北大别罗田超高压榴辉岩中峰期变质矿物:褐帘石和氟磷灰石

对北大别西南部"罗田穹隆"中超高压榴辉岩进行了变质岩石学研究,发现其中含有褐帘石和氟磷灰石.褐帘石主要以包体形式产出于石榴子石中,富含稀土元素,部分已退变为绿帘石;氟磷灰石主要以包体形式产出于石榴子石中或存在于基质中,产出于石榴子石中氟磷灰石具有较高的F含量(~3 wt%),而基质中氟磷灰石大多数具有磁黄铁矿针状出溶体及相对低的F含量(~1wt%).根据石榴子石中与褐帘石、氟磷灰石共生的包体矿物组合以及氟磷灰石中较高的F含量,证明它们形成于超高压条件下.由此提出了罗田榴辉岩曾发生超高压变质作用的新证据.     

A combined study of SHRIMP U-Pb dating, trace element and mineral inclusions on high-pressure metamorphic overgrowth zircon in eclogite from Qinglongshan in the Sulu terrane

Methods recently advanced for discrimination on the genesis of metamorphic zircon, such as analysis of mineral inclusions and trace elements, provide us powerful means to distinguish zircon overgrowth during high-pressure metamorphism. Zircons in ultrahigh-pressure eclogite from Qinglongshan in the Sulu terrane were studied by the SHRIMP U-Pb method in combining with trace element and mineral inclusion analyses. No inherited core was identified in the analyzed zircons by means of cathodoluminescence images. The occurrence of high-pressure metamorphic mineral inclusions in zircon, such as garnet, omphacite, rutile, and the flat HREE pattern in zircon indicate that the zircon formed at high-pressure metamorphic conditions. Therefore, a weighted average U-Pb age of 227.4±3.5 Ma obtained from such a kind of zircon is interpreted to represent the timing of peak nietamorphism for the Qinglongshan eclogite.     

Discovery of Sr-bearing and LREE daughter minerals in fluid inclusions of Maoniuping REE deposit, Sichuan Province

Maoniuping rare earth element (REE) deposit, located in Mianning area of Sichuan Province, is of unique geological characteristics and is large in scale. Some studies have shown that there are large amounts of multi phase fluid inclusions in fluorite, quartz and calcite. Besides the daughter minerals of halite, barite and gypsum, Sr bearing minerals (celestite, strontianite), apatite and eight light rare earth element (LREE) minerals have been found by scanning electron microscope/energy dispersive spectrometer techniques. The abundant occurrence of these daughter minerals shows that the ore-forming fluid is rich in Sr, Ba and LREE contents, and is related to nordmarkite in genesis.     

Yttrium zoning in garnet from the Xihuashan granitic complex and its petrological implications

The Xihuashan granitic complex is characterized by enrichment in rare-earth elements (REE). In particular, the second-stage granite (G-b) is markedly enriched in yttrium, and therefore contains complex associations of Y-bearing minerals. In this granite, garnet displays specific yttrium zoning with an Y-rich core and a “clean“ rim. Besides minute inclusions of Y-bearing minerals, garnet involves a striking amount of Y and HREE in its central area.It is suggested that enrichment in Y in the garnet core accords with that in the melt as a result of REE magmatic fractionation. However, the “clean“ rim may be the direct result of accumulation of fluid phases in the magma, which is virtually unfavorable for the entrance of REE in the garnet structure.     

应用锆石研究铀成矿流体的地球化学特征:以粤北棉花坑铀矿床为例

铀矿中锆石富集Li、P、Ti、Nb、Hf、U、Th、Ta、Y、Rare earth elements(REE)等微量元素,Th/U比值较低,在以大陆上地壳为标准化的模式图上呈现明显的重稀土富集、Ce、Y正异常和Eu负异常的特征。根据锆石/热液间微量元素的分配系数估算了成矿流体的微量元素质量分数。铀成矿流体具有富U,低Th/U比值,高稀土元素质量分数,轻、重稀土分异不明显,显著的Ce、Eu负异常和Y正异常,低Ce~(4+)/Ce~(3+)比值等特征。成矿流体主要来源于岩浆期后热液,并得到流体/岩石反应的改造,流体上升减压导致流体沸腾、气体溢出、碱性增高和还原环境,最终导致铀矿物的沉淀和铀矿床的形成。     

某凝灰岩型金矿稀土微量元素中子活化研究

通过对四川某金矿岩样的中子活化分析，揭示了岩石中稀土微量元素含量的特征，为寻找贵金属矿产，提供了有利的研究分析资料。     

川井坳陷赛汉组沉积物源分析及其对砂岩型铀成矿的控制作用

为明确晚白垩世赛汉期盆地沉积期构造分区、充填过程和沉积相空间分布,本文运用岩矿鉴定、重矿物分析、岩石地球化学特征分析等方法,讨论了川井坳陷赛汉组沉积物源,认为赛汉组碎屑岩具有低成熟度和近源堆积特征,重矿物成分主要以磁铁矿、石榴石为主,与蚀源区花岗岩相似;赛汉组稀土元素配分曲线表现为明显Eu负异常和右倾,微量元素曲线表现...     

ICP-MS的仪器参数对稀土元素离子信号强度的影响

研究了电感耦合等离子体质谱法（ICP－MS）的仪器主要参数（射频功率、雾化气流量、离子透镜电压）对15种稀土元素的离子、氧化物离子、氢氧化物离子和氢化物离子信号强度及各多原子离子产率的影响,并对各稀土元素多原子离子产率与各稀土元素性质的关系进行了探讨．研究结果有助于在测定单一高纯稀土中的其他稀土杂质时,选择仪器参数．     

洞庭盆地第四纪气候演变的沉积物地球化学记录

对洞庭盆地安乡凹陷东南部两护村ZKC1孔上新世末—第四纪沉积物的主量、微量和稀土元素以及粒度进行了分析,进而探讨洞庭盆地第四纪气候演变。曲线协变性及相关系数表明,ZKC1孔沉积物化学蚀变指数(CIA)与Cr、Ga、V、Nb、Be、Li、Sc、Th等微量元素含量呈明显的正相关。从陆相沉积物CIA及微量元素含量与温度和湿度正相关的概念出发,结合其他资料,重塑洞庭盆地第四纪气候演变过程:早更新世为冷干→暖湿→冷干→暖湿,中更新世为冷干→暖湿→冷干—温湿→暖湿,晚更新世为寒冷→温湿→寒冷,全新世总体为温湿—暖湿。这一结论与ZKC1孔孢粉组合特征反映的气候演变过程及中国东部第四纪气候演化基本吻合,说明沉积物CIA和微量元素含量较好地记录了第四纪气候演变信息。相关性分析表明洞庭盆地沉积物粒度对CIA无明显影响;CIA与沉积物粘土含量呈弱的正相关关系,应与湿热气候条件下有更强烈的风化和更多粘土矿物形成有关。     

贵州主要岩石类型风化土壤微量、稀土元素分布特征与生态环境关系探讨

根据贵州省地表出露岩石分布情况,将贵州分为5个区,即中部的碳酸盐岩区,东部新元古界浅变质岩区,西部威宁-赫章一带的玄武岩区,西北习水侏罗系碎屑岩区和西南部三叠系碎屑岩区.分别描述了4类岩石风化形成土壤的成土情况,认为碎屑岩和变质岩分布区成土性最好,玄武岩次之,碳酸盐岩区最差.对各岩石区形成的土壤微量、稀土元素含量分析,...     

大兴安岭北段漠河地区塔木兰沟组火山岩地球化学特征

 大兴安岭北段漠河地区分布有大面积的晚中生代火山岩,塔木兰沟组是其中喷发较早的一期。塔木兰沟组是一套中基性火山岩,包括熔岩和火山碎屑岩,研究其成因对于理解大兴安岭北段的构造演化具有重要意义。对塔木兰沟组火山岩样品进行了系统的主量元素和微量元素地球化学分析。结果表明：样品大部分呈碱性,SiO₂的质量分数为52.7%～57.8%,为中基性岩石,岩石类型为玄武质粗面安山岩和粗面安山岩;相容的过渡族金属元素如Cr、Co、Ni等含量低,微量元素比值如Nb/La、Ba/Nb、Nb/U、Ce/Pb等及稀土元素总量的变化范围大,具有右倾的轻稀土元素富集的稀土元素分布模式。岩石成因分析表明,富集的大陆岩石圈地幔先经历了部分熔融,然后熔浆受到了轻度的地壳物质的混染以及一定程度的分离结晶作用,最终形成了塔木兰沟组火山岩。     

副矿物地球化学研究进展

副矿物广泛分布于各类火成岩、变质岩和沉积岩中,对寄主岩石的形成环境有很高的敏感度。以锆石、金红石和磷灰石为例,分别从结构特征、微量元素地球化学特征和同位素年代学等方面介绍副矿物地球化学的主要研究进展。锆石中U和Th的含量、Th/U值、Zr/Hf值等均与锆石成因类型有关,但共生矿物的存在和蜕晶化等因素可能会对这些微量元素产生影响,也可能导致不准确的同位素年龄结果。金红石以高Nb和Ta为特征,不同类型岩浆岩中Nb/Ta值差异较大,Cr-Nb二元判别图解也可以用来判断变质原岩类型。Mn2+、Eu2+、Sm3+、Dy3+、Er3+等微量元素会使磷灰石在受到阴极射线的激发下产生黄、绿或蓝色的光,因此磷灰石的发光特征可以反映其化学组成。不同类型岩石中的副矿物REEs的组成特征明显不同,说明受后期地质活动影响较弱的副矿物仍能精确指示其形成环境。由于锆石中的Ti和金红石中的Zr均是温度的函数,因此是重要的地质温度计,而榍石中的Zr对压力较敏感,常被用作地质压力计。锆石、金红石和磷灰石均为高铀矿物,均可进行U-Pb同位素定年,副矿物Sm-Nd、Lu-Hf也已逐渐成为常规定年法。热年代学得到快速发展以来,高-中-低温同位素体系与地质温度计和压力计的配套使用,不仅能够获取更准确的年龄值,还能提供更完整的地质体演化p-T-t曲线。副矿物地球化学将会更注重于尚未深入研究的其他副矿物在岩浆和高温变质过程中、在油气成藏演化的不同阶段中、在微生物活动影响下的内部结构和成分变化,新的同位素体系、纳米技术和精度更高的分析仪器等的发展会为副矿物研究带来更多突破。     

米仓山区碱性花岗岩的物质组分

古老的碱性花岗岩在地壳中较为罕见。分布在米仓山区的碱性花岗岩属晋宁期同源岩浆演化后期的产物，其岩石化学成分以富碱（Ｋ＿２Ｏ＋Ｎａ＿２Ｏ＞８．０％）为特征，且Ｎａ＿２Ｏ＞Ｋ＿２Ｏ；含多种稀土、稀有分散元素。副矿物种类繁多，人工重砂中重矿物达３２种之多。稀土、稀有分散元素赋存状态多样。详细研究其物质组成及其特征对深入探索区内岩浆演化规律、元素地球化学特征及其成矿作用具有重要的理论和实际意义。     

内蒙古克什克腾旗白音高老组凝灰岩地球化学特征和构造环境探讨

内蒙古克什克腾旗地区出露有大面积的中生代白音高老组凝灰岩。凝灰岩时代为晚侏罗世与早白垩世,岩石类型主要为流纹质凝灰岩。通过主量地球化学特征研究,确认该区凝灰岩为高钾钙碱性系列—钾玄岩系列的偏碱质A型火山岩。稀土元素总量高,轻稀土略为富集,具较强的负Eu异常,稀土元素分配曲线相似;微量元素组表现为Rb、Th等大离子亲石元素相对富集,Sr、Zr等高场强元素相对亏损;主、微量元素地球化学特征显示该凝灰岩形成于非造山板内张性构造环境。     

小佟家堡子金矿床微量稀土元素特征

为进一步探讨小佟家堡子金矿床成矿物质来源及印支-燕山期岩浆活动对其成矿作用的影响,对该矿床岩矿石进行微量稀土元素的测试和特征分析.微量稀土元素特征显示,与矿体相比,盖县组片岩、大石桥组大理岩显示出相似的微量元素变化趋势以及稀土配分模式,印支期花岗岩仅在P,Zr,Hf等微量元素上出现较大反差,吕梁期-燕山期岩浆岩体在稀土配分模式上只有Er明显亏损,反映金成矿与地层和岩浆岩关系密切;稀土元素特征显示成矿热液为富Cl^-的还原性流体,成矿物质来源和成矿流体来源具有复杂性,吕梁期和燕山期花岗岩与盖县组片岩和大石桥组大理岩均为该矿体的形成提供了成矿物质,且深部成矿物质也参与成矿,矿床类型为岩浆热液叠加型金矿床.     

Discovery of Late Paleozoic retrograded eclogites from the middle part of the northern margin of North China Craton

The northern margin of the North China Craton (NCC), located between the Paleo-Asian Ocean tectonic region on the north and the NCC on the south, is a key region for studying the tectonic evolution of NCC. A Pre-cambrian retrograded eclogite (2500 Ma or 1800 Ma) was reported in Baimashi near Hengshan Mountain in the NCC, which is characterized by the vermicular symplec-tite of diopside and plagioclase with absence of ompha-cite[1,2]. In Hongqiyingzi Group from the middle part of the …     

Geochemical characteristics and tectonic implications of HP-UHP eclogites and blueschists in southwestern Tianshan, China

Four rock assemblages in correspondence with two different tectonic settings have been recognized in the NEE-SWW extending HP-UHP metamorphic belt in southwestern Tianshan, northwest China. Eclogite assemblage EC1 is geochemically akin to alkaline within-plate oceanic island basalt (OIB). EC2 shows affinity to enriched mid-oceanic ridge basalt (EMORB). Rare earth element (REE) and other immobile trace element characteristics of blueschist assemblage BS1 resemble those of normal mid-oceanic ridge basalt (NMORB). These three assemblages are likely formed on a seamount setting, and the prevalent presence of carbonate minerals and omphacite quartzite stripes/gobbets suggests ancient pelagic sediments including marls are probably developed upon the basaltic seamount. Whereas the geochemical characteristics of BS2 assemblage are of volcanic arc basalt-type. The seamount with the pelagic sediments on it is brought into the subduction zone, and volcanic arc basalts formed on the active continental margin and trench sediments are eroded and enwrapped in the subducting mass, they are altogether subjected to high to ultrahigh pressure metamorphism and subsequent exhumation towards surface. The HP-UHP metamorphic belt is thus interpreted as a subduction-accretionary complex formed by tectonic juxtaposition and imbrication of seamount, seafloor, trench and volcanic arc sequences during oceanic crust subduction.     

农用复合肥添加稀土对小麦幼苗生长发育影响的研究

为了研究复合肥添加稀土后对农作物生长发育的影响，以小麦作实验材料，在复合肥中添加不同剂量的稀土后作底肥，考察了小麦幼苗的生长发育情况，并分析了稀土和微量元素在小麦幼苗中的分布。实验结果表明：复合肥中一定剂量的稀土可以加快小麦幼苗的生长发育，同时能促进小麦幼苗对有益微量元素的吸收，减少稀土在小麦幼苗中的无益积累。预示农用复合肥恭加稀土在农业生产中有一定的推广价值。     

河南省土壤中稀土元素背景值的调查研究

本文对河南省110个县781个土壤样品进行三千多样次的分析.初步查明了河南省土壤中稀土元素含量和地理分布;揭示了它在各类土壤中可溶态含量水平,并初步澄清本省缺稀土的耕地土壤面积等.     

硝酸稀土对菜豆属(phaseolus)两个种幼苗期生理效应影响的研究

本文研究了不同浓度的硝酸稀土对菜豆属绿豆和赤豆两个种幼苗的生长以及主要成分、脂肪酶活力和其酯酶同工酶酶谱的影响。结果表明:①稀土浓度对赤豆的生长除500ppm 外,其余的浓度对主要成分的含量有促进作用;②稀土对绿豆的生长因浓度不同而有差别,其主要成分的含量亦不同,但均使酯酶同工酶酶带有所增加。