透率差异较大,很难形成大面积连片的优质储层,因此本区近岸水下扇沉积主要发育个体规模相对较小却数量众多的岩性油气藏和构造-岩性复合油气藏。