Taking up statistical thermodynamics: Equilibrium fluctuations and irreversibility

The microscopic explanation of the physical phenomena represented by a macroscopic theory is often cast in terms of the reduction of the latter to a more fundamental theory, which represents the same phenomena at the microscopic level, albeit in an idealized way. In particular, the reduction of thermodynamics to statistical mechanics is a much discussed case-study in philosophy of physics. Based on the Generalized Nagel–Schaffner model, the alleged reductive explanation would be accomplished if one finds a corrected version of classical thermodynamics that can be strictly derived from statistical mechanics. That is the sense in which, according to Callender (1999, 2001), one should not take thermodynamics too seriously. Arguably, the sought-after revision is given by statistical thermodynamics, intended as a macroscopic theory equipped with a probabilistic law of equilibrium fluctuations. The present paper aims to evaluate this proposal. The upshot is that, while statistical thermodynamics enables one to re-define equilibrium so as to agree with Boltzmann entropy, it does not provide a definitive solution to the problem of explaining macroscopic irreversibility from a microscopic point of view.     

The third law in Newton’s Waste book (or, the road less taken to the second law)

On the basis of evidence drawn from the Waste book, Westfall and Nicholas have argued that Newton arrived at his second law of motion by reflecting on the implications of the first law. I analyze another argument in the Waste book which reveals that Newton also arrived at the second law by another very different route. On this route, it is the consideration of the third law and the principle of conservation of motion—and not the first law—that prompts Newton to formulate the second law. The existence of these two routes is significant because each employs a distinct kind of reasoning about forces. Whereas the Nicholas-Westfall route via the principle of inertia bears the mark of Descartes’s influence, the alternative route proceeds from the action-reaction principle, which is widely regarded as an original Newtonian contribution to mechanics. In the course of exploring this alternate route to the second law, the origins and justification of the third law are examined.     

The quantitative content of statistical mechanics

I give a brief account of the way in which thermodynamics and statistical mechanics actually work as contemporary scientific theories, and in particular of what statistical mechanics contributes to thermodynamics over and above any supposed underpinning of the latter׳s general principles. In doing so, I attempt to illustrate that statistical mechanics should not be thought of wholly or even primarily as itself a foundational project for thermodynamics, and that conceiving of it this way potentially distorts the foundational study of statistical mechanics itself.     

The five problems of irreversibility

Thermodynamics has a clear arrow of time, characterized by the irreversible approach to equilibrium. This stands in contrast to the laws of microscopic theories, which are invariant under time-reversal. Foundational discussions of this “problem of irreversibility” often focus on historical considerations, and do therefore not take results of modern physical research on this topic into account. In this article, I will close this gap by studying the implications of dynamical density functional theory (DDFT), a central method of modern nonequilibrium statistical mechanics not previously considered in philosophy of physics, for this debate. For this purpose, the philosophical discussion of irreversibility is structured into five problems, concerned with the source of irreversibility in thermodynamics, the definition of equilibrium and entropy, the justification of coarse-graining, the approach to equilibrium and the arrow of time. For each of these problems, it is shown that DDFT provides novel insights that are of importance for both physicists and philosophers of physics.     

Genesis of Karl Popper's EPR-like experiment and its resonance amongst the physics community in the 1980s

I present the reconstruction of the involvement of Karl Popper in the community of physicists concerned with foundations of quantum mechanics, in the 1980s. At that time Popper gave active contribution to the research in physics, of which the most significant is a new version of the EPR thought experiment, alleged to test different interpretations of quantum mechanics. The genesis of such an experiment is reconstructed in detail, and an unpublished letter by Popper is reproduced in the present paper to show that he formulated his thought experiment already two years before its first publication in 1982. The debate stimulated by the proposed experiment as well as Popper's role in the physics community throughout 1980s is here analysed in detail by means of personal correspondence and publications.     

Quantum decoherence and the approach to equilibrium (II)

In a previous paper [Hemmo, M & Shenker, O (2003). Quantum decoherence and the approach to equilibrium I. Philosophy of Science, 70, 330–358] we discussed a recent proposal by Albert [(2000). Time and chance. Cambridge, MA: Harvard University Press. Chapter 7] to recover thermodynamics on a purely dynamical basis, using the quantum theory of the collapse of the quantum state of [Ghirardi, G, Rimini, A and Weber, T., (1986). Unified dynamics for microscopic and macroscopic systems. Physical Review, D 34, 470–479]. We proposed an alternative way to explain thermodynamics within no collapse interpretations of quantum mechanics. In this paper some difficulties faced by both approaches are discussed and solved: the spin echo experiments, and the problem of extremely light gases. In these contexts, we point out several ways in which the above quantum mechanical approaches as well as some other classical approaches to the foundations of statistical mechanics may be distinguished experimentally.     

The double transfer of thermodynamics: From physics to chemistry and from Europe to America

The aim of this study is twofold: to explore, first, the influence of the intellectual and social conditions on the transfer of thermodynamics to chemistry and thereby the making of chemical thermodynamics, and second, the way that this knowledge was transferred from Europe to America. Consequently, it is of interest to examine the methodological approaches used by physicists and chemists to transfer thermodynamics to chemistry, to evaluate the potential of this science to offer solutions to existing chemical problems, and to discuss the attitude of the scientific community towards these new ideas. The development of chemical thermodynamics in America followed a different route compared to the European experience. Although it was transferred from Europe, it had distinctive characteristics imposed by a different traditional, intellectual and social milieu. This study focuses on the content of the transferred knowledge to America and the direction that this knowledge assumed by the American scientists. As a paradigm, the chemical thermodynamics of Gilbert Newton Lewis will be considered.     

The case for black hole thermodynamics part II: Statistical mechanics

I present in detail the case for regarding black hole thermodynamics as having a statistical-mechanical explanation in exact parallel with the statistical-mechanical explanation believed to underlie the thermodynamics of other systems. (Here I presume that black holes are indeed thermodynamic systems in the fullest sense; I review the evidence for that conclusion in the prequel to this paper.) I focus on three lines of argument: (i) zero-loop and one-loop calculations in quantum general relativity understood as a quantum field theory, using the path-integral formalism; (ii) calculations in string theory of the leading-order terms, higher-derivative corrections, and quantum corrections, in the black hole entropy formula for extremal and near-extremal black holes; (iii) recovery of the qualitative and (in some cases) quantitative structure of black hole statistical mechanics via the AdS/CFT correspondence. In each case I briefly review the content of, and arguments for, the form of quantum gravity being used (effective field theory; string theory; AdS/CFT) at a (relatively) introductory level: the paper is aimed at readers with some familiarity with thermodynamics, quantum mechanics and general relativity but does not presume advanced knowledge of quantum gravity. My conclusion is that the evidence for black hole statistical mechanics is as solid as we could reasonably expect it to be in the absence of a directly-empirically-verified theory of quantum gravity.     

Classes of Copenhagen interpretations: Mechanisms of collapse as typologically determinative

The Copenhagen interpretation of quantum mechanics is the dominant view of the theory among working physicists, if not philosophers. There are, however, several strains of Copenhagenism extant, each largely accepting Born's assessment of the wave function as the most complete possible specification of a system and the notion of collapse as a completely random event. This paper outlines three of these sub-interpretations, typing them by what the author of each names as the trigger of quantum-mechanical collapse. Visions of the theory from von Neumann, Heisenberg, and Wheeler offer different mechanisms to break the continuous, deterministic, superposition-laden quantum chain and yield discrete, probabilistic, classical results in response to von Neumann's catastrophe of infinite regress.     

Experimental : The double standard in the quantum-information approach to the foundations of quantum theory

Among the alternatives of non-relativistic quantum mechanics (NRQM) there are those that give different predictions than quantum mechanics in yet-untested circumstances, while remaining compatible with current empirical findings. In order to test these predictions, one must isolate one's system from environmental induced decoherence, which, on the standard view of NRQM, is the dynamical mechanism that is responsible for the ‘apparent’ collapse in open quantum systems. But while recent advances in condensed-matter physics may lead in the near future to experimental setups that will allow one to test the two hypotheses, namely genuine collapse vs. decoherence, hence make progress toward a solution to the quantum measurement problem, those philosophers and physicists who are advocating an information-theoretic approach to the foundations of quantum mechanics are still unwilling to acknowledge the empirical character of the issue at stake. Here I argue that in doing so they are displaying an unwarranted double standard.     

Interactions between mechanics and differential geometry in the 19th century

Conclusion 79. This study of the interaction between mechanics and differential geometry does not pretend to be exhaustive. In particular, there is probably more to be said about the mathematical side of the history from Darboux to Ricci and Levi Civita and beyond. Statistical mechanics may also be of interest and there is definitely more to be said about Hertz (I plan to continue in this direction) and about Poincaré's geometric and topological reasonings for example about the three body problem [Poincaré 1890] (cf. also [Poincaré 1993], [Andersson 1994] and [Barrow-Green 1994]). Moreover, it would be interesting to find out how the 19^th century ideas discussed here influenced the developments in the 20^th century. Einstein himself is a hotly debated case.Yet, despite these shortcommings, I hope that this paper has shown that the interactions between mechanics and differential geometry is not a 20^th century invention. Klein's view (see my Introduction) that Riemannian geometry grew out of mechanics, more specifically the principle of least action, cannot be maintained. On the other hand, when Riemannian geometry became known around 1870 it was immediately used in mechanics by Lipschitz. He began a continued tradition in this field, which had several elements in common with the new view of mechanics conceived by the physicists and explicitly carried out by Hertz.Before 1870 we found only scattered interactions between differential geometry and mechanics and only direct ones for systems of two or three degrees of freedom. For more degrees of freedom the geometrical ideas were in some interesting cases taken over by analogy, but these analogies did not lead to formal introduction of geometries of more than three dimensions.     

Vital Instability: Life and Free Will in Physics and Physiology, 1860–1880

During the period 1860–1880, a number of physicists and mathematicians, including Maxwell, Stewart, Cournot and Boussinesq, used theories formulated in terms of physics to argue that the mind, the soul or a vital principle could have an impact on the body. This paper shows that what was primarily at stake for these authors was a concern about the irreducibility of life and the mind to physics, and that their theories can be regarded primarily as reactions to the law of conservation of energy, which was used among others by Helmholtz and Du Bois-Reymond as an argument against the possibility of vital and mental causes in physiology. In light of this development, Maxwell, Stewart, Cournot and Boussinesq showed that it was still possible to argue for the irreducibility of life and the mind to physics, through an appeal to instability or indeterminism in physics: if the body is an unstable or physically indeterministic system, an immaterial principle can act through triggering or directing motions in the body, without violating the laws of physics.     

The case for black hole thermodynamics part I: Phenomenological thermodynamics

I give a fairly systematic and thorough presentation of the case for regarding black holes as thermodynamic systems in the fullest sense, aimed at readers with some familiarity with thermodynamics, quantum mechanics and general relativity but not presuming advanced knowledge of quantum gravity. I pay particular attention to (i) the availability in classical black hole thermodynamics of a well-defined notion of adiabatic intervention; (ii) the power of the membrane paradigm to make black hole thermodynamics precise and to extend it to local-equilibrium contexts; (iii) the central role of Hawking radiation in permitting black holes to be in thermal contact with one another; (iv) the wide range of routes by which Hawking radiation can be derived and its back-reaction on the black hole calculated; (v) the interpretation of Hawking radiation close to the black hole as a gravitationally bound thermal atmosphere. In an appendix I discuss recent criticisms of black hole thermodynamics by Dougherty and Callender. This paper confines its attention to the thermodynamics of black holes; a sequel will consider their statistical mechanics.     

Physics from Fisher information

B. R. Frieden uses a single procedure, called extreme physical information, with the aim of deriving ‘most known physics, from statistical mechanics and thermodynamics to quantum mechanics, the Einstein field equations and quantum gravity’. His method, which is based on Fisher information, is given a detailed exposition in this book, and we attempt to assess the extent to which he succeeds in his task.     

Gibbs, Einstein and the Foundations of Statistical Mechanics

It is generally accepted that, around the turn of the century, GIBBS and EINSTEIN independently developed two equivalent formulations of statistical mechanics. GIBBS version is taken as genuine and rigorous, while EINSTEINs, despite some features which are characteristic of him, is usually considered a not totally satisfactory attempt. It will be shown in the present work that such a picture is oversimplified and requires further nuancing. In fact, there are significant differences, with important implications which have not been sufficiently examined, between the two formulations. Several issues relating to the impact of the two versions will also be addressed. (Received April 4, 1998)     

Theories of Newtonian gravity and empirical indistinguishability

In this essay, I examine the curved spacetime formulation of Newtonian gravity known as Newton–Cartan gravity and compare it with flat spacetime formulations. Two versions of Newton–Cartan gravity can be identified in the physics literature—a “weak” version and a “strong” version. The strong version has a constrained Hamiltonian formulation and consequently a well-defined gauge structure, whereas the weak version does not (with some qualifications). Moreover, the strong version is best compared with the structure of what Earman (World enough and spacetime. Cambridge: MIT Press) has dubbed Maxwellian spacetime. This suggests that there are also two versions of Newtonian gravity in flat spacetime—a “weak” version in Maxwellian spacetime, and a “strong” version in Neo-Newtonian spacetime. I conclude by indicating how these alternative formulations of Newtonian gravity impact the notion of empirical indistinguishability and the debate over scientific realism.     

The genesis of a mediaeval historian: Pierre Duhem and the origins of statics

Contrary to what might be expected given a religious or other motivation, Pierre Duhem's interest in mediaeval science was the result of his surprise encounter with Jordanus de Nemore while working on Les origines de la statique in the late autumn of 1903. Historical assumptions common among physicists at that time may explain this surprise, which occasioned a frantic search for more mediaeval precursors for Renaissance mechanics. It also raised serious historiographical problems that threatened even his methodological views, until they were resolved in his To save the phenomena of 1908.     

A simplified genesis of quantum mechanics

The bewildering complexity of the history of quantum theory tends to discourage its use as a means to understand or teach the foundations of quantum mechanics. The present paper is an attempt at simplifying this history so as to make it more helpful to physicists and philosophers. In particular, Heisenberg's notoriously difficult derivation of the fundamental equations of quantum mechanics, or later derivations of its statistical interpretation are replaced with shorter and more direct arguments to the same purpose. As the implied amputations and distortions do not imply major anachronisms, they should facilitate the grasping of the main historical steps without excluding a reasonable assessment of their historical or logical necessity.