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1.
对辽河断陷盆地内陆湖泊相下第三系沙三下部地层进行了研究,认为在此地层中碳酸盐δ13C严重正异常,并根据其特定的地质背景,进行了成因探讨.结果表明,沉积有机质经成岩演化后生成油气经历了成岩作用、深成作用和变质作用三个阶段.在成岩作用阶段,地质聚合物丢失部分13C同位素,在深成作用阶段残余母质中相对富集13C,变质阶段生成甲烷的δ13C值增大.同时还提出了与有机质分解油气生成有关的孤立封闭盆地δ13C异常成因模式.  相似文献   

2.
贵州二叠纪海相碳酸盐岩碳、氧同位素地球化学演化规律   总被引:1,自引:0,他引:1  
以贵州罗甸二叠纪剖面为研究对象,详细讨论了海相碳酸盐岩的碳、氧同位素组成特点,及影响碳酸盐岩的δ13C和δ18O的主要因素。在此基础上系统阐述了整个二叠纪海相碳酸盐岩的δ13C和δ18O的演化与海平面升降的关系,第一次系统建立了二叠纪古海洋碳酸盐岩的碳、氧同位素演化曲线。  相似文献   

3.
测量了非晶态Fe77Cr13Zr10合金的磁化强度与温度和磁场的关系.在居里点附近样品的磁特性符合二级相变规律,得到临界指数β=0.40,γ=1.45,δ=4.85,样品的居里温度Tc=(212.1±0.3)K.在实验误差范围内,临界指数β、γ、δ满足关系式γ=β(δ-1),在190~250K温度范围内,实验数据满足二级相变的磁状态方程.  相似文献   

4.
樊然学 《自然科学进展》1999,9(12):1126-1132
对川西争中段孝泉,新场合合兴场地区9个气藏的天然气进行了化学与碳同位素组成研究。天然以甲烷为主,总烃含量〉99%,湿度〉0.5%、δ^13C1〉-37‰与δ^13C2〉-27‰。天然气的烃类组分由沉积物有机质热解形成。  相似文献   

5.
用AM1法全优化计算了CLT酸和它的29种异构体的分子几何和电子结构,首次给出了它们的稳定性理论排序,在各异构体中,氨基和磺酸基处于邻位、对位时,分子总能量较低;CLT酸的分子总能量最低,故在所有异构体中最稳定;C.I.颜料红53的2种异构体的AM1计算表明,当羟基与磺酸基处于分子同侧时较稳定,2种构型的能量差为6.08kJ/mol,2种构型转换所需的位垒分别为22.90kJ/mol和16.82kJ/mol,并给出了2种构型彼此转换的位能曲线  相似文献   

6.
以一取代苯为基本模型,由一取代苯对位质子的 ̄1H──NMR谱化学位移δ_p与 ̄(13)C──NMR谱化学位移δ_c=128.5+A_p计算式中的取代参数A_p之间的线性关系,用最小二乘方法来得一取代苯对位碳核 ̄(13)C──NMR谱化学位移经验公式:δ'_c=9.2+16.39δ_p,其计算结果与文献值相一致。  相似文献   

7.
华南晚二叠世至早三叠世初灰岩碳同位素地层旋回   总被引:3,自引:1,他引:2  
在华南晚二叠世灰岩高分辨率碳同位素地层中,可明显识别出2个三级旋回和叠加其上的几个四级旋回.其中长兴阶包括3个碳同位素四级旋回,和吴家坪阶上部的一个四级旋回一起组成了完整的三级旋回.早三叠世初灰岩的δ13C值缓慢向正值方向移动,构成一个完整的四级旋回.华南长兴阶层型剖面灰岩的碳同位素四级旋回与“亚层序”相当,地层厚度为11m~18m,沉积时间约为1.2~1.7百万年.华南P/T界线地层上,生物集群绝灭导致的δ13C突变为高负值事件与界线附近的δ13C低值区相叠加,形成了δ13C的强烈负异常,其中生物集群绝灭成因可能占2/3以上,变负的幅度达0.5‰以上.据高分辨率地层框架估算,碳同位素强烈负异常事件的持续时间约1.5~2.6万年.  相似文献   

8.
内陆湖泊相碳酸盐δ^13C严重正异常成因模式   总被引:1,自引:0,他引:1  
对辽河断陷盆地内陆湖泊相下第三系沙三下部地层进行了研究,认为在此地层中碳酸盐δ^13C严重正异常,并根据其特定的地质背景,进行了成因探讨,结果表明,沉积有机质经成岩演化后生成油气经历了成岩作用、深成作用和变质作用三个阶段。在成岩作用阶段,地质聚合物丢失部分^13C同位素,在深成作用阶段残余母质中相对富集^13C,变质阶段生成甲烷的δ^13C值增大。同时还提出了与有机质分解油气生成有关的孤立封闭盆地  相似文献   

9.
山西省柳林奥陶系马家沟组第五段第一亚段主要由白云岩组成,顶部为灰岩、沉积于浅的、局限的、低能、基底起伏小、蒸发作用强的克拉通内陆表海环境下.白云石的δ13C值为-8.1~0.1‰,平均-3.0‰;δ18O值为-10.9~7.1‰,平均-8.9‰;白云石的碳氧稳定同位素值与泥晶方解石差别不大.准同生白云石的δ13C为-4.9~0.1‰,平均-2.1‰;δ18O值为-10.3~-7.1‰,平均-8.7‰.成岩白去石的δ13C值为-8.1~-3.3‰,平均-5.4‰;δ18O值为-10.9~-7.7‰,平均-9.2‰.白云石的Fe2O3含量为0.51%~2.99%,平均1.36%,白云石较泥晶方解石的铁含量高.白云石的Sr含量为13~47(10-6),平均23(10-6),白云石和泥晶解石的Sr含量均低.白云石较方解石的晶胞体积减少12.7%左右.白云石化所引起的体积缩小,产生了大量的晶间孔.有利于淡水的渗透、淋滤,晶间孔进一步改造,形成了晶间溶孔和溶蚀孔、洞、缝.白云石样品的MgCO3含量几乎都大于50mol%,白云石化,是淡水与富镁海水混合的结果.  相似文献   

10.
黔西南冰洲石矿床地球化学研究   总被引:3,自引:0,他引:3  
查明黔西南贞丰等地冰洲石矿床的成矿温度为126~160℃,成矿压力为(260~520)×105Pa;成矿流体盐度(SNaCl)为12.2%~19.6%。研究了不同成矿阶段方解石、冰洲石的氢、氧、碳同位素组成及变化特征:其中冰洲石成矿阶段δ18O值为16.24~18.48‰,平均17.36‰;W/R为0.16~0.18。而从薄层方解石阶段到冰洲石成矿阶段δDH2O=-49~-68‰。δ13C(PDB)=-0.60~0.73‰,δ13CCO2(PDB)为-0.37~2.43‰。计算出δ13C∑C=-2.08~-2.49‰。研究表明成矿流体来源于大气降水与加热的地下水的混合,碳来源于地层。探讨了冰洲石成矿时特定的物理化学条件及地质环境。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

15.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

16.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

17.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

18.
以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.  相似文献   

19.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

20.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

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