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1.
肉桂酸乙酯的合成研究 总被引:4,自引:0,他引:4
报道了以固载杂多酸盐TiSiW12O40/TiO2催化剂,对以肉桂酸和乙醇为原料合成肉桂酸乙酯的反应条件进行了研究。实验结果表明;TiSiW12O40/TiO2具有良好的催化活性,最佳反应条件为;醇酸物质的量比为9:1,催化剂的用量为反应物料总量的2.0%,反应时间3.0h,上述条件下,肉桂酸乙酯的产率为58.7%。 相似文献
2.
TiSiW12O40/TiO2催化合成苯甲酸丙酯 总被引:5,自引:1,他引:4
首次报道了以固载杂多酸盐TiSiW12O40/TiO2为多相催化剂,对以苯甲酸和丙醇为原料合成苯甲酸丙酯的反应条件进行了研究。实验表明:TiSiW12O40/TiO2是合成苯甲酸丙酯的良好催化剂,最佳反应条件为:醇酸摩尔比为4:1,催化剂用量为反应物料总量的1.5%,反应时间为2.5h。上述条件下,苯甲酸丙酯的产率可达70.5%。 相似文献
3.
TiSiW12O40/TiO2催化合成氯乙酸正丁酯 总被引:3,自引:0,他引:3
首次以固载杂多酸盐TiSiW12O40/TiO2为多相催化剂,通过氯乙酸和正丁酸反应合成了氯乙酸正丁酯,并探讨了诸因素对产率的影响。实验表明:TiSiW12O40/TiO2具有良好的催化活性,醇酸物质的量比为1.4:1,催化剂用量为反应物料总量的2.0%,反应时间0.5h,反应温度130-139℃,产率可达66.51%。 相似文献
4.
TiSiW_(12)O_(40)/TiO_2催化合成对羟基苯甲酸乙酯 总被引:6,自引:0,他引:6
首次以TiSiW12O40/TiO2为催化剂合成了对羟基本甲酸乙酯。结果表明:TiSiW12O40/TiO2具有良好的催化活性,醇酸摩尔比为4:1,催化剂的用量为反应液总量的2.0%,酯化反应时间为2.0h,反应温度为84~86℃,对羟基苯甲酸乙酯的产率可达87.5%。 相似文献
5.
TiSiW12O40/TiO2催化合成葡萄糖五丙酸酯 总被引:1,自引:0,他引:1
报道了新型催化剂TiSiW12O40/TiO2催化酯化合成葡萄糖五丙酸酯的糖酸比、催化剂用量、反应时间、反应温度诸因素对产率的影响。实验表明:TiSiW12O40/TiO2是合成葡萄糖五丙酸脂的良好催化剂。最佳反应条件为:糖酸摩尔比1:6.催化剂的用量为反应液的2.0%.酯化反应时间为2.0h,反应温度95℃~105℃.反应产率可达84.5%。 相似文献
6.
苯甲酸丙酯的合成研究 总被引:1,自引:1,他引:0
报道了以固载杂多酸盐TiSiW12O40/TiO2为催化剂,对以苯甲酸和丙醇为原料合成苯甲酸丙酯的反应条件进行了研究,实验结果表明,TiSiW12O40/TiO2具有良好的催化活性,最佳反应条件为:醇酸物质的量比为4:1,催化剂的用量为反应物料总量的1.5%,反应时间2.5h,上述条件下,苯甲酸丙酯的产率为70.5%。 相似文献
7.
报道了以TiSiW12O40/TiO2为催化剂,通过乙酰乙酸乙酯和1,2-丙二醇反应合成了苹果酯-B,探讨TiSiW12O40/TiO2对缩酮反应的催化活性,较系统地研究了原料量比、催化剂用量、反应时间等因素对产品收率的影响.实验表明:TiSiW12O40/TiO2是合成苹果酯-B的良好催化剂,在乙酰乙酸乙酯与1,2-丙二醇物质的量比为1:2,催化剂为反应物料总质量的1.13%,石油醚为带水剂,反应时间2.0 h的优化条件下,苹果酯-B的收率可达93.4%. 相似文献
8.
丁酸系列酯的合成研究 总被引:1,自引:0,他引:1
报道了以固栽杂多酸盐TiSiW12O40/TiO2为催化剂,对以乙醇、丙醇、丁醇、正戊醇、异戊醇和正丁酸为原料合成丁酸酯的反应条件进行了研究。实验结果表明。TiSiW12O40/TiO2具有良好的催化活性,最佳反应条件为:醇酸物质的量比为1.3;1,催化剂的用量为反应物料总量的2.0%。反应时间1.5h,上述条件下,丁酸乙酯的产率为75.6%,丁酸丙酯的产率为81.2%,丁酸丁酯的产率为84.7%,丁酸正戊酯的产率为85.1%.丁酸异戊酯的产率为83.1%。 相似文献
9.
TiSiW12O40/TiO2催化合成丙酸正丁酯 总被引:6,自引:2,他引:4
首次以固载杂多酸盐TiSiW12O40/TiO2为多相催化剂,通过丙酸和正丁醇反应合成了丙酸正丁酯,并探讨了诸因素对酯化率的影响,实验表明,TiSiW12O40/TiO2具有良好的催化活性,醇酸物质的量比为1.3:1,催化剂用量为反应物料总量的1.5%,反应时间1.0h,反应温度116-128度,酯化率可达71%。 相似文献
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11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness. 相似文献
12.
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly. 相似文献
13.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。 相似文献
14.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death. 相似文献
15.
Miao Maosheng 《华南师范大学学报(自然科学版)》2014,(6)
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula- 相似文献
16.
Yang Weitao 《华南师范大学学报(自然科学版)》2014,46(6):137-138
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re- 相似文献
17.
Bernard Kirtman 《华南师范大学学报(自然科学版)》2014,(6)
正The electronic and nuclear(structural/vibrational)response of 1D-3D nanoscale systems to electric fields gives rise to a host of optical,mechanical,spectral,etc.properties that are of high theoretical and applied interest.Due to the computational difficulty of treating such large systems it is convenient to model them as infinite and periodic(at least,in first approximation).The fundamental theoretical/computational problem in doing so is that 相似文献
18.
Michael Springborg 《华南师范大学学报(自然科学版)》2014,(6):136
For molecular systems,the quantum-mechanical treatment of their responses to static electromagnetic fields usually employs a scalar-potential treatment of the electric field and a vector-potential treatment of the magnetic field.Although the potential for each field separately is associated with the choice of an(unphysical)origin,the precise choice of the origin for the electrostatic field has little consequences for the results.This is different for the 相似文献
19.
Zhu Chaoyuan 《华南师范大学学报(自然科学版)》2014,46(6):140-140
Franck-Condon factors bridge the gap between theoretical modeling and experimental observations for molecular electronic spectroscopy and electron transfer.Under the displaced harmonic oscillator approximation,multidimensional Franck-Condon factors are decomposed into a product of many one-dimensional(1D)Franck-Condon(FC)factors,and each 1D-FC factor is associated with one Huang-Rhys factor that determines the leading contribution of 相似文献
20.
《上海师范大学学报(自然科学版)》2014,(5):550
<正>"The Journal of Shanghai Normal University:Mathematics"is published by Shanghai Normal University as regular issues of The Journal of Shanghai Normal University each year from 2014 in English.The editors-in-chief of the issues are professors Yuhao Cong and Maoan Han.The Journal of Shanghai Normal University was started in 1958 with 相似文献