共查询到20条相似文献,搜索用时 62 毫秒
1.
利用酚差基封端的聚砜和二氯封端、含Si-H功能键的硅氧烷低体合成交替偶联嵌段共聚物。由于Si-H键在碱性介质中不稳定,二氯封端的聚硅氧烷被选作嵌段基元。所得聚合物用IR、H^1NMR、GPS和TEM作了表征,结果表明嵌段合成是成功的。通过Si-G键与烯键的加成反应在该共聚物的分子链上引入了碱性侧基而得到一系列嵌段型高分子配体。 相似文献
2.
在Na2O-(CTMA)2O-SiO2-H2O与(TMA)2O-(CTMA)2O-SiO2-H2O体系中分别合成了不同硅铝比及全硅MCM-41分子筛作品,考察了诸因素对晶比过程的影响,同时对其酸性、热稳定性和催化性能进行了表征. 相似文献
3.
分析了金属间化合物α-(AlMnSi)的空间结构,并运用余瑞璜的固体与分子经验电子论中的键距差分析法计算了α-(AlMnSi)的理论键距及其各种原子所选取的杂阶.在此基础上计算出α-(AlMnSi)中Mn原子键络的共价键键能. 相似文献
4.
相变调温PET-PEG嵌段共聚物的性能和结构的研究 总被引:7,自引:0,他引:7
以酯交换法合成了一系列的PFT-PEG(聚对苯二甲酸乙二醇酯-聚乙二醇)嵌段共聚物,经DSC测试证明它们具有不同的常温相变温区,且常温相变来自于嵌段共聚物中的PEG链段。用FTIR,^1H—NMR表征了共聚物的结构,结果表明其是以PET硬链段封端的多嵌段共聚物,PEG软链段保有一定长度,PEG软链段含量受所投原料比例影响。通过改变加入的PEG相对分子质量和PEG/DMT投料比可控制PET-PEG嵌段共聚物相转变的热性能。 相似文献
5.
牛桂玲 《北京理工大学学报》1998,18(3):375-379
目的用裂解气相色谱/质谱法(PGC/MS)鉴定环氧乙烷-环氧丙烷三嵌段共聚物.方法用裂解气相色谱(PGC)法及裂解气相色谱/质谱(PGC/MS)法分别对聚环氧乙烷、聚环氧丙烷和环氧乙烷-环氧丙烷三嵌段共聚物在合适的色谱及质谱条件下进行分析.结果与结论样品在质谱分析的总离子流图16.13min处给出了聚环氧乙烷、聚环氧丙烷中没有的混杂二聚体,它们是这类三嵌段共聚物在高温下裂解产生的特征峰.并推断了这两种混杂二聚体在质谱中的断裂方式. 相似文献
6.
1,2-二环戊二烯基四甲基二硅烷与丁基锂作用生成[四甲基二硅撑]双(环戊二烯基负离子盐),后者随即与六羰基钨反应形成1,1-[四甲基二硅撑]双[环戊二烯基三羰基钨负离子盐],(Me2SiSiMe2)·[Cp′(CO)3W-]2·2Li+(I).(I)分别与六种卤化物反应,生成在钨原子上引入取代基的产物:(Me2SiSiMe2).[Cp′W(CO)3R]2,(R:Me,C2H5,2;PhCH2,3;CH2COOC2H5,4;CH3CO,5;P3hSn,6).(I)用醋酸处理后,随即分别与CCl4,NBS及I2作用,生成相应的钨卤化物,(Me2SiSiMe2)[Cp′W(CO)3X]2,(X:C1,8;Br,9;I,10),(I)与Fe3+/H3O+作用发生氧化偶联,生成双核W-W键产物(Me2SiSiMe2)[Cp′W(CO)3]2,11.(Cp′=C5H4) 相似文献
7.
研究了各种合成聚己内酰胺- 聚芳酰胺- 聚己内酰胺三嵌段共聚物的方法. 采用高温溶液直接缩聚法, 合成了具有不同长度的聚己内酰胺链段和聚对苯二甲酰对苯二胺链段的三嵌段共聚物, 并对这些三嵌段共聚物进行了表征. 相似文献
8.
MCM—41分子筛的合成与表征 总被引:1,自引:0,他引:1
在Na2O-(CTMA)2O-SiO2-H2O与(TMA)2O-(CTMA)2O-SiO2-H2O体系中分别合成了不同硅铝比及全硅MCM-41分子筛样品,考察了诸因素对晶化过程的影响,同时对其酸性,热稳定性和催化性能进行了表征。 相似文献
9.
溶胶-凝胶法制备TEOS-PDMS杂交材料 总被引:1,自引:0,他引:1
以羟基封端的聚二甲基硅氧烷(PDMS)低聚物为有机组分,以四乙氧基硅烷(TEOS)为无机原料,用溶胶-凝胶法制备了TEOS-PDMS有机/无机杂交材料。研究了材料的机械性能和动态力学行为。所得材料柔软透明,与纯的溶胶-凝胶玻璃差别很大,拉伸强度0.5~1.0MPa,极限伸长率可达7%,动态力学曲线显示有机物PDMS均匀分散在SiO_2无机网络中,没有出现相分离。 相似文献
10.
TS—1沸石合成过程中模板剂用量对钛进入骨架的影响 总被引:2,自引:1,他引:1
郭新闻 《大连理工大学学报》1998,38(3):354-358
以TPABr为模板剂、NH3.H2O为碱源,水热条件下合成了TS-1沸石,采用XRD、IR、UV-Vis、^29SiCPMASNMR、^27AlCMASNMR、^13CCPMASNMR等表征手段详细研究了模板剂不同用量对钛进入骨架的影响。 相似文献
11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness. 相似文献
12.
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly. 相似文献
13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。 相似文献
14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death. 相似文献
15.
Miao Maosheng 《华南师范大学学报(自然科学版)》2014,(6)
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula- 相似文献
16.
Yang Weitao 《华南师范大学学报(自然科学版)》2014,46(6):137-138
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re- 相似文献
17.
Bernard Kirtman 《华南师范大学学报(自然科学版)》2014,(6)
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that 相似文献
18.
《上海师范大学学报(自然科学版)》2014,(5):550
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with 相似文献
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20.
《吉林大学学报(理学版)》2014,(5):1105
<正>"Journal of Jilin University(Science Edition)"is a comprehensive academic journal in the fields of science sponsored by Jilin University and administrated by the Ministry of Education of the Peoples Republic of China.The journal started publication in 1955.The original name at starting publication was"Journal of Natural Science of Northeast People University",which was changed into"Acta Scientiarum Naturalium Universitatis Jilinensis"in 1958 owing to the name change of the university.The present journal name has 相似文献