首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
The aggregation behavior of a substituted fullerene compound, 1-benzyl-2-hydro[60]fullerene (C60-Be), in Z-type ultrathin ordered (e.g. LB) multilayers has been studied by UV-vis absorption, steady state and time-resolved fluorescence spectroscopies. The LB multilayers of pure C60-Be showed J-aggregate formation, characterized by a large red-shift of two absorption peaks (ΔE∼2 098 cm1 from 260→275 nm and ΔE∼1 076 cm-1 from 328→340 nm, respectively). The main fluorescence emission bands were found at 710, 646, 603, 600 and 595 nm for pure (C60-Be, mixed C60-Be (molar percentage 50%, 25% and 20%. respectively) multilayers and monomeric C60-Be in solution, respectively. The aggregates were dissociated by mixing with some inert materials. The fluorescence decay profiles of C60-Be, mixed C60-Be (molar percentage 50%, 25% and 20%, respectively) in LB films could be best-fitted by using a bi-exponential decay model.  相似文献   

2.
The photoluminescence quenching behaviors of ^5D3-^7Fj and ^5D4-^7Fj (J = 0—6) transitions of Tb^3+ in YBO3:Tb under 130—290 nm excitation were systematically investigated. The results revealed that the quenching concentrations of both ^5D3-^7Fj and ^5D4-^7Fj transitions of Tb^3+ in YBO3:Tb were mainly dependent on excitation wavelength. Particularly, the quenching concentrations of ^5D4-^7Fj transitions of Tb^3+ under 130—290 nm excitation were correlated with excitation bands of YBO3:Tb. The quenching concentrations of ^5D3-^7Fj transitions remained at low concentration (2%) under 186—290 nm excitation and then increased gradually with energy of incoming excitation photon when excited at 130—186 nm. This dependence should be involved in their excitation mechanisms and quenching pathway in particular excitation region.[第一段]  相似文献   

3.
The relaxation of the highly vibrationally excited CO (v = 1–8) by CO2 is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr3 with O2 generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO2 molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (1014 cm3 · molecule−1 · s−1), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO2. For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u3 mode of CO2 For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u1 mode of CO2.  相似文献   

4.
A 5.3 m lake core was drilled in Baahar Nuur Lake in the Ordos Plateau, and measurements of meangrain size, organic δ 13C (δ 13Corg), organic carbon content (TOC), C/N, carbonate content, carbonate δ 13C(δ 13Ccar) and δ 18O (δ 18Ocar) were conducted for retrieving the Holocene chronosequence of climaticchanges based on 15 AMS 14C dates. The record documented four major stages of climate change inthe Ordos Plateau: (IV) a cold and dry condition before ~7.65 14C ka BP; (III) a warm and humid stagebetween ~7.65 and ~5.40 ka BP; (II) a generally drier and cooler climate since ~5.40 ka BP with twohumid events occurring from ~4.70 to ~4.60 ka BP and from ~4.20 to ~3.70 ka BP, and (I) a dry climatecharacterized by complete desiccation of the lake after 3.70 ka BP. Stage III can be further divided intothree sub-stages: (IIIa) a warm and humid episode from ~7.65 to ~6.70 ka BP, (IIIb) a warm and relativelydry episode from ~6.70 to ~6.20 ka BP, and (IIIc) the magthermal and maghumid episode of the Holo-cene from ~6.20 to ~5.40 ka BP.  相似文献   

5.
Steady-state and time-resolved fluorescence spectroscopies have been used to study the excited state properties of Chl a in different aggregation forms of light-harvesting complex Ⅱ (LHC Ⅱ) from an intertidal green alga, Bryopsis corticulans, i.e. LHC Ⅱ monomer, trimer and oligomer. When either Chl a or Chl b was selectively excited, the observed decrease in Chl a fluorescence in the oligomer is proved to be caused mainly by the fast fluorescence quenching among Chl a molecules, rather than by the decrease in Chl b-to-Chl a singlet excitation transfer efficiency. Analyses of the picosecond time-resolved fluorescence kinetics identified two exponential decay components in all of the three forms of LHC Ⅱ: a longer-lived component (4.1 -4.7 ns) originating from fluorescence emission of Chl a, and a shorter-lived one (135-540 ps) from the rapid equilibration of singlet excitation among Chl a molecules. The time constant of excitation equilibration is 135 ps in oligomer, 520 ps in trimer and 540 ps in monomer. These results imply that LHC Ⅱ in oligomer form is inherently able to quench Chl a excitation, a mechanism which may be related to the photoprotection of PS Ⅱ via changing the degree of LHC Ⅱ aggregation in Bryopsis corticulans.  相似文献   

6.
The existence of nontrivial homoclinic orbits of periodic Hamiltonian systems: q + Vq(t,q) = 0 is proved, where q = (q1, q2,…,qn), n > 2; V(t, q) R1 × Rn \ {e}→ R1 is a potential with a singularity, i.e. - V(t, q)→+∞, as q→e. The main assumptions are Gordon-strong force condion and the uniqueness of a global maximum of V( t, q).  相似文献   

7.
Rapid growth behavior of ζ phase has been investigated in the undercooling experiments of Cu-14%Ge, Cu-15%Ge, Cu-18.5%Ge and Cu-22%Ge alloys. Alloys of the four compositions obtain the maximum undercoolings of 202 K(0.17TL), 245 K(0.20TL), 223 K(0.20TL) and 176 K(0.17TL), respectively. As the content of Ge increases, the microstructural transition of "a(Cu) dendrite + ζ" peritectic phase → ζ" peritectic phase →, ζ dendrite + (ε+ζ) eutectic" takes place in the alloy at small undercooling, while the microstructural transition of "fragmented α (Cu)dendrite + ζ peritectic phase →, ζ peritectic phase →ζ dendrite + ε phase" happens in the alloy at large undercooling. EDS analysis of the Ge content in peritectic phase indicates that undercooling enlarges the solid solubility of ζ rdendrite, which leads to a decrease in the Ge content in ζ phase as undercooling increases. In the Cu-18.5%Ge alloy composed of ζ peritectic phase, the Ge content in ζ phase increases when undercooling increases, which is due to the restraint of the Ge enrichment on the grain boundaries by high undercooling effect.  相似文献   

8.
YVO4:Er3+, Yb3+ with varying Yb3+ concentrations were prepared by a precipitation method. The results of X-ray diffraction (XRD) show that all the samples have a tetragonal zircon structure; the calculated average crystallite sizes are in the range of 14–22 nm. The lattice constants and cell volume of the samples decrease slightly with the increase in Yb3+ concentration. The upconversion luminescence spectra of all the samples were studied under 980 nm laser excitation. The strong green emission is observed, which is attributed to the 2H11/24I15/2 and 4S3/24I15/2 transitions of Er3+, and the red emission peaks in 650–675 nm can be ignored. The emission intensity for the sample depends on the Yb3+ concentration. These results reveal that the upconversion processes of YVO4:Er3+, Yb3+ are related to the structure and the doping Yb3+ concentration of the sample.  相似文献   

9.
In the medium of H2O, C2H5OH and HAC, the reaction of Gd(NO3)3·6H2O with C6H5COONa and C12H8N2 produced a novel binuclear Gd(III) complex in formula [Gd2(C12H8N2)2 (C6H5COO)6]. Crystallographic data: crystal system, triclinic; space group, P1; unit cell dimensions, a=1.191 9(2) nm,b =1.244 2(2) nm,c = 1.080 4(2) nm, α = 93.57(3)°, β= 113.33(3)°, γ= 105.06(3)°, Z=l. The finalR =0.037 6. The magnetic measurement of the crystal powder in the temperature region of 1.5–300 K shows that this complex possesses antiferromagnetic property with fitting magnetic parametersJ = −0.471 andg =1.975.  相似文献   

10.
Using in situ zircon dating by LA-ICP-MS and MC-ICP-MS, detrital zircon of 3981±9 Ma age was found in metamorphic rocks of the Ningduo Rock Group, Changdu Block of Northern Qiangtang. This is the oldest age record that has been found in the Qiangtang area. This finding also constitutes the third zircon locality in China with an age older than 3.9 Ga. Thus, the discovery provides new information for the study of Hadean crust. In addition, we found 3.51–3.13 Ga, ∼2440 Ma, ∼1532 Ma, ∼982 Ma and ∼618 Ma age peaks from 100 test spots. The younger ages of ∼982 Ma and ∼618 Ma correspond to the formation of the Rodinian super-continent and the Pan-African event, respectively. These findings suggest a close relationship between these zircons and the Gondwanan super-continent. The age of ∼618 Ma defines the lower limit on the deposit time of the protolith for the garnet-mica-quartz schist in the Ningduo Rock Group. Zircons with an age of ∼982 Ma generally display a negative ɛHf(t) and a two-stage Hf model with concentrated ages around 1933–2553 Ma. This pattern indicates that the source area of the Ningduo Rock Group underwent a significant separation of depleted mantle into the crust during the Paleoproterozoic Era. However, zircons with ages of 2854–3505 Ma also show a negative ɛHf(t) and a two-stage Hf model with a concentration of ages around 3784–4316 Ma. These results demonstrate that the source area of the Ningduo Rock Group contains a residual amount of ancient (Hadean) crustal materials. This paper provides new information on the relationship between the basement of the Qiangtang area and the Paleoproterozoic basements of the Gangdese and Himalayan regions, which constrains the northern boundary of Gondwana.  相似文献   

11.
Biological nitrogen fixation is one of the most im-portant biochemical reactions in nature. It is catalyzed by an anaerobic metalloenzyme complex-nitrogenase. Three genetically distinct nitrogenase systems exist in Azotobacter vinelandii (A. vinelandii): Mo-containing nitrogenase, V-containing one and “Fe only” nitro-genase[1―4]. They are composed of two separable com-ponent proteins. For example, conventional Mo-con- taining nitrogenase is composed of component I (MoFe protein) and com…  相似文献   

12.
The fluorescence emission from fluoroquinolones is shown to be associated with the substituted quinoline portion of the molecule. Neutral, anionic, zwitterionic and cationic forms of the fluorophore are proposed to account for the fluorescent behavior in aqueous and organic media of different acidities. In aqueous solution a ground-state pKa was observed for NFX and CPFX from a study of the pH vs. fluorescence profile with excitation at 331 nm, the ground-state microscopic dissociation constents for NFX or CPFX were determined. The causes of fluorescence changing were explained. The optimum condition for the fluorimetric determination of NFX, CPFX is an acidic medium (pH=2.0∼4.0) with λex=280 nm or 331 nm and λem=445 nm. Supported by the National Natural Science Foundation of China Huang Zuyun: born in Aug. 1963. Ph. D graduate student  相似文献   

13.
    
The distribution of a CP-asymmetric quantityA in the decay channelJ/ψπ + π π 0 is investigated. This dimensionless quantityA is constructed from the momenta of the π-meson final states, namely A=P x π + P y π -P x π P y π , whereP h,P x h andP y h are the module of the momentum of a hadron h, the x- and y-components of that momentum respectively, theJ/ψ particle is produced by e+ e collision, and the direction of the momentum of e+ is taken to be the positive direction ofz axis. There would exists the violation under the combined transformation of charge conjugation and space reflection (CP violation) when the average ofA among a lot of events, 〈A〉, be examined to be nonzero clearly from data. In this way, 748 events are selected from the BES experimental data, and analyzed. The corresponding averageA-value is measured to be 〈A〉 = 0.010 39 ± 0.014 61 ± 0.015 2. Further, some discussion of our result, the size of the data sample being need for further attempt and a possible perspective are given.  相似文献   

14.
The distribution of a CP-asymmetric quantityA in the decay channelJ/ψπ + π π 0 is investigated. This dimensionless quantityA is constructed from the momenta of the π-meson final states, namely A=P x π + P y π -P x π P y π , whereP h,P x h andP y h are the module of the momentum of a hadron h, the x- and y-components of that momentum respectively, theJ/ψ particle is produced by e+ e collision, and the direction of the momentum of e+ is taken to be the positive direction ofz axis. There would exists the violation under the combined transformation of charge conjugation and space reflection (CP violation) when the average ofA among a lot of events, 〈A〉, be examined to be nonzero clearly from data. In this way, 748 events are selected from the BES experimental data, and analyzed. The corresponding averageA-value is measured to be 〈A〉 = 0.010 39 ± 0.014 61 ± 0.015 2. Further, some discussion of our result, the size of the data sample being need for further attempt and a possible perspective are given.  相似文献   

15.
The crystal structure of a new mineral of the stibnite group, Sb-2Se-3, has been determined. The cell constants, obtained by least-squares calculation from direct θ -value's measurements on the diffractometer are: a =1.158 8(5), b =1.174 4(4), c =0.395 5(2) nm; orthorhombic; V =0.538 23 nm+3; Z =4. The space group is Pbnm. X-ray single crystal data, using Mo K α radiation, were measured on a RIGAKU RASA-5RP automated diffractometer and refined to a final R index of 0.048 1. Sb-2Se-3 is isostructural with Sb-2S-3 and Bi-2S-3. Each Sb(1) atom is six-coordinated by 3 Se(1), 1 Se(2) and 2 Se(3) atoms at distances 0.266 0-0.323 6 nm. Each Sb(2) atom is seven-coordinated by 2 Se(1), 2 Se(2) and 3 Se(3) atoms at distances of 0.258 1- 0.346 7 nm. The crystal structure consists of chains parallel to c or needle axis. The strongest bonds (shortest separations) are within the chains. Many important physical properties of antimonselite (optical, ferroelectric, etc.) are related to its crystal structure.  相似文献   

16.
Field measurements of air-sea CO2 exchange in three coral reef areas of the South China Sea (i.e. the Yongshu Reef atoll of the Nansha Islands, southern South China Sea (SCS); Yongxing Island of Xisha Islands, north-central SCS; and Luhuitou Fringing Reef in Sanya of Hainan Island, northern SCS) during the summers of 2008 and 2009 revealed that both air and surface seawater partial pressures of CO2 (pCO2) showed regular diurnal cycles. Minimum values occurred in the evening and maximum values in the morning. Air pCO2 in each of the three study areas showed small diurnal variations, while large diurnal variations were ob-served in seawater pCO2. The diurnal variation amplitude of seawater pCO2 was ~70 μmol mol–1 at the Yongshu Reef lagoon, 420–619 μmol mol–1 on the Yongxing Island reef flat, and 264–579 μmol mol–1 on the reef flat of the Luhuitou Fringing Reef, and 324–492 μmol mol–1 in an adjacent area just outside of this fringing reef. With respect to spatial relations, there were large differences in air-sea CO2 flux across the South China Sea (e.g. ~0.4 mmol CO2 m–2 d–1 at Yongshu Reef, ~4.7 mmol CO2 m–2 d–1 at Yongxing Island, and ~9.8 mmol CO2 m–2 d–1 at Luhuitou Fringing Reef). However, these positive values suggest that coral reef ecosystems of the SCS may be a net source of CO2 to the atmosphere. Additional analyses indicated that diurnal variations of surface seawater pCO2 in the shallow water reef flat are controlled mainly by biological metabolic processes, while those of deeper water lagoons and outer reef areas are regulated by both biological metabolism and hydrodynamic factors. Unlike the open ocean, inorganic metabolism plays a significant role in influencing seawater pCO2 variations in coral reef ecosystems.  相似文献   

17.
The definition of n-parameter infinite-dimensional (r,δ) -Ornstein-Uhlenbeck process {xt (·) } ((r, δ)-OUPn∞ for short) is given. The absolute continuity of distribution μt of Xt(·) and the limit of Xt(·) when |t| →∞ is discussed.  相似文献   

18.
The characteristics of the geopotential coefficient J2 in different periods are analyzed using satellite laser ranging data spanning the last 27 years.The satellites used in the analysis are Lageos1 and Lageos2.The variations in J2 are obtained by determining the dynamic orbit.The results show that there are strong seasonal and long-term variations.For different data spans,the seasonal variations agree well in terms of both amplitude and phase.Using all the data,the amplitude and phase of the annual term are 2.5 10-10 and 127°,respectively,while the amplitude and phase of the semiannual term are 0.94 10-10 and 213°,respectively.In the case of long-term variation,the secular variation in J2(J2) is-2.2 10-11 a-1 from 1984 to 2010.J2 differs for the different periods because of interannual variations,such as the "1998 anomaly".Another anomaly may have taken place during 2007-2010.Although the cause of the anomaly is unknown,it is an important observational constraint on the shape of the Earth.  相似文献   

19.
Let I= [0,1] and ω0 be the first limit ordinal number. Assume that f: I→I is continuous , piece-wise monotone and the set of periods of f is { 2': i∈ {0} ∪ N}. It is known that the order of (I, f) is ω0 or ω0 + 1. It is shown that the order of the inverse limit space (I, f) is ω0 (resp. ω0 + 1) if and only if f is not (resp. is) chaotic in the sense of Li-Yorke.  相似文献   

20.
Using a new ground-state ab initio potential energy surface reported by Deskevich et al., the product polarizations in the reactions F+HCl→HF+Cl and F+DCl→DF+Cl were studied by employing the quasi-classical trajectory method. At a collision energy of 10 kcal/mol, the four generalized polarization-dependent differential cross-sections (2π/σ)(dσ00/dω t ), (2π/σ)(dσ20/dω t ), (2π/σ)(dσ22+/dω t ) and (2π/σ)(dσ21−/dω t ) were calculated in the center-of-mass frame. The distribution of the angle between k and j′, P r ), the distribution of the dihedral angle denoting the k-k′-j′ correlation, P r ), and the angular distribution of the product rotational vectors in the form of polar plots P r , φ r ) were also calculated. The evident influence of isotope substitution on the product polarization is revealed. This effect may result from the different mass factors of the two reactions.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号